公开(公告)号：RU2151142C1

公开(公告)日：2000-06-20

申请号：RU97102108

申请日：1995-06-21

Applicant: BASF AG

Inventor： BERND MJULLER ,  KHARTMANN KENIG ,  REJNKHARD KIRSTGEN ,  KLAUS OBERDORF ,  FRANTS REL ,  NORBERT GETTS ,  KHUBERT ZAUTER ,  GIZELA LORENTS ,  EHBERKHARD AMMERMANN

IPC: C07D231/06 ,  A01N20060101 ,  A01N43/40 ,  A01N43/56 ,  A01N47/22 ,  A01N47/24 ,  A01N47/30 ,  A01P3/00 ,  C07C239/10 ,  C07C271/28 ,  C07C271/58 ,  C07D20060101 ,  C07D231/08 ,  C07D231/20 ,  C07D231/22 ,  C07D231/30 ,  C07D401/04 ,  C07D403/04

Abstract: agriculture. SUBSTANCE: described are new compounds, namely 2- [(dihydro)pyrazolyl-3'-oxymethylene] anilides of formula I wherein -- denotes single or double bond, and indexes and substituents are defined as follows: n is 0,1 or 2; m is 0,1 or 2, R2 substituents are different if m is more than 1; X is straight bond, 0 or NRa; Ra are hydrogen; R1 is C1-C4 alkyl, halogen or in case wherein n is 2, is hydrocarbon bridge additionally bonded with two adjacent ring atoms, said bridge containing 3 or 4 carbon atoms; R2 in nitro, halogen, C1-C4 alkyl, C1-C4 halogenalkyl or C1-C4 alkoxycarbonyl; R3 is optionally substituted alkyl, optionally substituted saturated ring or optionally substituted single or binuclear aromatic radical which, in addition to carbon atoms contains one to four nitrogen atoms as ring members; R4 is hydrogen or optionally substituted alkyl; R5 is alkyl, or in case X is NRa is additionally hydrogen. Compounds of formula I are useful for controlling pests and harmful fungi. Also described are method of preparation thereof and, intermediate compounds, agent for controlling agricultural pests and harmful fungi, and control method. EFFECT: increased efficiency of the title compounds and agents for controlling agricultural pests and harmful fungi. 12 cl, 6 tbl

公开(公告)号：RU2165927C2

公开(公告)日：2001-04-27

申请号：RU97102107

申请日：1995-06-21

Applicant: BASF AG

Inventor： BERND MJULLER ,  KHUBERT ZAUTER ,  NORBERT GETTS ,  KHARTMANN KENIG ,  FRANTS REL ,  GIZELA LORENTS ,  EHBERKHARD AMMERMANN

IPC: A01N43/653 ,  A01N47/08 ,  A01N47/12 ,  A01N47/24 ,  A01N47/30 ,  A01P3/00 ,  C07C205/06 ,  C07C205/19 ,  C07C239/08 ,  C07C239/10 ,  C07C239/20 ,  C07C271/00 ,  C07C271/06 ,  C07D249/10 ,  C07D249/12 ,  C07D401/04 ,  C07D403/04

公开(公告)号：RU2119911C1

公开(公告)日：1998-10-10

申请号：RU95114359

申请日：1993-12-17

Applicant: BASF AG

Inventor： AL BREKHT KHARREUS ,  NORBERT GETTS ,  FOLKER MAJVAL D ,  GARAL D RANG ,  UL F MISSLITTS ,  UL RIKH KLJAJN

IPC: C07C239/20 ,  C07C251/54 ,  C07C253/30 ,  C07C255/54 ,  C07C259/06

Abstract: FIELD: organic chemistry and chemical technology. SUBSTANCE: invention relates to simple hydroxylamine ethers of the formula (I) where X is halogen, C 1-4 -alkyl and C 1-4 -halogenalkyl; Y is H, NO 2 , halogen, C 1-4 -alkyl; n = 0-2; Alk is C 2 -- or C 3 --alkylene chain that can carries from one to three C 1-3 -alkyl groups. Ethers are synthesized by interaction of hydroxyimino-compound of the formula (II) where R is alkyl; R is alkyl, alkoxy or R + R is alkylene chain with alkylating agent in the presence of base, or the corresponding anion of compound (II) is treated directly with alkylating agent (III) and converted to hydroxyimino-derivative (IV) . Then (IV) is split to salt of compound (I) with mineral acid or strong organic acid. The synthesized compounds are intermediate products used for synthesis of compounds used for plant protection and synthesis of pharmaceutical preparations. EFFECT: improved method of synthesis. 9 cl, 1 tbl, 8 ex.

