Abstract:
The invention relates to an aqueous impregnating resin solution containing (A) between 77.5 and 99.8 wt. %, in relation to the impregnating resin solution, of aqueous condensates based on melamine and formaldehyde; (B) between 0.1 and 20 wt. %, in relation to the impregnating resin solution, of at least one specific quaternary ammonium compound; and (C) between 0.1 and 2.5 wt. %, in relation to the impregnating resin solution, of an aqueous hardener solution. The invention also relates to an aqueous impregnating resin solution consisting of constituents (A) and (B), and to an aqueous hardener mixture consisting of constituents (B) and (C). The invention further relates to an impregnating resin film containing fibrous substances containing cellulose and impregnated with the aqueous impregnating resin solution, and to the use of the aqueous impregnating resin solution, or impregnating resin film, for the antistatic finishing of coated materials.
Abstract:
The invention relates to an aqueous melamine resin mixture with a resin content in the range of 50 to 70 wt. %, based on the aqueous melamine resin mixture, with melamine and formaldehyde present in the resin in a molar ratio of 1:3 to 1:1 and the resin contains 1 to 10 wt. % polyvalent alcohols, 0 to 8 wt. % caprolactam and 0.5 to 10 wt. % 2-(2-phenoxyethoxy)-ethanol and/or polyethylene glycol with an average molecular mass of 200 to 1500 each based on the aqueous melamine resin mixture. The invention further relates to a method for production of said melamine resin mixtures and use thereof for the impregnation of absorbent support materials and a composite material made from the melamine resin mixture and the support material.
Abstract:
Disclosed is a method for producing alkoxycarbonylamino triazines of formula (I) by reacting diaminotriazines or triaminotriazines with cyclic carbonic acid esters and optional subordinate quantities of acyclic carbonic acid esters in the presence of an alcohol and an alkaline alkanol or alkaline-earth alkanol as a base. In said formula, Y represents hydrogen, C1-C4 alkyl, phenyl that is optionally substituted by C1-C4 alkyl, C1-C4 alkoxy, or halogen, or a radical of formula NR R while R , R , R , R , R , and R independently represent hydrogen or a radical of formula COOX or X, wherein X represents C1-C13 alkyl, the carbon skeleton of which can be interrupted by 1 or 2 oxygen atoms having the function of ether and/or substituted by hydroxy, or C3-C6 alkenyl provided that at least one of the radicals R to R in formula (I) represents COOX, or at least one of the radicals R to R in said formula represents COOX if Y represents NR R .
Abstract:
In a process for preparing alkoxycarbonylaminotriazines, di- or triaminotriazines are reacted with cyclic carbonic esters and optionally with minor amounts of acyclic carbonic esters in the presence of an alcohol and of an alkali metal alkoxide or alkaline earth metal alkoxide as a base.
Abstract:
Aqueous melamine resin mixture (I) comprises a resin content (50-70 wt.% based on (I)) comprising polyvalent alcohols (a) (1-10 wt.%), caprolactam (b) (0-8 wt.%) and 2-(2-phenoxy-ethoxy)-ethanol (c) (0.5-10 wt.%) and/or polyethylene glycol (d) with an average molecular weight of 200-1500, respectively based on (I); where the molar ratio of melamine and formaldehyde present in the resin is 1:3-1:1. Independent claims are also included for the preparation of (I) comprising converting (I) in a pH of 8-10 at 60-160[deg]C; and a composite material obtained by thermal treatment of (I) with a support material.
Abstract:
In a process for preparing alkoxycarbonylaminotriazines, di- or triaminotriazines are reacted with cyclic carbonic esters and optionally with minor amounts of acyclic carbonic esters in the presence of an alcohol and of an alkali metal alkoxide or alkaline earth metal alkoxide as a base.
Abstract:
In a process for preparing alkoxycarbonylaminotriazines, di- or triaminotriazines are reacted with cyclic carbonic esters and optionally with minor amounts of acyclic carbonic esters in the presence of an alcohol and of an alkali metal alkoxide or alkaline earth metal alkoxide as a base.
Abstract:
Production of alkoxycarbonylamino-triazine compounds comprises reaction of a triazine with carboxylic acid esters in the presence of an alcohol and a base. The triazine is reacted with dimethyl carbonate and a 2-13C alcohol whose hydrocarbon group contains ether groups, in the presence of an alkali or alkaline earth methanolate as base. Process for the production of alkoxycarbonylamino-triazine compounds of formula (I) comprises reaction of a triazine of formula (II) with carboxylic acid esters in the presence of an alcohol and a base. The triazine of formula (II) is reacted with dimethyl carbonate and a 2-13C alcohol whose hydrocarbon group contains ether groups, in the presence of an alkali or alkaline earth methanolate as base. Y1 = H, 1-4C alkyl or phenyl, optionally substituted by 1-4C alkyl, alkoxy or halogen, or NR5R6; R1-R6 = H, COOX or X, provided that at least one of R1-R6 is COOX; X = 1-13C alkyl optionally containing 1-2 ether linkages; Y2 = H, 1-4C alkyl, amine or phenyl optionally substituted by 1-4C alkyl, alkoxy or halogen whereby when Y2 is not amine at least one of R1-R4 is H.