公开(公告)号：DE3114341A1

公开(公告)日：1982-11-11

申请号：DE3114341

申请日：1981-04-09

Applicant: BASF AG

Inventor： HENNE ANDREAS DIPL CHEM DR ,  HESSE ANTON DIPL CHEM DR ,  JACOBI MANFRED DIPL CHEM DR ,  WALLBILLICH GUENTER DIPL CHEM ,  BRONSTERT BERND DIPL CHEM DR

IPC: C08K5/00 ,  C07F9/30 ,  C07F9/36 ,  C07F9/38 ,  C07F9/40 ,  C07F9/58 ,  C08F2/00 ,  C08F2/48 ,  C08F2/50 ,  C08K5/49 ,  C08K5/51 ,  C08K5/53 ,  C08K5/5313 ,  C08K5/5398 ,  C08L33/00 ,  C08L33/02 ,  C08L67/00 ,  G03F1/88 ,  G03F7/029 ,  C08K5/50 ,  C08J3/24 ,  C09D7/12 ,  C09D11/10 ,  G03C1/68

Abstract: Acylphosphine compounds of the formula I where X is oxygen, sulfur or an electron pair, R1 is R4 or OR4, R2 is -OM, where M is a monovalent cation, R3 is aryl which is substituted at least at the two positions ortho to the carbonyl group, and R4 is hydrogen, alkyl or aryl, are very effective photoinitiators for photopolymerizable materials, such as coating compositions, finishes, printing inks, unsaturated polyesters, recording media and preferably aqueous polymer dispersions or solutions.

公开(公告)号：DE2644986A1

公开(公告)日：1978-04-13

申请号：DE2644986

申请日：1976-10-06

Applicant: BASF AG

Inventor： BRONSTERT BERND DIPL CHEM DR ,  LENZ WERNER DIPL CHEM DR ,  HARTMANN HEINRICH DIPL CHEM DR ,  WERTHER HEINZ-ULRICH DIPL CHEM ,  ZUERGER MANFRED ING GRAD

IPC: G03F7/032 ,  C08F2/50 ,  C08F283/04 ,  C08L77/00 ,  G03F7/004 ,  G03F7/027 ,  G03F7/02 ,  G03C1/68

Abstract: Photopolymerizable compositions for the manufacture of relief printing plates, especially relief plates for making mats, comprising an alcohol-soluble linear polyamide, a photoinitiator and a mixture of (a) a diether or triether obtained from 1 mole of an aliphatic diol or triol and from 2 to 3 moles of N-hydroxymethylacrylamide or N-hydroxymethylmethacrylamide and (b) an unsaturated ester-urethane obtained from 1 mole of toluylene diisocyanate and 2 moles of a hydroxyalkyl acrylate or methacrylate, (a) and (b) being mixed in specific ratios.

公开(公告)号：DE2759163A1

公开(公告)日：1979-07-12

申请号：DE2759163

申请日：1977-12-31

Applicant: BASF AG

Inventor： BRONSTERT BERND DIPL CHEM DR ,  KUESTERS WERNER DIPL CHEM DR ,  JUN MONG-JON DIPL CHEM DR ,  WALLBILLICH GUENTER DIPL CHEM

IPC: C08F2/48 ,  G03F7/031 ,  G03F7/10

Abstract: The compsns. contain (a) >=1 cpd. of low mol. wt. and contg. >=1 unsatd. photopolymerisable double bond; (b) >=1 compatible organic polymeric binder; (c) a photo-initiator; and (d) 0.001-0.1 wt. % of an etherified thioanthraquinone cpd. of formula (I):- in which R is 1-12C alkyl, 1-8C alkyl substd. by an opt. etherified and/or esterified OH gp. and/or an alkoxycarbonyl gp., or an opt. substd. phenyl gp. Pref. cpds. (I) are propyl-, n-butyl-, and isobutylthioanthraquinones, and esp. 2-butylthio-2-anthraquinone (II). Presence of the (I) in known photopolymerisable compsns. reduces undesired polymerisation of the compsn. in the shadow of fine opaque image elements during exposure in contact with a negative, thus giving improved image clarity. The presence of the (I) does not reduce the light sensitivity or exposure latitude of the material.