公开(公告)号：RU2092484C1

公开(公告)日：1997-10-10

申请号：SU4895396

申请日：1991-05-08

Applicant: BASF AG

Inventor： ULF MISSLITS ,  NORBERT MEJER ,  YURGEN KAST ,  NORBERT GETTS ,  ALBREKHT KHARREUS ,  BRUNO VYURTSER ,  KHELMUT VALTER ,  KARL-OTTO VESTFALEN ,  MATTIAS GERBER

IPC: A01N35/10 ,  A01N43/08 ,  A01N43/10 ,  A01N43/14 ,  A01N43/16 ,  A01N43/28 ,  A01P13/00 ,  C07C215/50 ,  C07C239/20 ,  C07C251/42 ,  C07C251/48 ,  C07C251/50 ,  C07C251/54 ,  C07C323/29 ,  C07C323/47 ,  C07D233/88 ,  C07D249/04 ,  C07D249/14 ,  C07D263/32 ,  C07D275/02 ,  C07D277/20 ,  C07D277/24 ,  C07D277/26 ,  C07D277/28 ,  C07D277/30 ,  C07D307/14 ,  C07D307/40 ,  C07D307/42 ,  C07D309/04 ,  C07D309/06 ,  C07D309/20 ,  C07D317/28 ,  C07D333/16 ,  C07D333/26 ,  C07D335/02 ,  C07D339/06 ,  C07D401/08 ,  C07D403/08 ,  C07D405/08 ,  C07D407/12 ,  C07D409/08 ,  C07D409/12 ,  C07D411/08 ,  C07D413/08 ,  C07D417/12 ,  C07D405/12

Abstract: Cyclohexenone oxime ethers (I) where R1 is alkyl; A is substituted or unsubstituted alkylene or alkenylene, where methylene is replaced by an oxygen atom, a sulfur atom, a sulfoxyl group, a sulfonyl group or -NRa-, Z is phenyl or a 5- or 6-membered heteroaromatic structure; X is substituted or unsubstituted amino, nitro, cyano, halogen, alkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkyl, C1-C4-haloalkoxy, carboxyl, C1-C4-alkoxycarbonyl, substituted or unsubstituted benzyloxycarbony or phenyl; n is 0 to 3, or 1 to 5 where X is halogen; R2 is alkoxyalkyl or alkylthioalkyl, substituted or unsubstituted cycloalkyl or cycloalkenyl, a substituted or unsubstituted 5-membered saturated heterocyclic structure with one or two heteroatoms, a substituted or unsubstituted 6- or 7-membered heterocyclic structure with 1-2 heteroatoms and 0-2 double bonds, a substituted or unsubstituted 5-membered heteroaromatic radical with 1-3 heteroatoms, or substituted or unsubstituted phenyl or pyridyl, and their agriculturally useful salts and esters of C1-C10-carboxylic acids and inorganic acids, processes for their manufacture, and their use as herbicides.

