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公开(公告)号：DE2500309A1
公开(公告)日：1976-07-08
申请号：DE2500309
申请日：1975-01-07
Applicant: BASF AG
Inventor： MERGER FRANZ , SANDER HANS DIPL CHEM DR , HARTMANN HEINRICH DIPL CHEM DR , WOERNER FRANK PETER DIPL CHEM
IPC: C08G18/62 , C08G18/65 , C09D125/02 , C09D133/06 , C09D133/14 , C09D3/80 , C09D3/72
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公开(公告)号：DE3148051A1
公开(公告)日：1983-06-09
申请号：DE3148051
申请日：1981-12-04
Applicant: BASF AG
IPC: C08F2/04 , C08L33/06 , C08L61/20 , C09D133/06 , C09D3/80
Abstract: Baking finishes having a high solids content contain, as the binder, a copolymer of one or more mono-acrylate or monomethacrylate of an alkanediol, an ester of acrylic or methacrylic acid whose homopolymer has a glass transition temperature of below -40 DEG C., an ester of acrylic acid or methacrylic acid whose homopolymer has a glass transition temperature of above 35 DEG C. and acrylic acid or methacrylic acid, which copolymer has a Fikentscher K value of from 13 to 17 and may or may not be used in combination with conventional aminoplast precondensates having a crosslinking action. These baking finishes are particularly useful as binders for automotive finishes.
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公开(公告)号：DE2750123A1
公开(公告)日：1979-05-10
申请号：DE2750123
申请日：1977-11-09
Applicant: BASF AG
IPC: C08G59/68 , C09D163/00 , C08K5/34 , C08L63/00 , C08L67/00
Abstract: A heat-hardenable, liq., one-component compsn. contains a mixt. of (a) a copolymer or polyester contg. COOH gps., and (b) an epoxide resin, with (c) a pyridinium salt as hardening catalyst. Compsn. has improved storage stability, and gives coatings with very good mechanical properties. The compsn. is esp. used as a coating on household equipment and as a filler in the automobile industry.
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公开(公告)号：DE2500310A1
公开(公告)日：1976-07-08
申请号：DE2500310
申请日：1975-01-07
Applicant: BASF AG
Inventor： MERGER FRANZ DIPL CHEM DR , SANDER HANS DIPL CHEM DR , HARTMANN HEINRICH DIPL CHEM DR , FOUQUET FERD DIPL CHEM DR
Abstract: Butanediol-1,3)-1-mono-(3'-hydroxybutyrates) of formula (I) are new R2-CH2-CHOH-CHR'-COOCH2-CHR'--CHOH-CH2R2 (I) (where individual gps. R' and R2 are opt. same and denote H or an aliphatic gp). (I) are prepd. by reaction of butanediol-(1,3)-3-mono-(3'-hydroxybutyrates) of formula R2-CH2-CHOH-CHR'-COO-CH(CH2R2)-CHR'-CH2OH (Ii) at 120-220 degrees C. (I) are starting materials for prepn. of polyesters, esp. those stable to saponification polyurethanes, plastics and plasticisers. (I) can be reacted with fumaric acid or maleic anhydride for 8 hrs. at 180-200 degrees C to form polyesters which copolymerise with 30 wt.% styrene to a on-saponificaable, water-repellant resin, useful as swimming-pool lacquers, outdoor paints, weather-proof wood finishes. (I) can also react in 1:2 mol ratio with (meth)acrylic acid to form bi-functional monomers for synthesis of radiation hardenable lacquers, e.g. on wood, plastics, paper, metal, in combination with unsatd. polymers. (I) can form cross-linkable coatings which can be sprayed on and have high gloss.
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Patent Agency Ranking
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公开(公告)号：DE2500308A1
公开(公告)日：1976-07-15
申请号：DE2500308
申请日：1975-01-07
Applicant: BASF AG
Inventor： MERGER FRANZ DIPL CHEM DR , SANDER HANS DIPL CHEM DR , HARTMANN HEINRICH DIPL CHEM DR , WOERNER FRANK PETER DIPL CHEM
Abstract: Crosslinkable coating compsn. contains (A) an ester diol of formula (HO-CHR-CR2R3-COO-CHR4-CR5R6-CHR7-OH (I) (where R1 to R7 can be H or 1-4C alkyl and R2 with R3 and R5 an dR6 can also be linked to a 5-8C cycloalkyl ring, provided gps. R1 to R3 and R4 to R7 each contain 2 alkyl gps.), having mol. wt. 204-500, or a mixt. of (I), provided component (A) is liquid below 35 degrees C, and (b) a polyisocyanate. Proportions of (A) and (B) are such that equiv. ratio -NCO:OH gps. is 0.7:1 to 1.3:1. The compsns are used for coating metals, wood or plastic substrates, e.g. by spraying, brushing on, immersion or airless spraing. Compsns. have low viscosity, good sprayability and form hard, glossy coatings.
