公开(公告)号：JPH1082793A

公开(公告)日：1998-03-31

申请号：JP20594997

申请日：1997-07-31

Applicant: BASF AG

Inventor： FRIEDRICH THOMAS DR ,  SCHREPP WOLFGANG DR ,  AKARI SABRI DR

IPC: G01N33/532 ,  G01N23/225 ,  G01N33/543 ,  G01Q60/42 ,  G01N37/00

Abstract: PROBLEM TO BE SOLVED: To realize a screening method capable of analyzing multiple specimens in a short time by detecting an active compound based on the change of a signal which can be observed by using a device for a scanning atomic force microscopic inspection. SOLUTION: A receptor 5 is fixed on a surface 4 of a support. The change of connection of an active compound 3 to the receptor 5 is measured by using a signal S. The active compound 3 is similarly fixed on a chip 1 of a scanning atomic force microscope by means of a spacer 2 in convenient. The active compound 3 is fixed on the surface 4 of the support and the receptor 5 is on the chip 1 of the microscope. Firstly, the chip 1 is coated with an evaporation layer of chromium as an adhesion accelerator having a thickness of, for example, 5nm, then it is coated with a gold having a thickness of 50nm. The chip 1 coated with gold is similarly coated with mercapto carboxylic acid and a spacer 2 is suspended on the chip 1. When estimation is executed by simultaneously using a plurality of probes, a piezoelectric cantilever is utilized.

公开(公告)号：DE59208624D1

公开(公告)日：1997-07-24

申请号：DE59208624

申请日：1992-08-07

Applicant: BASF AG

Inventor： KELLER HARALD DR ,  SCHREPP WOLFGANG DR ,  FUCHS HARALD DR

IPC: C07C319/20 ,  C07C323/03 ,  C07C323/12 ,  C07C323/25 ,  C07C323/52 ,  C07C323/66 ,  C07D209/48 ,  C23C22/02 ,  C23C22/05 ,  C23F11/16

Abstract: The invention relates to disulphides of the general formula X -(CH2)n-S-S-(CH2)n-X in which X and X are identical to one another and represent -Br, -N-phthalimide, -NH2, -OOC-(CH2)3-COOH, -O-SO2-CH3, -NH-(CH2)2- NH2, -SO3H or -SO3 M where M = an alkali metal ion, and n = 11 to 25, or X represents -OH and X represents -Br or X and X represent -COO-CH2-CH3 and n = 10 to 25, and to a process for their preparation. These disulphides are suitable for the preparation of monomolecular layers on noble metal supports and for the building up of multimolecular layers.

公开(公告)号：DK0529373T3

公开(公告)日：1997-07-07

申请号：DK92113508

申请日：1992-08-07

Applicant: BASF AG

Inventor： FUCHS HARALD DR ,  SCHREPP WOLFGANG DR ,  KELLER HARALD DR

IPC: C07C319/20 ,  C07C323/03 ,  C07C323/12 ,  C07C323/25 ,  C07C323/52 ,  C07C323/66 ,  C07D209/48 ,  C23C22/02 ,  C23C22/05 ,  C23F11/16

Abstract: The invention relates to disulphides of the general formula X -(CH2)n-S-S-(CH2)n-X in which X and X are identical to one another and represent -Br, -N-phthalimide, -NH2, -OOC-(CH2)3-COOH, -O-SO2-CH3, -NH-(CH2)2- NH2, -SO3H or -SO3 M where M = an alkali metal ion, and n = 11 to 25, or X represents -OH and X represents -Br or X and X represent -COO-CH2-CH3 and n = 10 to 25, and to a process for their preparation. These disulphides are suitable for the preparation of monomolecular layers on noble metal supports and for the building up of multimolecular layers.

