MULTI-LAYER ELEMENTS SUITABLE FOR THE PRODUCTION OF PRINTING PLATES AND RELIEF COPIES INCLUDING AN ADHESIVE LAYER CONTAINING ISOCYANATE HARDENED RESIN AND OH-FREE POLYCARBONATE

    公开(公告)号:CA1166884A

    公开(公告)日:1984-05-08

    申请号:CA393501

    申请日:1982-01-04

    Applicant: BASF AG

    Abstract: This invention relates to a multi-layer element, suitable for the production of printing plates and relief plates, which comprises (a) a photosensitive layer of a mixture which is soluble and/or dispersible in aromatic hydrocarbon solvents or aliphatic halohydrocarbon solvents and consists essentially of at least one elastomeric polymer as the binder, at least one photopolymerizable, ethylenically unsaturated monomer compatible with the binder, and a photopolymerization initiator which is activated by actinic light, with or without conventional additives, (b) a sheet-like polyester shaped article as the dimensionally stable base for the photosensitive layer (a) and (c) a thin adhesive layer, between the layer (a) and base (b), consisting of a thermally hardened mixture which is insoluble in the aromatic hydrocarbon solvents or aliphatic halohydrocarbon solvents and contains (c1) from 90 to 40% by weight, based on the sum of (c1) and (c2), of à resin which has been hardened and crosslinked with isocyanate, and which has from about 4 to 20% by weight, based on the non-crosslinked and hardenable resin, of free OH groups before hardening and crosslinking with isocyanate, and (c2) from 10 to 60% by weight, based on the sum of (c1) and (c2), of an OH-free polycarbonate which is compatible with the resin (c1) before the latter is hardened and crosslinked. The above defined multi-layer element possesses improved stability in processing and use.

    PHOTOPOLYMERISABLE COMPOSITIONS
    3.
    发明专利

    公开(公告)号:AU534701B2

    公开(公告)日:1984-02-09

    申请号:AU6348880

    申请日:1980-10-17

    Applicant: BASF AG

    Abstract: Photopolymerizable compositions based on an elastomeric styrene-diene block polymer, one or more photopolymerizable olefinically unsaturated monomers and one or more photopolymerization initiators exhibit improved properties if they contain, as an essential constituent, an elastomeric block copolymer of the general structure A-B-C, where A is a thermoplastic, non-elastomeric polymer block based on styrene compounds and having a second order transition point above +25 DEG C., B is an elastomeric polymer block based on butadiene and/or isoprene and having a second order transition point below -20 DEG C. and C is a polymer block, different from B, having a second order transition point of from -30 DEG C. to +15 DEG C., C being either a homopolymer or copolymer block based on butadiene or isoprene or a random copolymer block based on conjugated dienes and styrene compounds. The photopolymerizable compositions may be used, inter alia, for the production of photo-curable adhesives, resilient and flexible sheet material and, in particular, flexographic relief printing plates.

    4.
    发明专利
    未知

    公开(公告)号:NO141506C

    公开(公告)日:1980-03-26

    申请号:NO743605

    申请日:1974-10-04

    Applicant: BASF AG

    Abstract: The invention relates to relief plates for flexographic printing comprising a relatively soft elastomeric base (U) having a modulus of elasticity of from 10 to 200 kg/cm2 and a thickness of from 0.5 to 6 mm and, firmly bonded thereto, a thin, relatively hard, difficultly soluble intermediate layer Z having a modulus of elasticity of from 1 x 103 to 2.1 x 106 kg/cm2 and a thickness of from 5 to 500 mu and, firmly bonded to said intermediate layer Z, a relief layer P' consisting of a photocrosslinked elastomeric mixture having a modulus of elasticity of from 30 to 2000 kg/cm2 and a thickness of from 200 to 300 mu , the modulus of elasticity of the photocrosslinked relief layer P' being the same as or higher than that of the base U and the neutral surface of the relief plate lying in or near the intermediate layer Z. The invention also relates to photosensitive laminates for the production of such plates.

    6.
    发明专利
    未知

    公开(公告)号:BR9305753A

    公开(公告)日:1997-01-28

    申请号:BR9305753

    申请日:1993-01-08

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP93/00021 Sec. 371 Date Jul. 13, 1994 Sec. 102(e) Date Jul. 13, 1994 PCT Filed Jan. 8, 1993 PCT Pub. No. WO93/14257 PCT Pub. Date Jul. 22, 1993.A continuous process for dyeing yarns with vattable dyes comprises, in continuous yarn dyeing ranges, metering an aqueous dye dispersion into the circulating chemical liquor.

    7.
    发明专利
    未知

    公开(公告)号:DE3686402D1

    公开(公告)日:1992-09-17

    申请号:DE3686402

    申请日:1986-12-06

    Applicant: BASF AG

    Abstract: Ionic polymers with a main chain (A), one or more olefinically unsatd. side groups (B), and one or more cations (C) where (A) is formed from an alkadiene polymer A with a number average mol. wt. Mn of 500 20,000 (B) comprises a structure (I) obtd. by (1() maleinisation and (2) partial esterification or amidification of A', R1,R2 = are different H or alkadiene chains A' ; R3 = a multivalent, linear or branched 1 20C aliphatic hydrocarbon whose chain or branches may be interrupted with O, N or S; X = O, S or NH2; Y = a polar gp.; m = O or 1 5; n = 1 3; Z = methylene, ether, amide or ester; R4 = H or methyl Q = carboxyl or carboxylate; (C) cations of Main Gps. I V, I VIII sub-Gps. or the multifunctional organic amines and/or hydrazine. (D) pref. in addiation one or more residues are pres. obtd. by (1) maleinisation and (2) partial esterification or amidification of A', R5 = an at least one free polar gp. contg. a multivalent, linear or branched 1 25C aliphatic hydrocarbon whose chain and branches may be interrupted with O, N or S, an omega-hydroxy-poly(alklene oxide)-alpha-yl or an omega-alkyl-poly(alkylene oxide)-alpha-yl.

    PHOTOPOLYMERIZABLE COMPOSITIONS AND PHOTO-CURABLE ELEMENTS MADE THEREFROM

    公开(公告)号:CA1152247A

    公开(公告)日:1983-08-16

    申请号:CA362514

    申请日:1980-10-16

    Applicant: BASF AG

    Abstract: O.Z. 0050/034095 PHOTOPOLMYERIZABLE COMPOSITIONS AND PHOTO-CURABLE ELEMENTS MADE THEREFROM Photopolymerizable compositions based on an elastomeric styrene-diene block polymer, one or more photopolymerizable olefinically unsaturated monomers and one or more photopolymerization initiators exhibit improved properties if they contain, as an essential-constituent, an elastomeric block copolymer of the general structure A-B-C, where A is a thermoplastic, non-elastomeric polymer block based on styrene compounds and having a second order transition point above +25.degree.C, B is an elastomeric polymer block based on butadiene and/or isoprene and having a second order transit1on point below -20.degree.C and C is a polymer block, different from B, having a second order transition point of from - 30.degree.C to + 15.degree.C, C being either a homopolymer or copolymer block based on butadiene or isoprene or a random copolymer block based on conjugated dienes and styrene compounds. The photopolymerizable compositions may be used, inter alia, for the production of photo-curable adhesives, resillent and flexible sheet material and, in particular, flexographic relief printing plates.

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