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公开(公告)号:DE3783292D1
公开(公告)日:1993-02-11
申请号:DE3783292
申请日:1987-08-18
Applicant: BASF AG
Inventor: GOERRISSEN HEINER DR , SAENGER DIETRICH , SCHUETTE WILHELM DR , WALTER MANFRED DR
Abstract: Moulding compsns. consist of (A) at least one polyoxymethylene homo- and/or copolymer, (B) at least one thermoplastic polyurethane elastomer and (C) opt. additives and (D) 0.005-2 wt.% w.r.t. the total wt. of (A) plus (B), of at least one alkaline earth silicate as additive to improve heat-stability. (D) has formula MO.xSiO2.nH2O (I) where M = alkaline earth metal, esp. Ca or Mg; X = no. 1.4-10 and n = at least zero.
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公开(公告)号:DE3628561C2
公开(公告)日:1994-11-10
申请号:DE3628561
申请日:1986-08-22
Applicant: BASF AG
Inventor: GOERRISSEN HEINER DR , SAENGER DIETRICH DR , SCHUETTE WILHELM DR , WALTER MANFRED DR
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公开(公告)号:DE3628561A1
公开(公告)日:1988-03-03
申请号:DE3628561
申请日:1986-08-22
Applicant: BASF AG
Inventor: GOERRISSEN HEINER DR , SAENGER DIETRICH DR , SCHUETTE WILHELM DR , WALTER MANFRED DR
IPC: C08K3/34 , C08K5/3492 , C08K5/521 , C08L59/00 , C08L61/28 , C08L77/00 , C08J5/00 , C08K5/13 , C08K5/32 , C08K5/34 , C08K7/14
Abstract: The invention relates to reinforced polyoxymethylene moulding compositions having improved thermostability comprising (A) at least one polyoxymethylene homopolymer and/or copolymer, (B) at least one reinforcing material, preferably glass fibres or textile sheet-like structures made from glass fibres, (C) at least one alkoxymethylmelamine and (D) optionally additives, which contain, in order to improve the heat resistance, reduce the tendency to discoloration and minimise the free formaldehyde content, as (E) additive, at least one alkaline earth metal glycerophosphate and/or magnesium silicate, expediently in an amount of from 0.01 to 2% by weight, based on the weight of components (A) and (B). In order to prepare the reinforced moulding compositions, the formative components are expediently melted together in an extruder at temperatures of from 150 to 260 DEG C. The reinforced poloxymethylene compositions are suitable for the production of mouldings used, for example, in the automotive, electrical appliance and electronics industries.
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公开(公告)号:DE3628559A1
公开(公告)日:1988-03-03
申请号:DE3628559
申请日:1986-08-22
Applicant: BASF AG
Inventor: GOERRISSEN HEINER DR , SAENGER DIETRICH DR , SCHUETTE WILHELM DR , WALTER MANFRED DR
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公开(公告)号:DE3441546A1
公开(公告)日:1986-05-15
申请号:DE3441546
申请日:1984-11-14
Applicant: BASF AG
Inventor: HEINZ GERHARD DR , SCHUETTE WILHELM DR , SIMON GEORG NIKOLAUS DR
IPC: C08L59/00 , C08K3/00 , C08K3/34 , C08L7/00 , C08L21/00 , C08L23/00 , C08L23/04 , C08L33/00 , C08L33/02 , C08L59/02 , C08L61/20 , C08L83/00 , C08L83/04 , C08L101/00 , C08K5/34 , C08K5/54
Abstract: Thermoplastic polyoxymethylene molding materials having high abrasion resistance contain (A) from 4 to 94.7 parts by weight of polyoxymethylene, (B) from 5 to 50 parts by weight of wollastonite, (C) from 0.2 to 5 parts by weight of N-hydroxymethylmelamines in which some or all of the hydroxymethyl groups are etherified with alkanols, (D) from 0.1 to 5 parts by weight of a silicone oil having a degree of polycondensation n of from 10 to 5,000 and/or (E) from 0.1 to 10 parts by weight of polyethylene and/or copolymers of ethylene and alpha -olefins having a molecular weight of from 100,000 to 1,000,000, the number of parts by weight of components A, B, C, D and E summing to 100, with or without (F) effective amounts of additives.