公开(公告)号：AT142019T

公开(公告)日：1996-09-15

申请号：AT92109973

申请日：1992-06-13

Applicant: BASF AG

Inventor： SCHREPP WOLFGANG DR ,  RAMESH CHANDRA AHUJA DR ,  BUDACH WOLFGANG ,  MOEBIUS DIETMAR DR

IPC: G01N21/64 ,  G01N21/76 ,  G01N33/52 ,  G01N33/543

Abstract: The invention relates to a chemical sensor comprising …… (a) a solid support material, … (b) a layer (D) which is deposited on the support material and which contains at least one fluorescent compound, and … (c) a layer (A) which is deposited on the layer (D) and which contains one or more coupling components (D) which, as a result of reaction with the analyte, produce one or more specific absorption bands which overlap spectrally with the emission of the fluorescent compound in the layer (D). …… …

公开(公告)号：DE4127821A1

公开(公告)日：1993-02-25

申请号：DE4127821

申请日：1991-08-23

Applicant: BASF AG

Inventor： KELLER HARALD DR ,  SCHREPP WOLFGANG DR ,  FUCHS HARALD DR

IPC: C07C319/20 ,  C07C323/03 ,  C07C323/12 ,  C07C323/25 ,  C07C323/52 ,  C07C323/66 ,  C07D209/48 ,  C23C22/02 ,  C23C22/05 ,  C23F11/16

Abstract: The invention relates to disulphides of the general formula X -(CH2)n-S-S-(CH2)n-X in which X and X are identical to one another and represent -Br, -N-phthalimide, -NH2, -OOC-(CH2)3-COOH, -O-SO2-CH3, -NH-(CH2)2- NH2, -SO3H or -SO3 M where M = an alkali metal ion, and n = 11 to 25, or X represents -OH and X represents -Br or X and X represent -COO-CH2-CH3 and n = 10 to 25, and to a process for their preparation. These disulphides are suitable for the preparation of monomolecular layers on noble metal supports and for the building up of multimolecular layers.

公开(公告)号：DE4030651A1

公开(公告)日：1992-04-09

申请号：DE4030651

申请日：1990-09-28

Applicant: BASF AG

Inventor： FUCHS HARALD DR ,  SCHREPP WOLFGANG DR ,  RAPP MICHAEL DR ,  HUNKLINGER SIEGFRIED PROF DR ,  SCHICKFUS MANFRED VON DR

IPC: G01N9/00 ,  G01N29/02

Abstract: The invention relates to a highly sensitive surface-wave gas sensor in which the frequency of an oscillatory circuit containing a surface-wave delay line is altered as a function of the type of gas and gas concentration as a result of the interaction of a surface-wave field with a solid-state film suitable for adsorbing the gas to be determined. The delay line provided for the adsorption of the gas is completely coated with the solid-state film and the dimensioning of the delay lines is such that the length of the surface-wave transducer is greater than that of the delay line.

公开(公告)号：DE3929053A1

公开(公告)日：1991-03-07

申请号：DE3929053

申请日：1989-09-01

Applicant: BASF AG

Inventor： BROX WOLFGANG DR ,  FUNHOFF DIRK DR ,  LICHT ULRIKE ,  FUCHS HARALD DR ,  SCHREPP WOLFGANG DR

IPC: G02F1/35 ,  C07C211/48 ,  C07C211/52 ,  C07C245/08 ,  C07C251/24 ,  C07C251/86 ,  C07C255/58 ,  C07C323/37 ,  C07D213/24 ,  C07D251/24 ,  C08F16/14 ,  C08F16/28 ,  C08F26/00 ,  C08F26/02 ,  C08F28/00 ,  C08F28/02 ,  G02F1/355 ,  G02F1/361