公开(公告)号：DE2722421A1

公开(公告)日：1978-11-23

申请号：DE2722421

申请日：1977-05-18

Applicant: BASF AG

Inventor： BRONSTERT BERND DIPL CHEM DR ,  KUESTERS WERNER DIPL CHEM DR ,  JUN MONG-JON DIPL CHEM DR ,  WALLBILLICH GUENTER DIPL CHEM

IPC: G03F7/031 ,  G03F7/10 ,  C08L77/00

Abstract: The compsn. is based on a mixt. of low-mol. (poly)olefinic cpd(s). (I) and compatible organic polymeric binder(s) (II) contg. a photoinitiator. The novelty is that the compsn. contains 0.001-0.1 wt. % homogeneously dispersed 1-12C-alkyl-thio-anthraquinone (III) and pref. also 0.01-1 wt. % of an organic tert. amine (IV) or an aromatic alpha-ketocarboxylic acid (V) or its 1-18 C-alkyl ester or 0.02-2 wt. % of an organic N-nitrosohydroxylamine salt (VI). The relief structure is improved by reducing undesired polymerisable in the complete shadow of fine opaque image elements, with simultaneous favourable exposure latitude and without impairing the speed.

公开(公告)号：DE3045516A1

公开(公告)日：1982-07-08

申请号：DE3045516

申请日：1980-12-03

Applicant: BASF AG

Inventor： BRONSTERT BERND DIPL CHEM DR ,  HAHN HERBERT DIPL CHEM DR ,  HOFFMANN GERHARD DIPL CHEM DR ,  LENZ WERNER DIPL CHEM DR

IPC: G03F7/09 ,  B41N1/06 ,  B41N1/12 ,  G03F7/105 ,  G03F7/11 ,  G03F7/16 ,  G03C1/76 ,  G03C1/94 ,  G03C1/68 ,  G03F7/26

Abstract: A photosensitive multi-layer material comprising a base and a photosensitive layer which has a polyamide binder and is soluble or dispersible in an alcoholic solvent contains two layers between the base and the photosensitive layer, namely (a) an adhesion-promoting layer, adjacent to the base, which is derived from a polyurethane binder, prepared by reacting a hydroxyl-containing epoxy resin and a polyisocyanate, and a pigment combination in which a white zinc sulfide pigment is the essential constituent, and (b) an adhesive layer, adjacent to the photosensitive layer, which consists of a baked mixture of an alcohol-soluble copolyamide and a melamine-formaldehyde resin.

公开(公告)号：DE3045515A1

公开(公告)日：1982-07-08

申请号：DE3045515

申请日：1980-12-03

Applicant: BASF AG

Inventor： HOFFMANN GERHARD DIPL CHEM DR ,  BRONSTERT BERND DIPL CHEM DR ,  HAHN HERBERT DIPL CHEM DR ,  JUN MONG-JON DIPL CHEM DR

IPC: B41N1/06 ,  B41N1/12 ,  G03F7/09 ,  G03F7/11 ,  G03F7/16 ,  G03C1/80 ,  G03C1/68 ,  G03F7/26

Abstract: A photosensitive multi-layer material comprising a base, which may or may not be provided with an adhesion-promoting layer, and a photopolymerizable layer, consisting of a mixture of a photoinitiator, a binder and a photopolymerizable monomer, possesses, between the base and the photopolymerizable layer, an adhesive layer of a hardened mixture of a binder and an etherified melamine-formaldehyde condensate, hardenable at 60 DEG -120 DEG C.

