公开(公告)号：JP2003026620A

公开(公告)日：2003-01-29

申请号：JP2002130876

申请日：2002-05-02

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフト

Inventor： ANSMANN ANDREAS ,  HENKELMANN JOCHEM ,  KINDLER ALOIS ,  ETZRODT HEINZ ,  OOST CARSTEN ,  STUTZ SUSANNE ,  TRAGUT CHRISTIAN ,  BOCKSTIEGEL BERNHARD ,  REIMER KLAUS ,  STROEZEL MANFRED ,  DOBLER WALTER

IPC: B01J23/44 ,  B01J23/50 ,  B01J35/04 ,  B01J35/06 ,  B01J37/02 ,  C07B61/00 ,  C07C29/17 ,  C07C29/32 ,  C07C29/42 ,  C07C33/02 ,  C07C33/048 ,  C07C45/48 ,  C07C45/62 ,  C07C45/67 ,  C07C49/203

CPC classification number: C07C49/203 ,  B01J23/44 ,  B01J23/50 ,  B01J35/04 ,  B01J35/06 ,  B01J37/0225 ,  C07C29/17 ,  C07C29/42 ,  C07C45/62 ,  C07C45/676 ,  C07C33/02 ,  C07C33/048 ,  C07C49/04

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a higher α,β-unsaturated alcohol in which engineering is easily performed. SOLUTION: This method for producing the alcohol represented by formula Ia or Ib [R is a 1-4C alkyl group; R is a group of formula II (R is hydrogen or a 1-4C alkyl group; a broken line is an additional double bond; and n is 0 or 1-6), hydrogen, or a saturated alkyl group] comprises (a) mono-ethynylating a ketone or formula: R -CO-CH2 -R in ammonia solution by using a basic catalyst, (b) optionally hydrogenating the alcohol of formula Ib on a Pd catalyst, and (c) subjecting the hydrogenated product to a purification distillation, and if necessary, reacting Ia or Ib produced by the steps (a) to (c) or by the steps (a) and (c) with an alkyl acetoacetate of formula IV [R is a 1-4C alkyl group], or a diketene to provide a methyl ketone, and using the ketone as a starting material in the steps (a) to (c).

Abstract translation: 要解决的问题：提供一种制造其中易于进行工程的较高α，β-不饱和醇的方法。 解决方案：用于制备由式Ia或Ib表示的醇的方法[R 1]是1-4C烷基; R 2是式II的基团（R 3是氢或1-4C烷基;虚线是另外的双键; n是0或1-6），氢或饱和烷基 基团]包括（a）通过使用碱性催化剂在氨溶液中使酮或式：R 1 -CO-CH 2 -R 2单乙炔基化，（b）任选地在Pd催化剂上氢化式Ib的醇 和（c）使氢化产物进行纯化蒸馏，如果需要，使由步骤（a）至（c）或步骤（a）和（c）制备的Ia或Ib与式 IV [R 5是1-4C烷基]或二烯酮以提供甲基酮，并且在步骤（a） - （c）中使用酮作为原料。

公开(公告)号：AU2004281952B2

公开(公告)日：2010-11-25

申请号：AU2004281952

申请日：2004-10-14

Applicant: BASF AG

Inventor： BOHN ROLAND ,  TROPSCH JURGEN ,  STUTZ SUSANNE ,  KLUMPE MARKUS ,  NORENBERG RALF ,  KAHL ROLF-DIETER

IPC: C07C43/11 ,  C09K23/42 ,  C11D1/72 ,  C11D1/722 ,  C11D1/825

Abstract: The alkoxylate mixtures comprise alkoxylates of the formula (I) C5H11CH(C3H7)CH2O(B)p(A)n(B)m(A)qH(I) where A is ethyleneoxy, B, in each case independently, are C3-10-alkyleneoxy or mixtures thereof, groups A and B being present in the form of blocks in the stated sequence, p is a number from 0 to 10, n is a number greater than 0 to 20, m is a number greater than 0 to 20, q is a number greater than 0 to 10, p+n+m+q is at least 1, from 70 to 99% by weight of alkoxylates A1, in which C5H11 is n-C5H11, and from 1 to 30% by weight of alkoxylates A2, in which C5H11 is C2H5CH(CH3)CH2 and/or CH3CH(CH3)CH2CH2, being present in the mixture.

公开(公告)号：AT384693T

公开(公告)日：2008-02-15

申请号：AT04790431

申请日：2004-10-14

Applicant: BASF AG

Inventor： KLUMPE MARKUS ,  TROPSCH JUERGEN ,  KAHL ROLF-DIETER ,  BOEHN ROLAND ,  STUTZ SUSANNE ,  NOERENBERG RALF

IPC: C07C43/11 ,  C09K23/42 ,  C11D1/72 ,  C11D1/722 ,  C11D1/825

Abstract: The alkoxylate mixtures comprise alkoxylates of the formula (I) C5H11CH(C3H7)CH2O(B)p(A)n(B)m(A)qH(I) where A is ethyleneoxy, B, in each case independently, are C3-10-alkyleneoxy or mixtures thereof, groups A and B being present in the form of blocks in the stated sequence, p is a number from 0 to 10, n is a number greater than 0 to 20, m is a number greater than 0 to 20, q is a number greater than 0 to 10, p+n+m+q is at least 1, from 70 to 99% by weight of alkoxylates A1, in which C5H11 is n-C5H11, and from 1 to 30% by weight of alkoxylates A2, in which C5H11 is C2H5CH(CH3)CH2 and/or CH3CH(CH3)CH2CH2, being present in the mixture.

