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    DIPHOSPHINE
    3.
    发明专利
    DIPHOSPHINE 未知

    公开(公告)号：MY134246A

    公开(公告)日：2007-11-30

    申请号：MYPI20023638

    申请日：2002-09-28

    Applicant: BASF AG

    Inventor： SAVA XAVIER DR ,  SLANY MICHAEL DR ,  PER MICHAEL R XD PROF DR

    IPC: B01J31/28 ,  B01J31/24 ,  C07F9/6568 ,  C07B61/00 ,  C07C51/14 ,  C07C57/03 ,  C07C67/38 ,  C07C69/533 ,  C07F9/6571

    Abstract: A SYSTEM COMPRISING A DIPHOSPHINE OF THE FORMULA @R1>P-(CH)n-PR2R3WHERER1 IS A DIVALENT RADICAL WHICH TOGETHER WITH THE PHOSPHORUS ATOM TO WHICH IT IS LINKED FORMS AN UNSUBSTITUTED OR SUBSTITUTED 2-PHOSPHATRICYCLO [3.3.1.1 ] DECYL GROUP OR A DERIVATIVE THEREOF IN WHICH ONE OR MORE OF THE CARBON ATOMS ARE REPLACED BY HETEROATOMS,R2, R3 ARE EACH, INDEPENDENTLY OF ONE ANOTHER, A MONOVALENT RADICAL HAVING FROM 1 TO 20 ATOMS OR TOGETHER FORM A DIVALENT RADICAL HAVING FROM 2 TO 20 ATOMS,n IS 4 OR 5AND A MIXTURE OF SUCH DIPHOSPHINES,AND PALLADIUM OR A PALLADIUM COMPOUND IS SUITABLE AS CARBONYLATION CATALYST FOR THE CARBONYLATION OF A CONJUGATED DIENE.

    Production of carbon monoxide-olefin copolymers, used for production of fibers, film and molded products
    4.
    发明专利
    Production of carbon monoxide-olefin copolymers, used for production of fibers, film and molded products 未知

    公开(公告)号：DE19746279A1

    公开(公告)日：1999-04-22

    申请号：DE19746279

    申请日：1997-10-20

    Applicant: BASF AG

    Inventor： QUEISSER JOACHIM DR ,  SLANY MICHAEL DR ,  LUDWIG ALFONS DR

    IPC: B01J31/16 ,  B01J31/18 ,  B01J31/24 ,  B01J37/03 ,  C07F9/50 ,  C07F15/00 ,  C08G67/02 ,  C08J5/00 ,  C08J5/04 ,  C08J5/18 ,  C08L73/00 ,  D01F6/96

    Abstract: A supported catalyst for the production of carbon monoxide copolymers is obtained by suspending the support in non-polar aprotic solvent, adding a solution of a Group VIIIB, IB or IIB metal complex with bi- or tri-dentate ligand(s) in a polar aprotic solvent, possibly adding non- polar solvent and working up by filtration. A process for the production of linear alternating copolymers of carbon monoxide (CO) and olefinically unsaturated compounds uses an activator compound and a supported heterogeneous catalyst system, which is obtained by: (a) suspension of the support material in a non-polar aprotic liquid (NPAL), (b) controlled addition of a Group VIIIB, IB or IIB metal chelate complex with bi- or tri- dentate ligand(s) as a solution in a polar aprotic liquid, (c) filtration, optionally followed by washing with NPAL and (d) optionally removing liquid residues with inert gas. Alternatively, the mixture obtained from stage (b) may be mixed with NPAL before performing stages (c) and (d) as above. An Independent claim is also included for carbon monoxide copolymers obtained by this process.

    METHOD FOR PRODUCING METHYL FORMATE
    8.
    发明专利
    METHOD FOR PRODUCING METHYL FORMATE 未知

    公开(公告)号：MY138058A

    公开(公告)日：2009-04-30

    申请号：MYPI20031440

    申请日：2003-04-17

    Applicant: BASF AG

    Inventor： ADAMI CHRISTOPH DR ,  SLANY MICHAEL DR ,  KARL JOERN DR ,  KAIBEL GERD DR ,  SCHAFER MARTIN DR ,  ZEHNER PETER DR ,  PER MICHAEL R XD PROF DR

    IPC: C07C67/36

    Abstract: THE INVENTION RELATES TO A PROCESS FOR THE PREPARATION OF METHYL FORMATE BY REACTING METHANOL WOTH CARBON MONOXIDE AT A PRESSURE OF FROM 0.5 TO 10 MPA ABS. AND A TEMPERATURE OF FROM 50 TO 150°C IN THE PRESENCE OF A METAL ALKOXIDE AS CATALYST IN A REACTOR, IN WHICH A GAS STREAM IS WITHDRAWN FROM THE REACTOR, ENTRAINED METHYL FORMATE IS REMOVED FROM THIS GAS STREAM BY CONDENSATION, AND ALL OR SOME OF THE REMAINING GAS STREAM IS RETURNED TO THE REACTOR AS CIRCULATING-GAS STREAM AND A MEAN GAS SUPERFICIAL VELOCITY OF FROM 1 TO 20 CM/S IS SET IN AT LEAST ONE REGION OF THE REACTOR IN WHICH THE GAS FLOWS ESSENTIALLY IN ONE DIRECTION.

    Cis-bridged metal complex and Lewis and/or protonic acid mixture
    10.
    发明专利
    Cis-bridged metal complex and Lewis and/or protonic acid mixture 未知

    公开(公告)号：DE19651786A1

    公开(公告)日：1998-06-25

    申请号：DE19651786

    申请日：1996-12-12

    Applicant: BASF AG

    Inventor： SLANY MICHAEL DR ,  HOEHN ARTHUR DR

    IPC: B01J31/18 ,  B01J31/24 ,  C08G67/02 ,  B01J31/22 ,  C08J5/00 ,  C08J5/18 ,  C08L73/00 ,  C09D173/00 ,  D01F6/28

    Abstract: A catalyst system (I) consists of (A) a metal complex of formula (1) and (B) a Lewis and/or a protonic acid. Also claimed are: (i) a method for the preparation of copolymers (II) of carbon monoxide and olefin(s) in the presence of (1); and (ii) fibre, film, moulded articles and coatings containing (II). In (1), R = H, 1-20C hydrocarbon, 3-30C organosilicon, NR R or formula (1a); q = 0-20; R', R", R -R = H, 1-20C hydrocarbon or 3-30C organosilicon; M = Group VIIIB metal; E , E , Z = Group VA element; R -R = 1-20C hydrocarbon or 3-30C organosilicon; A , B = 1-4C alkylene, silylene bridged organic group or NR ; L , L = ligand; p, m, n = 0-4; and p = m\*n.

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