公开(公告)号：RU95114359A

公开(公告)日：1997-06-10

申请号：RU95114359

申请日：1993-12-17

Applicant: BASF AG

Inventor： AL BREKHT KHARREUS ,  NORBERT GETTS ,  FOLKER MAJVAL D ,  GARAL D RANG ,  UL F MISSLITTS ,  UL RIKH KLJAJN

IPC: C07C239/20 ,  C07C251/54 ,  C07C253/30 ,  C07C255/54 ,  C07C259/06

Abstract: Взаявкеописываетсяполучениепростыхгидроксиламиновыхэфиров:(Х= NO, СN, галоген, алкили галогеналкил; У=Н,NО, СN, галоген, алкили галогеналкил; n= 0-2 либо 1-4 вслучае, еслиУ ивсеХ обозначаютгалоген; Аlk обозначаетприопределенныхусловияхзамещенныйалкилен), атакжеихсолей, получаемыхс помощьюминеральныхкислотилисильныхорганическихкислот. Получениеосуществляютследующимпутем: либогидроксииминосоединение:(R= алкил; R= алкил, алкоксиилиК+К=алкиленоваяцепь) вприсутствиигидроксидащелочногометалла, алкоголятащелочногометалла, гидрокарбонатащелочногометаллаиликарбонатащелочногометаллав качествеоснования, либосоответствующийанионсоединениянепосредственно, спомощьюалкилирующегосредства:(R= приопределенныхусловияхзамещенныйалкилилиприопределенныхусловияхзамещенныйфенил) трансформируютв оксиминопроизводноезатемоксиминопроизводноес помощьюминеральнойкислотыилисильнойорганическойкислотырасщепляютв сольсоединенияи этусольпринеобходимостипереводятс помощьюоснованияв свободноесоединение.Простыегидроксиламиновыеэфирыпредставляютсобойпромежуточныепродуктыдлясредствзащитырастенийи дляфармацевтическихпрепаратов.

公开(公告)号：RU2014317C1

公开(公告)日：1994-06-15

申请号：SU4830460

申请日：1990-07-17

Applicant: BASF AG

Inventor： RAJNER KOBER ,  RAJNER SEELE ,  KHAJNTS ISAK ,  EKKARD KHIKMANN ,  NORBERT GETTS ,  TOMAS TSIRKE

IPC: C07C17/35 ,  C07C17/357 ,  C07C25/24 ,  C07C43/225 ,  C07C43/29 ,  C07D233/56 ,  C07D233/58 ,  C07D249/08 ,  C07D303/08 ,  C07D521/00 ,  C07C17/24

Abstract: A method for stereoselective preparation of Z -1,2-diarylallylchlorides of the general formula where R1 and R2 independently one of another are hydrogen, halogen, alkyl, halogenalkyl, alkoxy, halogenalkoxy or unsubstituted or substituted aromatic residue, n and m =1,2 or 3. chlorohydrins of the general formula where R1 and R2 having above mentioned value are dehydrated in the inert ether or ester of carboxylic acid and as solvent in the presence of anhydride of carboxylic acid or respective ketene and organic or inorganic acid or oleum at temperatures to 50 °C.

公开(公告)号：RU2143423C1

公开(公告)日：1999-12-27

申请号：RU97110779

申请日：1995-11-10

Applicant: BASF AG

Inventor： BERND MJULLER ,  RUT MJULLER ,  KHERBERT BAJER ,  KHUBERT ZAUTER ,  FRANTS REL ,  EHBERKHARD AMMERMANN ,  GIZELA LORENTS ,  NORBERT GETTS

IPC: A01N37/22 ,  A01N37/34 ,  A01N47/20 ,  A01N47/24 ,  A01N47/30 ,  A01N47/40 ,  A01P3/00 ,  A01P7/04 ,  C07C20060101 ,  C07C205/34 ,  C07C239/08 ,  C07C251/58 ,  C07C255/64 ,  C07C259/06 ,  C07C269/06 ,  C07C271/28 ,  C07C271/38 ,  C07C271/58 ,  C07C271/60 ,  C07C273/18 ,  C07C275/64 ,  C07C317/26 ,  C07C317/28 ,  C07C323/18 ,  C07C323/23 ,  C07C327/38 ,  C07C327/42 ,  C07D213/56 ,  C07D239/24 ,  C07D241/10 ,  C07D521/00 ,  C07C251/52

公开(公告)号：RU2125997C1

公开(公告)日：1999-02-10

申请号：RU94011635

申请日：1991-11-26

Applicant: BASF AG

Inventor： RAJNER KOBER ,  RAJNER SEELE ,  KHAJNTS ISAK ,  EHKKARD KHIKMANN ,  NORBERT GETTS ,  TOMAS TSIRKE

IPC: C07C17/35 ,  C07C17/357 ,  C07C25/24 ,  C07C43/225 ,  C07C43/29 ,  C07D233/56 ,  C07D233/58 ,  C07D249/08 ,  C07D303/08 ,  C07D521/00

Abstract: FIELD: agriculture. SUBSTANCE: present invention describes chloromethyldiaryloxiranes I: R R wherein and are independently hydrogen, halogen, n and m are 1,2 or 3, which are useful as intermediate products for synthesis of azolylmethyloxiranes having fungicidal activity. Compounds of formula I are prepared by epoxidation of corresponding diarylallyl chlorides III. Compounds of formula I make it possible to obtain final products with higher yield and less number of stages. EFFECT: improved properties of the title compounds. 2 cl, 1 dwg, 11 ex, 2 tbl