公开(公告)号：DE2545957A1

公开(公告)日：1977-04-21

申请号：DE2545957

申请日：1975-10-14

Applicant: BASF AG

Inventor： WALLBILLICH GUENTER DIPL CHEM ,  SAENGER DIETRICH DIPL CHEM DR ,  BRONSTERT BERND DIPL CHEM DR

IPC: G03F7/023 ,  G03F7/10

Abstract: Light-sensitive material for positive-working photoresists and for the prodn. of printing plates is based on a water-insol. polycondensate (I) of phenol(s) with an aldehyde and contains o-quinone-diazide-sulphonyl gps. In addn. to condensed units of phenolic cpd(s). (II), (I) also contains condensed units of phenolic cpd(s). (III) in which the OH or NH2 gps. are (partly) reacted to o-quinone-diazide-sulphonic ester or amide gps. which is strongly absorbing in the 300-400 nm wavelength range and pref. has a molar extinction coefft. epsilon >103 in that range. The material has higher sensitivity and gives faster printing plates than compsns. contg. naphthoquinone-1,2-diazide-5-sulphonic ester. It adheres well to substrates, has good film-forming properties and can be produced easily and cheaply. Pref. (I) has a mol. wt. of 1000-10000 and contains a (III) unit to every 2-15 phenolic units. In an example a light-sensitive phenolic resin was prepd. from a o-quinonediazide-sulphonic diester of 2,2',4,4'-tetrahydroxybenzophenone monoacetate, bisphenol A and HCHO.

公开(公告)号：DE2909992A1

公开(公告)日：1980-10-02

申请号：DE2909992

申请日：1979-03-14

Applicant: BASF AG

Inventor： LECHTKEN PETER DIPL CHEM DR ,  BRONSTERT BERND DIPL CHEM DR ,  HOFFMANN GERHARD DIPL CHEM DR ,  VYVIAL RUDOLF DIPL ING ,  LYNCH JOHN DIPL CHEM DR

IPC: C07F9/32 ,  C07F9/40 ,  C07F9/46 ,  C07F9/48 ,  C07F9/53 ,  C08F2/48 ,  C08F2/50 ,  C08F283/00 ,  C08F291/18 ,  G03F7/029 ,  G03C1/68

Abstract: A photopolymerizable recording composition which comprises a mixture, containing a photoinitiator, of (a) a photopolymerizable olefinically unsaturated monomer and (b) an organic polymeric binder, wherein the photoinitiator is an acylphosphine oxide compound of the formula R1R2PO-CO-R3, where R1 and R2 are certain organic radicals and R3 is tert.-alkyl or a cyclic radical with two substituents in the ortho-position to the carbonyl group. The recording compositions have a high reactivity when irradiated with UV light and are used in particular for the preparation of printing plates, relief plates and photo-resists.

公开(公告)号：DE2720560A1

公开(公告)日：1978-11-09

申请号：DE2720560

申请日：1977-05-07

Applicant: BASF AG

Inventor： HOFFMANN GERHARD DIPL CHEM DR ,  KLEUSER DIETER DIPL CHEM DR ,  BRONSTERT BERND DIPL CHEM DR

IPC: G03C1/00 ,  C08F2/00 ,  C08F2/50 ,  G03F7/004 ,  G03F7/031 ,  C08F283/00 ,  G03F1/02 ,  G03C1/68

Abstract: Photopolymerizable compositions for the production of printing plates and relief plates, consisting essentially of a photoinitiator-containing mixture of olefinically unsaturated photopolymerizable compounds with polymeric binders, contain up to 1% by weight of a compound having the structural element of anthrone, e.g. bianthrone and 9,9'-bianthryl, which results in an improved relief image in the production of relief plates.

公开(公告)号：DE2545697A1

公开(公告)日：1977-04-21

申请号：DE2545697

申请日：1975-10-11

Applicant: BASF AG

Inventor： WALLBILLICH GUENTER DIPL CHEM ,  SAENGER DIETRICH DIPL CHEM DR ,  BRONSTERT BERND DIPL CHEM DR

IPC: G03F7/023 ,  G03F7/10

Abstract: The material for positively acting photographic coatings is based on polymes having a -C-C- chain carrying O-quinonediazide-sulphonyl side-gps. These are introduced by means of a cpd. (I) having >2-OH and/or -NH2 gps. which absorbs strongly in the wavelength range of 300-400 nm and pref. has a molar extinction coefft. epsilon >103. (I) is partially converted to an o-quinonediazide sulphonic acid ester and/or amide by reaction of some of the -OH and/or -NH2 gps. The resulting prod. (II) still having >=1 -OH or -NH2 gp. is then combined with the reactive gps. of a polymer. The material has improved light-sensitivity and gives mechanically stable printing plates at an increased rate. In an example a light-sensitive polymer was obtd. by reacting 2,2',4,4'-tetrahydroxybenzophenone and 2,1,5-diazonaphthaquinone-sulphonyl chloride with successive addns. of NEt3, acetic anhydride, NEt3, styrene-maleic anhydride copolymer (5% in acetone) and finally more NEt3.