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公开(公告)号：DE3049551A1
公开(公告)日：1982-07-29
申请号：DE3049551
申请日：1980-12-31
Applicant: BASF AG
Inventor： NAARMANN HERBERT DIPL CHEM DR , NAEGELE DIETER DIPL CHEM DR , PENZIEN KLAUS DIPL CHEM DR , SCHLAG JOHANNES DIPL PHYS DR , KIENER VOLKER DIPL CHEM DR , BOEHN HUGO
IPC: C08G73/00 , C08G61/12 , C08G73/06 , C08J5/18 , H01B1/12 , H01L51/30 , H01M4/60 , C25B3/02 , C08G73/20 , B01J31/06 , C08K5/34 , B05D5/12 , H01M4/00 , H01B1/14
Abstract: Electrically conductive complexes of polypyrroles with nitroaromatic anions are prepared by polymerizing pyrrole, an N-alkylpyrrole and/or an N-arylpyrrole by anodic oxidation in a polar solvent, in the presence of a salt of an acidic nitroaromatic compound.
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公开(公告)号：DE3000379A1
公开(公告)日：1981-07-09
申请号：DE3000379
申请日：1980-01-07
Applicant: BASF AG
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公开(公告)号：DE3215970A1
公开(公告)日：1983-03-03
申请号：DE3215970
申请日：1982-04-29
Applicant: BASF AG
Inventor： NAARMANN HERBERT DIPL CHEM DR , MUENCH VOLKER DIPL CHEM DR , PENZIEN KLAUS DIPL CHEM DR , SCHLAG JOHANNES DIPL PHYS DR
IPC: C08K5/23 , C08L49/00 , H01B1/12 , C08K5/54 , C08K5/55 , C08K5/59 , C08L65/02 , G11C11/21 , H01B1/24 , H01L23/52 , H01L31/18 , H05F1/02
Abstract: The invention relates to a process for the preparation of stable, electroconductive polymers having electrical conductivity values of greater than 10 S/cm from polyphenylenes, heteropolyphenylenes or polyacetylenes, in which from 0.1 to 75 per cent by weight of an organic aromatic diazofluoro-metal compound of the formula: Ar-(X)y in which Ar is an optionally substituted aromatic radical and X is N=N -Me-Fn in which Me is B, Ge, Si, P, As or Sb, n is 4, 5 or 6, and y is 1, 2 or 3, are added to the polymers in the absence of oxygen. In particular, a diazofluorometallate compound of the formula (I): in which X is as defined above, and R is H, alkyl, Cl, Br, I, F, OH, NO2, N(CH3)2, N(C2H5)2, C6H5, COOC2H5 or COOH, and R , R and R are R or X, is used. The electroconductive polymers can be used in electrical engineering for the production of solar cells, for the conversion and fixation of radiation, for the production of electrical and magnetic switches and electrical storage systems and for the antistatic finishing of plastics.
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公开(公告)号：DE3034988A1
公开(公告)日：1982-04-29
申请号：DE3034988
申请日：1980-09-17
Applicant: BASF AG
Inventor： NAARMANN HERBERT DIPL CHEM DR , NAEGELE DIETER DIPL CHEM DR , PENZIEN KLAUS DIPL CHEM DR , SCHLAG JOHANNES DIPL PHYS DR
IPC: C08G65/00 , C08G65/48 , C08G73/00 , C08G75/00 , C08G75/0209 , C08G75/0286 , C08G75/20 , C08G79/00 , C08G85/00 , C09K3/16 , C25B3/23 , H01B1/12 , C08G61/12 , C08L81/00 , C08L79/08 , C08L71/04 , C08J7/12
Abstract: 1. A process for the preparation of an electrically conductive polyaromatic having an electrical conductivity greater than 10**-2 S/cm, wherein polyaromatics of the formulae I and II see diagramm : EP0047903,P7,F4 see diagramm : EP0047903,P7,F5 where X is SO2 , S, O, NH, Se or see diagramm : EP0047903,P7,F6 K is a fused aromatic, eg. naphtalene, anthracene, perylene, coronene, biphenyl or terphenyl, R is CH3 , phenyl or cyclohexyl, m is from 1 to 5, preferably 1 or 2, and n is from 5 to 1,000, preferably from 5 to 500, are oxidized electrochemically, preferably anodically, in the presence of a conductive salt.
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Patent Agency Ranking
公开(公告)号：DE2948454A1
公开(公告)日：1981-06-11
申请号：DE2948454
申请日：1979-12-01
Applicant: BASF AG
Inventor： NAARMANN HERBERT DIPL CHEM DR , NAEGELE DIETER DIPL CHEM DR , PENZIEN KLAUS DIPL CHEM DR , SCHLAG JOHANNES DIPL PHYS DR
Abstract: A process for the preparation of electrically conductive polyaromatics having conductivities greater than 10-2S/cm., wherein from 0.5 to 5% by weight, based on the polyaromatics, of sodium, potassium, rubidium, cesium or their amides, preferably in tetrahydrofuran, dimethoxyglycol, anthracene, naphthalene or 2-methylstyrene, are incorporated into polyaromatics, in the absence of moisture and of oxygen. The conductive polyaromatics obtained may be used in the electrical industry for the manufacture of solar cells, for the conversion of radiation and for the manufacture of electrical and magnetic switches, and may also be used to render plastics antistatic.
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公开(公告)号：DE2519583A1
公开(公告)日：1976-11-18
申请号：DE2519583
申请日：1975-05-02
Applicant: BASF AG
Abstract: Thermoplastic polybutylene terephthalate molding compositions of improved stability due to the presence of from 0.01 to 10 percent by weight, based on the total molding composition, of a lactam derivative.
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公开(公告)号：DE3105948A1
公开(公告)日：1982-08-19
申请号：DE3105948
申请日：1981-02-18
Applicant: BASF AG
Inventor： NAARMANN HERBERT DIPL CHEM DR , PENZIEN KLAUS DIPL CHEM DR , SCHLAG JOHANNES DIPL PHYS DR , SIMAK PETR DIPL CHEM DR
IPC: C08L49/00 , C08F8/42 , C08F8/50 , C09K3/16 , H01B1/12 , H01L31/02 , H01L51/00 , H01L51/30 , C08F38/02 , C08F138/02
Abstract: Stable electrically conductive polymers having conductivities greater than 10-2 S/cm are prepared by heating p-doped polyacetylenes, in the absence of oxygen and moisture, for from 0.1 to 3 hours, preferably from 0.5 to 1.0 hour, at from 500 DEG to 1,100 DEG C., preferably from 550 DEG to 850 DEG C. The electrically conductive polymers obtained can be used in the electrical industry for the production of solar cells, for the utilization and fixing of radiation, for the production of electrical and magnetic switches and stores, and for the antistatic treatment of plastics.
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公开(公告)号：DE3048445A1
公开(公告)日：1982-07-22
申请号：DE3048445
申请日：1980-12-22
Applicant: BASF AG
Inventor： NAARMANN HERBERT DIPL CHEM DR , PENZIEN KLAUS DIPL CHEM DR , NAEGELE DIETER DIPL CHEM DR , SCHLAG JOHANNES DIPL PHYS DR
IPC: C08F281/00 , C08F283/00 , H01B1/12 , H01L51/30 , H01L51/42 , C08F38/00
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