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    PROCESS FOR CATALYTIC HYDROGENATION
    1.
    发明专利
    PROCESS FOR CATALYTIC HYDROGENATION 审中-公开

    公开(公告)号：JP2003231887A

    公开(公告)日：2003-08-19

    申请号：JP2002297104

    申请日：2002-10-10

    Applicant: BASF AG

    Inventor： KOCH MICHAEL ,  SCHWAB EKKEHARD ,  TRUBENBACH PETER ,  SCHAFER HARALD

    IPC: C10G65/16 ,  C07C5/03 ,  C10G45/08 ,  C10G45/38

    Abstract: PROBLEM TO BE SOLVED: To provide a process for catalytically hydrogenating a hydrocarbon stream by which the fewest possible undesired secondary components such as oligomers and/or polymers and/or cracking products are formed. SOLUTION: The hydrocarbon stream is catalytically hydrogenated by adding a basic compound to the starting material stream without using a different solvent from the hydrocarbon stream to be hydrogenated. Thereby, the formation of undesired secondary components on the catalyst is effectively prevented. COPYRIGHT: (C)2003,JPO

    METHOD FOR HYDRATING POLY- OR MONOMETHYLOL ALKANALS
    4.
    发明申请
    METHOD FOR HYDRATING POLY- OR MONOMETHYLOL ALKANALS 审中-公开
    PROCESS加氢多晶硅或monomethylolalkanals的

    公开(公告)号：WO0238525A2

    公开(公告)日：2002-05-16

    申请号：PCT/EP0112681

    申请日：2001-11-02

    Applicant: BASF AG ,  DERNBACH MATTHIAS ,  KOCH MICHAEL ,  SCHULZ GERHARD ,  WEIGL HAGEN ,  MAAS STEFFEN

    Inventor： DERNBACH MATTHIAS ,  KOCH MICHAEL ,  SCHULZ GERHARD ,  WEIGL HAGEN ,  MAAS STEFFEN

    IPC: C07B61/00 ,  C07C29/141 ,  C07C31/20 ,  C07C31/22 ,  C07C31/24 ,  C07C45/78 ,  C07C47/19

    CPC classification number: C07C29/141 ,  C07C31/20 ,  C07C33/26 ,  C07C31/22

    Abstract: The invention relates to a method for catalytically hydrating a poly- or monomethylol alkanal of the general formula (I), wherein R is the same or different and may represent a substituted or unsubstituted aliphatic hydrocarbon with 6 to 22 carbon atoms, an aryl or arylalkyl group with 6 to 22 carbon atoms or a methylol group, in the presence of a copper-containing catalyst. The inventive method is characterized in that the poly- or monomethylol alkanal containing batch to be hydrated has a total content of up to 5 ppm of metal ions of the groups 3 to 14 of the periodic system.

    Abstract translation: 本发明涉及一种用于一聚的催化氢化或monomethylolalkanal通式（I），其中R可以是相同的或不同的，并且是具有1至22个碳原子，具有6〜22的芳基或芳基取代或未取代的脂族烃 碳原子或羟甲基，在含铜催化剂，其特征在于，所述氢化的聚或monomethylolalkanal含有具有基团3的Gwsamtgehalt至5ppm的金属离子的元素周期表第14的存在。

    9.
    发明专利
    未知

    公开(公告)号：DE502005001845D1

    公开(公告)日：2007-12-13

    申请号：DE502005001845

    申请日：2005-07-07

    Applicant: BASF AG

    Inventor： HAUNERT ANDREA ,  PINKOS ROLF ,  KRUG THOMAS ,  SIRCH TILMAN ,  KOCH MICHAEL ,  TEBBEN GERD-DIETER

    IPC: C07C29/145 ,  C07C29/149 ,  C07C31/20

    Abstract: The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).

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