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1.发明申请METHOD FOR HYDROGENATION OF METHYLOLALKANALS TO GIVE POLYVALENT ALCOHOLS WITH LOW ACETAL CONTENT 审中-公开PROCESS FOR羟甲基链烷对多元醇低甲醛加氢
公开(公告)号：WO2007099049A2
公开(公告)日：2007-09-07
申请号：PCT/EP2007051634
申请日：2007-02-21
Applicant: BASF AG , MAAS STEFFEN , JOHANN THORSTEN , STEINIGER MICHAEL , SIRCH TILMAN , SCHLITTER STEPHAN , RITTINGER STEFAN
Inventor： MAAS STEFFEN , JOHANN THORSTEN , STEINIGER MICHAEL , SIRCH TILMAN , SCHLITTER STEPHAN , RITTINGER STEFAN
CPC classification number: C07C29/141 , C07C31/22 , C07C31/245
Abstract: The invention relates to a method for production of polyvalent alcohols with low acetal content by catalytic hydrogenation of methylolalkanals of general formula (I), where R 1 and R 2 independently = a further methylol or C 1 - 22 alkyl group or C 6 - C 33 aryl or aralkyl group in the liquid phase on a hydrogenation catalyst, characterised in that at least one tertiary amine, inorganic base or inorganic or organic acid is added to the hydrogenation feed to adjust the pH value of the hydrogenation product to 7.0 to 9.0.
Abstract translation: 一种用于在具有由通式（I）的羟甲基链烷的催化氢化的低乙缩醛的制备多元醇的方法，其中R 1 和R 2 彼此独立地，进一步的羟甲基或烷基基团的 具有1至22个碳原子或至少加入叔胺，无机碱或无机酸或有机酸的具有在氢化催化剂6至33个碳原子，在液相中的芳基或芳烷基，其特征在于 氢化调节至pH 7.0至9.0的氢化。
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公开(公告)号：WO2004054948A8
公开(公告)日：2005-06-23
申请号：PCT/EP0313634
申请日：2003-12-03
Applicant: BASF AG , FISCHER ROLF-HARTMUTH , KRUG THOMAS , HAUNERT ANDREA , ROEPER MICHAEL , SIRCH TILMAN , STUEER WOLFRAM
Inventor： FISCHER ROLF-HARTMUTH , KRUG THOMAS , HAUNERT ANDREA , ROEPER MICHAEL , SIRCH TILMAN , STUEER WOLFRAM
IPC: C07C29/17 , C07C29/149 , C07C31/20 , C07C67/347 , C07C69/593
CPC classification number: C07C29/177 , C07C31/20
Abstract: The invention relates to a method for producing 1,6-hexanediol having a purity of > 99.5 wt. % by catalytic dimerisation of acrylic acid esters, catalytic hydrogenation of the thus obtained hexene diacidic diester in order to form 1.6-hexanediol. Said method consists in: a) dimerising C1- C8-acrylic acid esters in the presence of at least one rhodium compound in order to form mixtures predominantly of 2- and 3-hexene diacdic diesters, b) hydrating the obtained dimerisation discharge in the presence of chrome-free catalysts containing mainly copper as a hydrogenation component and c) purifying the thus obtained raw 1.6-hexanediol by fractionating distillation.
Abstract translation: 本发明涉及一种用于制备具有> 99.5重量％的纯度的1,6-己二醇，由丙烯酸酯，以这种方式获得成1,6-己二醇的二酯己烯的催化氢化方法，其包括催化二聚化：一个 ）C1至C8丙烯酸酯在二聚的至少一种铑化合物的存在下，得到主要为2-和3-己烯二酯的混合物，b）中氢化在无铬的存在下将所得二聚化流出物，含有作为氢化主要是铜催化剂，和c）将如此得到的粗1 1,6-己二醇通过分馏进行纯化。
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公开(公告)号：WO03042151A8
公开(公告)日：2004-06-24
申请号：PCT/EP0212491
申请日：2002-11-08
Applicant: BASF AG , WARTINI ALEXANDER , DERNBACH MATTHIAS , SCHROEDER JUERGEN , MARTIN FRIEDRICH-GEORG , SIRCH TILMAN
Inventor： WARTINI ALEXANDER , DERNBACH MATTHIAS , SCHROEDER JUERGEN , MARTIN FRIEDRICH-GEORG , SIRCH TILMAN
Abstract: The invention relates to a method for producing (meth) acrylic acid esters of polyhydric alcohols by reacting (meth) acrylic acid and the corresponding polyhydric alcohols in the presence of at least one acid catalyst and, optionally, of at least one polymerization inhibitor and, optionally, in the presence of a solvent, whereby the polyhydric alcohol that is used has a content of bound formaldehyde of less than 500 ppm.