Abstract: The novel compounds of the general formula I having nonlinear optical properties in which the variables have the following meaning: X is a straight-chain or branched alkanediyl radical having 1 to 20 C atoms or X is a straight-chain or branched alkanediyl radical having 2 to 20 C atoms, the carbon chain of which is interrupted by -O-, -S- and/or -NR-; R is a hydrogen atom, a straight-chain or branched alkyl radical having 1 to 6 C atoms or a cycloalkyl radical, Y is a non-centrosymmetrical radical containing an easily polarisable conjugated pi -electron system and at least one terminal electron acceptor group; are outstandingly suitable as nonlinear optical materials for nonlinear optical arrangements and for the preparation of polymers having nonlinear optical properties. In particular, they are used for the preparation of organopolysiloxanes having nonlinear optical properties and which contain side groups of the general formula Ia in which the variables have the abovementioned meaning. These novel organopolysiloxanes having nonlinear optical properties are in turn outstandingly suitable for the preparation of Langmuir-Blodgett films.

公开(公告)号：ES2102430T3

公开(公告)日：1997-08-01

申请号：ES92113508

申请日：1992-08-07

Applicant: BASF AG

Inventor： KELLER HARALD DR ,  SCHREPP WOLFGANG DR ,  FUCHS HARALD DR

IPC: C07C319/20 ,  C07C323/03 ,  C07C323/12 ,  C07C323/25 ,  C07C323/52 ,  C07C323/66 ,  C07D209/48 ,  C23C22/02 ,  C23C22/05 ,  C23F11/16

Abstract: The invention relates to disulphides of the general formula X -(CH2)n-S-S-(CH2)n-X in which X and X are identical to one another and represent -Br, -N-phthalimide, -NH2, -OOC-(CH2)3-COOH, -O-SO2-CH3, -NH-(CH2)2- NH2, -SO3H or -SO3 M where M = an alkali metal ion, and n = 11 to 25, or X represents -OH and X represents -Br or X and X represent -COO-CH2-CH3 and n = 10 to 25, and to a process for their preparation. These disulphides are suitable for the preparation of monomolecular layers on noble metal supports and for the building up of multimolecular layers.

公开(公告)号：AT154595T

公开(公告)日：1997-07-15

申请号：AT92113508

申请日：1992-08-07

Applicant: BASF AG

Inventor： KELLER HARALD DR ,  SCHREPP WOLFGANG DR ,  FUCHS HARALD DR

IPC: C07C319/20 ,  C07C323/03 ,  C07C323/12 ,  C07C323/25 ,  C07C323/52 ,  C07C323/66 ,  C07D209/48 ,  C23C22/02 ,  C23C22/05 ,  C23F11/16

Abstract: The invention relates to disulphides of the general formula X -(CH2)n-S-S-(CH2)n-X in which X and X are identical to one another and represent -Br, -N-phthalimide, -NH2, -OOC-(CH2)3-COOH, -O-SO2-CH3, -NH-(CH2)2- NH2, -SO3H or -SO3 M where M = an alkali metal ion, and n = 11 to 25, or X represents -OH and X represents -Br or X and X represent -COO-CH2-CH3 and n = 10 to 25, and to a process for their preparation. These disulphides are suitable for the preparation of monomolecular layers on noble metal supports and for the building up of multimolecular layers.

公开(公告)号：DE59206983D1

公开(公告)日：1996-10-02

申请号：DE59206983

申请日：1992-06-13

Applicant: BASF AG

Inventor： SCHREPP WOLFGANG DR ,  RAMESH CHANDRA AHUJA DR ,  BUDACH WOLFGANG ,  MOEBIUS DIETMAR DR

IPC: G01N21/64 ,  G01N21/76 ,  G01N33/52 ,  G01N33/543

Abstract: The invention relates to a chemical sensor comprising …… (a) a solid support material, … (b) a layer (D) which is deposited on the support material and which contains at least one fluorescent compound, and … (c) a layer (A) which is deposited on the layer (D) and which contains one or more coupling components (D) which, as a result of reaction with the analyte, produce one or more specific absorption bands which overlap spectrally with the emission of the fluorescent compound in the layer (D). …… …