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公开(公告)号:DE1669727B1
公开(公告)日:1971-04-15
申请号:DE1669727D
申请日:1967-10-17
Applicant: BASF AG
Inventor: SANDER BRUNO DR , SCHUETTE WILHELM DR
Abstract: 1,234,057. Stabilizing oxymethylene polymers by addition of a #-aminolactamide. BADISCHE ANILIN- & SODA-FABRIK A.G. ]6 Oct., 1968 [17 Oct., 1967 (2)], No. 48967/68. Heading C3P. Compositions comprise an oxymethylene polymer and a stabilizing compound of formula where R 1 is H, OH, NR 2 R 2 , -CH 2 -CH(OH)- CONH 2 , in which m is 1 to 3 and n is 1 or 2, or m is 1 and n is 1 to 3, or in which m + n is 1 to 5 and m is 1 to 5, and R 2 is H or CH 2 .CH(OH)-CONH 2 . Phenolic antioxidants and a polycondensate of isophthalic diamide, a cyclic -N,N 1 - alkylene urea having 2 to 5 carbon atoms, and formaldehyde may also be included. In the examples, trioxan-1,3- dioxolan copolymers treated with NaF are stabilized with nitrilotrilactamide or ethylene diamine tetralactamide and a conventional bisphenol.
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公开(公告)号:AT268670B
公开(公告)日:1969-02-25
申请号:AT581566
申请日:1966-06-17
Applicant: BASF AG
Inventor: SCHUETTE WILHELM DR , OLSEN BJOERN DR , ZENDATH JOSEF ING
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公开(公告)号:ES2053485T3
公开(公告)日:1994-08-01
申请号:ES87111931
申请日:1987-08-18
Applicant: BASF AG
Inventor: GOERRISSEN HEINER DR , SAENGER DIETRICH , SCHUETTE WILHELM DR , WALTER MANFRED DR
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公开(公告)号:DE3926869A1
公开(公告)日:1991-02-21
申请号:DE3926869
申请日:1989-08-16
Applicant: BASF AG
IPC: B22F3/10 , C04B35/634 , C04B35/638
Abstract: Process for prodn. of an inorganic sintered moulding (I) comprises injection moulding or extruding a mixt. of a sinterable inorganic powder (II) and polyoxymethylene binder (III) to form a green moulding (IV), removing the binder (III) and sintering; the novelty is that (III) is removed by treatment of (IV) in a gaseous atmos. contg. an acid or BF3 gas. Treatment of (IV) is carried out at 20-150 deg.C; acid is HNO3, Halogen and/or an organic acid with b.pt. below 130 deg.C, pref. formic acid. (II) is, e.g. alumina, zirconia, yttrium oxide, SiC, Si3N4, Si powder, Fe powder, etc.; (III) is a homopolymer or copolymer of trioxan with ethylene oxide, 1,3-dioxolan, butanediol formal (V), etc., with mol.wt. 25,000-75,000.
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10.
公开(公告)号:DE3560680D1
公开(公告)日:1987-10-29
申请号:DE3560680
申请日:1985-10-25
Applicant: BASF AG
Inventor: HEINZ GERHARD DR , SCHUETTE WILHELM DR , SIMON GEORG NIKOLAUS DR
IPC: C08L59/00 , C08K3/00 , C08K3/34 , C08L7/00 , C08L21/00 , C08L23/00 , C08L23/04 , C08L33/00 , C08L33/02 , C08L59/02 , C08L61/20 , C08L83/00 , C08L83/04 , C08L101/00
Abstract: Thermoplastic polyoxymethylene molding materials having high abrasion resistance contain (A) from 4 to 94.7 parts by weight of polyoxymethylene, (B) from 5 to 50 parts by weight of wollastonite, (C) from 0.2 to 5 parts by weight of N-hydroxymethylmelamines in which some or all of the hydroxymethyl groups are etherified with alkanols, (D) from 0.1 to 5 parts by weight of a silicone oil having a degree of polycondensation n of from 10 to 5,000 and/or (E) from 0.1 to 10 parts by weight of polyethylene and/or copolymers of ethylene and alpha -olefins having a molecular weight of from 100,000 to 1,000,000, the number of parts by weight of components A, B, C, D and E summing to 100, with or without (F) effective amounts of additives.
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