Abstract translation: 一种通过（甲基）丙烯酸的反应制备的多元醇的（甲基）丙烯酸酯和在至少一种酸性催化剂的存在下，相应的多元醇和任选的至少一种聚合抑制剂和任选地在溶剂的存在下，其中使用的多元醇具有的结合的内容的处理 包括下500ppm的甲醛。
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4.发明专利
公开(公告)号：CA2466295C
公开(公告)日：2010-01-12
申请号：CA2466295
申请日：2001-11-15
Applicant: BASF AG
Inventor： MELDER JOHANN-PETER , DERNBACH MATTHIAS , WARTINI ALEXANDER , SIRCH TILMAN
Abstract: The invention relates to a method for removing acetals containing formaldehy de from polyvalent alcohols, especially trimethylolpropane. The inventive metho d is characterised in that the polyvalent alcohol is liberated of low-boiling constituents after it has been produced by distillation, is then subjected t o tempering and is repurified, preferably by means of distillation.
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公开(公告)号：ES2271376T3
公开(公告)日：2007-04-16
申请号：ES02801897
申请日：2002-10-18
Applicant: BASF AG
Inventor： KOCH MICHAEL , WARTINI ALEXANDER , SIRCH TILMAN , DERNBACH MATTHIAS
Abstract: Procedimiento para la descomposición de formiato de trialquilamonio a partir de metilolalcanos, que han sido obtenidos mediante condensación de formaldehído con un aldehído superior, a 100 hasta 250ºC y a una presión mayor que 106 Pa, caracterizado porque se descompone el formiato de trialquilamonio sobre catalizadores que contienen, al menos, un metal de los grupos octavo a decimosegundo del Sistema Periódico, con aporte de gases que contengan hidrógeno.
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Patent Agency Ranking
公开(公告)号：AT334957T
公开(公告)日：2006-08-15
申请号：AT02792927
申请日：2002-12-06
Applicant: BASF AG
Inventor： SIRCH TILMAN , KAIBEL GERD , WARTINI ALEXANDER , DERNBACH MATTHIAS
IPC: C07C29/38 , C07B61/00 , C07C29/141 , C07C29/80 , C07C31/22
Abstract: Trimethylolpropane is isolated from a reaction mixture which has been obtained by reaction of n-butyraldehyde with formaldehyde in the presence of a base and, if appropriate, hydrogenation of the resulting mixture by distilling the mixture by means of a dividing wall column or a distillation column with a precolumn or a distillation column with an after-column. The process has low capital costs and a low energy consumption and gives reduced formation of high-boiling by-products.
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公开(公告)号：AT334956T
公开(公告)日：2006-08-15
申请号：AT03799469
申请日：2003-12-03
Applicant: BASF AG
Inventor： FISCHER ROLF-HARTMUTH , KRUG THOMAS , HAUNERT ANDREA , ROEPER MICHAEL , SIRCH TILMAN , STUEER WOLFRAM
IPC: C07C29/17 , C07C29/149 , C07C31/20 , C07C67/347 , C07C69/593
Abstract: Production of 1,6-hexanediol of purity at least 99.5 % comprises: (1) catalytically dimerizing a 1-8C acrylic acid ester in presence of rhodium compounds to a mixture mainly of 2- and 3-hexenedioic acid diesters; (2) hydrogenating the ester mixture in chromium-free mainly copper-containing catalysts; and (3) purifying the resulting diol mixture by fractional distillation.
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公开(公告)号：BR0311166A
公开(公告)日：2005-03-15
申请号：BR0311166
申请日：2003-05-21
Applicant: BASF AG
Inventor： WARTINI ALEXANDER , DERNBACH MATTHIAS , TISCHER GERLINDE , SIRCH TILMAN
Abstract: The invention provides a process for preparing polyester polyols of polyhydric alcohols by mono- or polyesterification of at least one carboxylic acid having at least two acid groups and/or at least one derivative of a dicarboxylic acid with polyhydric alcohols, optionally with the addition of a catalyst, while removing the water of reaction, wherein the polyhydric alcohol used has a formaldehyde acetal content of less than 500 ppm.
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公开(公告)号：BR0214133A
公开(公告)日：2004-10-13
申请号：BR0214133
申请日：2002-11-08
Applicant: BASF AG
Inventor： WARTINI ALEXANDER , DERNBACH MATTHIAS , DER J RGEN SCHR , MARTIN FRIEDRICH-GEORG , SIRCH TILMAN
Abstract: (Meth)acrylates of polyhydric alcohols are prepared by reacting (meth)acrylic acid and the corresponding polyhydric alcohol in the presence of at least one acidic catalyst and, if required, at least one polymerization inhibitor and in the presence or absence of a solvent, by a process in which the polyhydric alcohol used contains less than 500 ppm of bound formaldehyde.
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公开(公告)号：DE10223054A1
公开(公告)日：2003-12-04
申请号：DE10223054
申请日：2002-05-24
Applicant: BASF AG
Inventor： WARTINI ALEXANDER , DERNBACH MATTHIAS , HACKMANN CLAUS , SIRCH TILMAN
IPC: C07C29/38 , C07C31/22 , C08G65/26 , C08G65/28 , C08G65/10 , C07C41/03 , C07C43/13 , C07C51/367 , C07C67/31 , C07B41/04
Abstract: The invention provides a process for preparing polyetherols of polyhydric alcohols by reacting an alkylene oxide with the appropriate polyhydric alcohol in the presence of a base and in the presence or absence of a solvent, wherein the polyhydric alcohol used has a formaldehyde acetal content of less than 500 ppm.
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