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公开(公告)号:DE2331773A1
公开(公告)日:1975-01-23
申请号:DE2331773
申请日:1973-06-22
Applicant: BASF AG
Abstract: Polyolefin moulding compsns. contg. (1) a thermoplastic, synthetic, high-polymer polyolefin and (2) 0.01 to 3 wt% (w.r.t. the polyolefin) of >=1 sensitisers of formula: cyclopentadienyl-Mn(CO)3, cyclopentadienyl-Co(CO)2, cyclopentadienyl-V(CO)4, cyclopentadienyl-Cr(CO)3 2, cyclopentadienyl-Mo(CO)3 2, cyclopentadienyl-W(CO)3 2, and/or cyclopentadienyl-Ni(CO)2 2. The high polymer olefins are polymers of e.g. ethylene or propylene from which disposable prods., e.g. packing foil, are produced in large quantities. Such polymers include polyethylene, polypropylene and polybutylene-(1). The polymers may also contain expanding agents for forming foamed prods., lubricating agents, pigments, dyes. The sensitisers may be used singly or as mixts. of >2. These additives may be incorporated into the polyolefin compsns. by conventional methods, e.g. using rolls or extruders. The compsns. can be moulded using conventional appts. The sensitisers accelerate the decompsn. of the polymer prods. under the influence of light without effecting other props. adversely.
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公开(公告)号:DE3102135A1
公开(公告)日:1982-08-19
申请号:DE3102135
申请日:1981-01-23
Applicant: BASF AG
Abstract: For work-up and regeneration of aqueous solutions containing polymers containing ionic groups and possibly further substances in dissolved form, as produced during the washing of exposed photosensitive recording materials for optical information fixing, small amounts of ionogenic organic flocculation auxiliaries are added to the aqueous solutions, and the resultant precipitate is separated off.
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公开(公告)号:DE2545957A1
公开(公告)日:1977-04-21
申请号:DE2545957
申请日:1975-10-14
Applicant: BASF AG
Inventor: WALLBILLICH GUENTER DIPL CHEM , SAENGER DIETRICH DIPL CHEM DR , BRONSTERT BERND DIPL CHEM DR
Abstract: Light-sensitive material for positive-working photoresists and for the prodn. of printing plates is based on a water-insol. polycondensate (I) of phenol(s) with an aldehyde and contains o-quinone-diazide-sulphonyl gps. In addn. to condensed units of phenolic cpd(s). (II), (I) also contains condensed units of phenolic cpd(s). (III) in which the OH or NH2 gps. are (partly) reacted to o-quinone-diazide-sulphonic ester or amide gps. which is strongly absorbing in the 300-400 nm wavelength range and pref. has a molar extinction coefft. epsilon >103 in that range. The material has higher sensitivity and gives faster printing plates than compsns. contg. naphthoquinone-1,2-diazide-5-sulphonic ester. It adheres well to substrates, has good film-forming properties and can be produced easily and cheaply. Pref. (I) has a mol. wt. of 1000-10000 and contains a (III) unit to every 2-15 phenolic units. In an example a light-sensitive phenolic resin was prepd. from a o-quinonediazide-sulphonic diester of 2,2',4,4'-tetrahydroxybenzophenone monoacetate, bisphenol A and HCHO.
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公开(公告)号:DE3143106A1
公开(公告)日:1983-05-11
申请号:DE3143106
申请日:1981-10-30
Applicant: BASF AG
Abstract: In a process and device for the regeneration of aqueous washing-out solutions and water-developable photosensitive recording materials, the washing-out solution (2) loaded with washed-out material is continuously purified by ultrafiltration, the filtrate (7) is recycled as washing-out solution to the developing machine (1) for re-use and the concentrate (8) with the washed-out material is added to the washing-out solution (2). The following arrangement can be used for carrying out the process: The overflow branch of the developing machine (1) is connected via an interposed tank (3), a pump (4) and a prefilter (5) to the ultrafiltration unit (6), while the filtrate outlet branch is connected to the developing machine (1) and the concentrate outlet branch is connected to the tank. This process ensures that the environment is not polluted by spent washing-out solution.
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公开(公告)号:DE2922746A1
公开(公告)日:1980-12-11
申请号:DE2922746
申请日:1979-06-05
Applicant: BASF AG
Abstract: A positive working photosensitive film resist material suitable for multiple image-wise exposure comprises, on a dimensionally stable base film, a photosensitive coating which contains (a) a polymer which possesses aromatic or hetero-aromatic o-nitrocarbinol ester groups (for example o-nitrobenzyl acrylate units) and which can be washed out, after exposure, with an alkaline solvent, and (b) a transparent plasticizer compatible with (a). The product may be used as photopolymer dry film resist material in the production of electrical conductor boards, chemically milled fine-line parts, and identification plates.
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公开(公告)号:DE2545697A1
公开(公告)日:1977-04-21
申请号:DE2545697
申请日:1975-10-11
Applicant: BASF AG
Inventor: WALLBILLICH GUENTER DIPL CHEM , SAENGER DIETRICH DIPL CHEM DR , BRONSTERT BERND DIPL CHEM DR
Abstract: The material for positively acting photographic coatings is based on polymes having a -C-C- chain carrying O-quinonediazide-sulphonyl side-gps. These are introduced by means of a cpd. (I) having >2-OH and/or -NH2 gps. which absorbs strongly in the wavelength range of 300-400 nm and pref. has a molar extinction coefft. epsilon >103. (I) is partially converted to an o-quinonediazide sulphonic acid ester and/or amide by reaction of some of the -OH and/or -NH2 gps. The resulting prod. (II) still having >=1 -OH or -NH2 gp. is then combined with the reactive gps. of a polymer. The material has improved light-sensitivity and gives mechanically stable printing plates at an increased rate. In an example a light-sensitive polymer was obtd. by reacting 2,2',4,4'-tetrahydroxybenzophenone and 2,1,5-diazonaphthaquinone-sulphonyl chloride with successive addns. of NEt3, acetic anhydride, NEt3, styrene-maleic anhydride copolymer (5% in acetone) and finally more NEt3.
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公开(公告)号:DE2331676A1
公开(公告)日:1975-01-16
申请号:DE2331676
申请日:1973-06-22
Applicant: BASF AG
Abstract: Environmental contamination by discarded plastic packing materials is diminished by their accelerated decomposition sensitised by inclusion of 0.01-3 wt. % of di(cyclopentadienyl) iron (ferrocene). Materials which can be modified by this method include films, foams, horticultural mulch foils, etc., made from polyethylene, polypropylene and polybutene-(1) opt. with usual additives, such as lubricants, pigments, dyes, etc.
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公开(公告)号:DE2309372A1
公开(公告)日:1974-09-05
申请号:DE2309372
申请日:1973-02-24
Applicant: BASF AG
Inventor: IMMEL GUENTHER DIPL CHEM DR , KRAUCH CARL HEINRICH DIPL CHEM , DRUSCHKE WOLFGANG DIPL CHEM DR , SAENGER DIETRICH DIPL CHEM DR
IPC: C08F20/00 , C08F20/34 , C09J7/02 , C09J133/04 , C08F3/64
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公开(公告)号:SE7402192L
公开(公告)日:1974-08-26
申请号:SE7402192
申请日:1974-02-19
Applicant: BASF AG
Inventor: IMMEL GUENTHER DIPL CHEM DR , KRAUCH CARL HEINRICH DIPL CHEM , DRUSCHKE WOLFGANG DIPL CHEM DR , SAENGER DIETRICH DIPL CHEM DR
IPC: C08F20/00 , C08F20/34 , C09J7/02 , C09J133/04
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