公开(公告)号：RU2096401C1

公开(公告)日：1997-11-20

申请号：SU5011959

申请日：1992-06-29

Applicant: BASF AG

Inventor： RAJNER KOBER ,  RAJNER SEELE ,  KHAJNTS ISAK ,  EKKARD KHIKMANN ,  NORBERT GETTS ,  TOMAS TSIRKE

IPC: C07B53/00 ,  C07C17/00 ,  C07C17/35 ,  C07C17/357 ,  C07C22/04 ,  C07C25/24 ,  C07C41/18 ,  C07C41/48 ,  C07C43/225 ,  C07C43/29 ,  C07D233/56 ,  C07D233/58 ,  C07D249/08 ,  C07D301/16 ,  C07D303/08 ,  C07D405/06 ,  C07D521/00

Abstract: Preparation of Z-1,2-diarylallyl chlorides of the general formula I in which the radicals R and R independently of one another are hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or a substituted aromatic radical, and n and m represent 1, 2 or 3, by dehydrating chlorohydrins of the formula II in which the radicals have the abovementioned meanings, at temperatures of up to 50 DEG C in the presence of a carboxylic anhydride and of an organic or inorganic acid, in an inert ether or carboxylate as the solvent, the reaction of these products to give azolylmethyloxiranes, and novel intermediates.

公开(公告)号：RU2084447C1

公开(公告)日：1997-07-20

申请号：RU92004580

申请日：1992-12-04

Applicant: BASF AG

Inventor： NORBERT MEJER ,  YURGEN KAST ,  ULF MISSLITS ,  ALBREKHT KHARREUS ,  NORBERT GETTS ,  BRUNO VYURTSER ,  KHELMUT VALTER ,  KARL-OTTO VESTFALEN ,  MATTIAS GERBER

IPC: A01N35/10 ,  A01N43/08 ,  A01N43/10 ,  A01N43/14 ,  A01N43/16 ,  A01N43/18 ,  A01N43/30 ,  A01N43/32 ,  A01N43/36 ,  A01N43/80 ,  A01P13/00 ,  C07C239/08 ,  C07C239/20 ,  C07C251/34 ,  C07C251/36 ,  C07C251/42 ,  C07C251/50 ,  C07C251/52 ,  C07C251/54 ,  C07C251/60 ,  C07C255/62 ,  C07C323/47 ,  C07D207/32 ,  C07D207/335 ,  C07D257/02 ,  C07D261/02 ,  C07D261/04 ,  C07D261/08 ,  C07D275/02 ,  C07D307/14 ,  C07D309/04 ,  C07D309/06 ,  C07D309/20 ,  C07D317/26 ,  C07D317/28 ,  C07D319/06 ,  C07D333/04 ,  C07D333/16 ,  C07D333/22 ,  C07D333/58 ,  C07D335/02 ,  C07D339/06

Abstract: Cyclohexenone oxime ethers of the general formula I in which the substituents have the following meanings: R is alkyl; A is optionally substituted C3-, C5- or C6-alkylene or C3-, C5- or C6-alkenylene, X is NO2, CM, halogen, alkyl, alkoxy, phenoxy, alkylthio, haloalkyl, haloalkoxy, carboxyl, alkoxycarbonyl, optionally substituted benzyloxycarbonyl, optionally substituted phenyl, n is 0 - 3 or 1 - 5 if X is halogen; R is alkoxyalkyl or alkylthioalkyl; optionally substituted cycloalkyl or cycloalkenyl, an optionally substituted 5-membered saturated heterocycle having one or two oxygen and/or sulphur atoms as hetero atoms, an optionally substituted 6- or 7-membered heterocycle having up to two oxygen and/or sulphur atoms and up to two double bonds, an optionally substituted 5-membered hetaryl having up to two nitrogen atoms and one oxygen atom or one sulphur atom, optionally substituted phenyl or pyridyl, and their agriculturally utilisable salts and esters of C1-C10-carboxylic acids and inorganic acids, methods and intermediates for their preparation, and their use as herbicides.