公开(公告)号：JP2006169520A

公开(公告)日：2006-06-29

申请号：JP2005351129

申请日：2005-12-05

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフトBASF Aktiengesellschaft

Inventor： BOUILLO NATHALIE ,  ROESSLER GERHARD

IPC: C08F2/00 ,  A61K8/81 ,  A61K47/32 ,  C08F220/10 ,  C08F226/06

CPC classification number: A61K47/32 ,  A61K8/04 ,  A61K8/8182 ,  A61Q19/00 ,  C08F2/00 ,  C08F2/001 ,  C08F2/16 ,  C08F220/18 ,  C08F226/10

Abstract: PROBLEM TO BE SOLVED: To provide a preparation process of an aqueous secondary dispersion liquid for a water insoluble polymer without using a surfactant.
SOLUTION: The preparation process of an aqueous secondary dispersion liquid for a water insoluble polymer is characterized by performing a free radical solution polymerization in a polymerization medium, either an organic/water miscible solvent or a mixture of water and an organic/water miscible solvent, of an ethylenic unsaturated monomer M containing (i) at least one kind of monoethylenic unsaturated monomer M1 with the water solubility of 30 g/l or less at 25°C and 1 bar and (ii) at least one kind of hydrophilic and monoethylenic unsaturated nonionic comonomer M2 with the water solubility of 80 g/l or less at 25°C and 1 bar, replacing the solvent with water, and adding some amount of the monomer M as a monomer composition M' consisting essentially of the monomer M2 before completing the polymerization. The water-soluble polymer dispersion liquid is also provided and the use of the above liquid especially in pharmacology and cosmetics is specified.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供不使用表面活性剂的水不溶性聚合物的水性二次分散液的制备方法。 解决方案：用于水不溶性聚合物的水性二次分散液的制备方法的特征在于在聚合介质中进行自由基溶液聚合，有机/水可混溶的溶剂或水与有机/水的混合物 含有（i）在25℃和1巴水溶性为30g / l以下的至少一种单烯属不饱和单体M1和（ii）至少一种亲水性单体的乙烯性不饱和单体M的混溶溶剂， 和单烯不饱和非离子共聚单体M2，其在25℃和1巴下的水溶解度为80g / l以下，用水代替溶剂，加入一定量的单体M作为主要由单体组成的单体组合物M' M2在完成聚合之前。 还提供了水溶性聚合物分散液，并且规定了特别是在药理学和化妆品中使用上述液体。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：WO2007017452A2

公开(公告)日：2007-02-15

申请号：PCT/EP2006064993

申请日：2006-08-02

Applicant: BASF AG ,  BOUILLO NATHALIE ,  PIEROBON MARIANNA ,  ROESSLER GERHARD ,  DOBRAWA RAINER ,  MEYER-BOEHM KATHRIN ,  LANGE RONALD FRANS MARIA

Inventor： BOUILLO NATHALIE ,  PIEROBON MARIANNA ,  ROESSLER GERHARD ,  DOBRAWA RAINER ,  MEYER-BOEHM KATHRIN ,  LANGE RONALD FRANS MARIA

CPC classification number: C08F226/06

Abstract: The invention relates to the use of copolymers which comprise a) 60 to 99 % by weight of N-vinylcaprolactam; b) 1 to 40 % by weight of at least one monomer b) selected from the group including: b1) C8-C30 alkyl esters of monoethylenically unsaturated C3-C8 carboxylic acids; b2) N-alkyl- or N,N-dialkyl-substituted amides of the acrylic acid or the methacrylic acid with C8 to C30 alkyl groups; b3) the vinyl esters of aliphatically unbranched C8-C30 carboxylic acids; b4) the C8-C30 alkyl-vinyl ethers, as solubilizers for substances that are difficult to dissolve in water.

Abstract translation: 使用包括：a）60〜99重量％的N-乙烯基己内酰胺共聚物; B）1〜40重量 - 的至少一种单体B的％）选自:. b1的选择的）的不饱和C 3 monoethylensich -C 8 - 羧酸C 8 -C 30烷基酯; b2）的N-烷基或N，N-二烷基取代的丙烯酸或甲基丙烯酸与C8至C30烷基的酰胺; B3）的脂肪族无支链C8-C30羧酸的乙烯基酯; B4）的C8-C30烷基乙烯基醚，如增溶剂为水难溶性物质。

公开(公告)号：DE59601732D1

公开(公告)日：1999-05-27

申请号：DE59601732

申请日：1996-08-29

Applicant: BASF AG

Inventor： STEIN STEFAN ,  BOECKH DIETER ,  SCHADE CHRISTIAN DR ,  ROESSLER GERHARD

IPC: C08F2/10 ,  C08F26/00 ,  C08F26/02 ,  C08F26/06 ,  C11D3/00 ,  C11D3/37

Abstract: PCT No. PCT/EP96/03795 Sec. 371 Date Mar. 3, 1998 Sec. 102(e) Date Mar. 3, 1998 PCT Filed Aug. 29, 1996 PCT Pub. No. WO97/09359 PCT Pub. Date Mar. 13, 1997Porous polymers which are in powder form and contain N-vinylimidazole units and which are obtainable by free-radical precipitation polymerization of a) 5-100% by weight of at least one N-vinylimidazole of the formula where R1, R2 and R3 are identical or different and are H, C1-C4-alkyl, N-vinylaxazolidone, N-vinyltriazole, 4-vinylpyridine N-oxide or mixtures of said monomers, b) 0-95% by weight of other copolymerizable monoethylenically unsaturated monomers and c) 0-50% by weight of at least one monomer with at least two non-conjugated ethylenic double bonds in aqueous solution which contains 0.5-30% by weight of at least one electrolyte and, based on the monomers employed, 0.5-80% by weight of at least one surfactant, a process of the preparation thereof, and the use of the porous polymers.