公开(公告)号：ES2160868T3

公开(公告)日：2001-11-16

申请号：ES97108000

申请日：1997-05-16

Applicant: BASF AG

Inventor： ROSCH JOACHIM DR ,  WUNSCH JOSEF DR

IPC: C08F2/14 ,  C08F2/08 ,  C08F2/20 ,  C08F4/623 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/68 ,  C08F8/00 ,  C08F8/08 ,  C08F10/00 ,  C08F10/02 ,  C08F10/06 ,  C08F32/00 ,  C08F110/06

Abstract: A process for the production of crystalline polymers of ethylene, propylene and/or cyclic olefin, comprises polymerisation in dispersion in presence of metallocene catalyst systems.

公开(公告)号：ES2135157T3

公开(公告)日：1999-10-16

申请号：ES96120745

申请日：1996-12-23

Applicant: BASF AG

Inventor： ROSCH JOACHIM DR

IPC: C07B61/00 ,  C08F4/629 ,  C07C2/32 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C10G50/00

Abstract: Catalyst systems for the polymerisation of olefinically unsaturated compounds, containing (A) a metallocene complex of a Sub-Group 4, 5 or 6 metal, (B) a metallocenium ion-forming compound and (C) a sterically hindered organic Lewis base. Also claimed is a process for the production of polymers by linking at least two unsaturated monomers at 0-450 degrees C and 0.1-500000 kPa in presence of a catalyst system as above. Preferably component (B) is a 1-10C aluminoxane, and component (C) is a sterically hindered hydroxyaryl or aryloxyaluminium compound, preferably a phenol, naphthol or hydroxyanthracene derivative in which the ring positions directly adjacent to the hydroxy or aluminoxy groups are substituted with bulky groups.

公开(公告)号：ES2160869T3

公开(公告)日：2001-11-16

申请号：ES97108001

申请日：1997-05-16

Applicant: BASF AG

Inventor： ROSCH JOACHIM DR ,  BIDELL WOLFGANG DR ,  LANGHAUSER FRANZ DR

IPC: C08F2/38 ,  C08F2/40 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/625 ,  C08F4/64 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/10 ,  C08F110/02 ,  C08F110/06

Abstract: A process for the production of polymers of 2-12C alkenes at -50 to 300 degrees C and 0.5-3000 bar in presence of a catalyst system, with the addition of a compound of formula H-M )R (I); where M = B, Al, Ga, In or Tl; R , R = H, 1-10C alkyl, 6-15C aryl, or alkaryl or aralkyl with a 1-10C alkyl and a 6-20C aryl group, or 5- to 7-membered cycloalkyl (optionally substituted with 1-10C alkyl); or R + R may form a 4-15C cyclic group. Preferably R and R together form part of a 4-15C bicyclic group; M = boron. The catalyst system contains (A) a metallocene complex and (B) a metallocenium ion-forming compound. A metal compound of formula M )r(R )s(R )t (IV) may also be added; M = alkali or alkaline earth metal, or a Sub-Group III metal, i.e. B, Al, Ga, In or Tl; R = 1-10C alkyl, 6-15C aryl, or alkaryl or aralkyl with 1-10C alkyl and 6-20C aryl groups; R , R = as for R , or also halogen or 1-10C alkoxy; r = 1-3; s, t = 0-2; r + s + t = the valency of M .