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公开(公告)号：DE2500312A1
公开(公告)日：1976-07-08
申请号：DE2500312
申请日：1975-01-07
Applicant: BASF AG
Inventor： MERGER FRANZ DIPL CHEM DR , SANDER HANS DIPL CHEM DR , HARTMANN HEINRICH DIPL CHEM DR , FOUQUET GERD DIPL CHEM DR
Abstract: Butanediol-(1,3-3-mono-(3'-hydroxybutyrates) have formula R2-CH2-CHOH-CHR'-COO-CH(CH2R2)-CHR'-CH2OH (I) (where R' and R2 are opt. same and denote an aliphatic gp. or H). (I) are prepd. by reacting 3-hydroxy-butanols of formual R2-CH2-CHOH-CHR'-CHO (II) for >=2 hrs. at 40-150 (40-130) esp. 90-130 degrees C. (I) are starting materials for prepn. of polyesters, esp. those partic. stable to saponification, polyurethanes, plastics and plasticisers (I) react with fumaric acid or maleic anhydride for 8 hrs. at 180-200 degrees C to form polyesters which copolymerise with 30 wt. % styrene to non-saponifiable, water-repellant resins, suitable as swimming-pool lacquers, outdoor paints and weather-resistant wood-varnishes. (I) can be esterified, in 1:2 mol. ratio with (meth) acrylic acid to form bifunctional monomers for synthesis of radiation-hardenable lacquers, e.g. on wood, plastics, paper, metals, in combination with unsatd. polymers e.g. epoxides, polyesters, (I) can also form cross-linkable coating compsns.
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9.发明专利
公开(公告)号：DE2728459A1
公开(公告)日：1979-01-18
申请号：DE2728459
申请日：1977-06-24
Applicant: BASF AG
IPC: C08L63/00 , C09D125/14 , C09D133/02 , C09D133/06 , C09D163/00 , C09D3/81 , C09D3/58
Abstract: Low solvent stoving enamels comprise (A) an acrylate resin; (B) an epoxide resin; (C) a mixt. of organic solvents, and opt. pigments, catalysts and other additives. (A) is a copolymer, contg. in polymeric linking, 10-35% carboxylic acids contg. alpha:beta-ethylenic links and having a Fikentscher K value of 15 and an acid value of 70-250 mg. KOH/g. (B) contains >=2 oxirane gps/mol., (C) comprises 20-80% of a solvent boiling at 100-280 degrees C and dielectric constant of 2-4.99, and 80-20% of a solvent boiling at 80-200 degrees C and dielectric constant 5-27. The wt. ratio of (A)/(B) is 5 to 27 and the wt. ratio of (A+B)/(C) is 7/3 to 5/5. Used for painting household appliances and as undercoating layers for cars. They may be applied from prepns. contg. very little solvent. In an example, prepns. contg. >70% esp. 75-85% dry wt., may be sprayed onto vertical surfaces where they flow out well and on stoving form coatings having good mechanical props, resistance to chemical agents and solvents and showing good protection against corrosion. They may also be applied onto vertical surfaces to form layers 40 um thick, without running and without the presence of thixotropic agents.
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公开(公告)号：DE2539104A1
公开(公告)日：1977-03-10
申请号：DE2539104
申请日：1975-09-03
Applicant: BASF AG
IPC: C08G18/62 , C08G18/78 , C08G18/79 , C09D175/04 , C09D3/72
Abstract: Baking finishes of low solvent content, which have a viscosity of from 20 to 300 DIN seconds, measured in a DIN cup No. 4, and comprise from 40 to 85% by weight of hydroxyl-containing polymers, from 10 to 55% by weight of amine/formaldehyde resins and from 5 to 35% by weight of polyisocyanates, and may also contain up to 15% by weight of monohydric or dihydric alcohols, up to 35% by weight of solvents, up to 65% by weight of pigments and fillers and up to 3% by weight of crosslinking catalysts. The finishes are particularly suitable for coating automotive components.
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