公开(公告)号：BRPI0415391B1

公开(公告)日：2015-03-17

申请号：BRPI0415391

申请日：2004-10-14

Applicant: BASF AG

Inventor： KLUMPE MARKUS ,  TROPSCH JÜRGEN ,  KAHL ROLF-DIETER ,  BÖHN ROLAND ,  STUTZ SUSANNE ,  NÖRENBERG RALF

IPC: C07C43/11 ,  C09K23/42 ,  C11D1/72 ,  C11D1/722 ,  C11D1/825

公开(公告)号：BRPI0513245A

公开(公告)日：2008-04-29

申请号：BRPI0513245

申请日：2005-07-15

Applicant: BASF AG

Inventor： WULFF CHRISTIAN ,  SEELMANN-EGGEBERT HANS-PETER ,  STUTZ SUSANNE ,  OETTER GUENTER

IPC: C09D5/00 ,  C08G65/00 ,  C09K23/42

Abstract: The present invention relates to a coating material formulation comprising a mixture comprising as component a1 at least one surfactant and as component a2 at least one compound corresponding to the general formula (I) R1-O-(CH2-CHR2-O)n-(CH2-CH2-O)m-R3 (I) in which R1 is phenyl or substituted phenyl, C4-C14 alkyl, R2 is C1-C8 alkyl, R3 is hydrogen, C1-C6 alkyl, benzoyl, acetyl, acryloyl, methacryloyl, n has an average value of 0 to 10, m has an average value of 1 to 10, where n+m n, and the alkylene oxide structural units, which are different if appropriate, can be distributed randomly or arranged in blocks, 1%-95% by weight of film-forming binders and resins, 0%-80% by weight of fillers, 0%-40% by weight of pigments, 0%-20% by weight of additives and 0%-90% by weight of organic solvents and/or water, the sum of the weight percentages being 100% by weight, and to the use of the mixture of the invention for lowering the surface tension in a coating material by addition to the coating material.

公开(公告)号：DE102004034646A1

公开(公告)日：2006-02-16

申请号：DE102004034646

申请日：2004-07-16

Applicant: BASF AG

Inventor： WULFF CHRISTIAN ,  SEELMANN-EGGEBERT HANS-PETER ,  STUTZ SUSANNE ,  OETTER GUENTER

IPC: C08G65/00 ,  C09D5/00 ,  C09D7/00 ,  C09K23/42

Abstract: The present invention relates to a coating material formulation comprising a mixture comprising as component a1 at least one surfactant and as component a2 at least one compound corresponding to the general formula (I) R1-O-(CH2-CHR2-O)n-(CH2-CH2-O)m-R3 (I) in which R1 is phenyl or substituted phenyl, C4-C14 alkyl, R2 is C1-C8 alkyl, R3 is hydrogen, C1-C6 alkyl, benzoyl, acetyl, acryloyl, methacryloyl, n has an average value of 0 to 10, m has an average value of 1 to 10, where n+m n, and the alkylene oxide structural units, which are different if appropriate, can be distributed randomly or arranged in blocks, 1%-95% by weight of film-forming binders and resins, 0%-80% by weight of fillers, 0%-40% by weight of pigments, 0%-20% by weight of additives and 0%-90% by weight of organic solvents and/or water, the sum of the weight percentages being 100% by weight, and to the use of the mixture of the invention for lowering the surface tension in a coating material by addition to the coating material.

公开(公告)号：CA2542644A1

公开(公告)日：2005-04-28

申请号：CA2542644

申请日：2004-10-14

Applicant: BASF AG

Inventor： KLUMPE MARKUS ,  NOERENBERG RALF ,  BOEHN ROLAND ,  TROPSCH JUERGEN ,  KAHL ROLF-DIETER ,  STUTZ SUSANNE

IPC: C07C43/11 ,  C09K23/42 ,  C11D1/72 ,  C11D1/722 ,  C11D1/825

Abstract: The alkoxylate mixtures comprise alkoxylates of the formula (I) C5H11CH(C3H7)CH2O(B)p(A)n(B)m(A)qH(I) where A is ethyleneoxy, B, in each case independently, are C3-10-alkyleneoxy or mixtures thereof, groups A and B being present in the form of blocks in the stated sequence, p is a number from 0 to 10, n is a number greater than 0 to 20, m is a number greater than 0 to 20, q is a number greater than 0 to 10, p+n+m+q is at least 1, from 70 to 99% by weight of alkoxylates A1, in which C5H11 is n-C5H11, and from 1 to 30% by weight of alkoxylates A2, in which C5H11 is C2H5CH(CH3)CH2 and/or CH3CH(CH3)CH2CH2, being present in the mixture.

公开(公告)号：CA2260814A1

公开(公告)日：1998-03-12

申请号：CA2260814

申请日：1997-08-21

Applicant: BASF AG

Inventor： RUEHL THOMAS ,  STUTZ SUSANNE ,  HENKELMANN JOCHEM ,  STAMMER ACHIM

IPC: B01J27/24 ,  C07C29/42 ,  C07C33/044

Abstract: The invention concerns a process for preparing alkyne diols or mixtures of alkyne diols with alkyne monools by reacting acetylene with more than equimolar amounts of ketones and/or aldehydes in the presence of an alkaline compound, the alkaline compound being used in a molar amount which is less than half the molar amount of the ketone and/or aldehyde to be reacted, in the presence of ammonia and/or at least one reactive primary amine.

公开(公告)号：BRPI0415391A

公开(公告)日：2006-12-12

申请号：BRPI0415391

申请日：2004-10-14

Applicant: BASF AG

Inventor： KLUMPE MARKUS ,  TROPSCH JUERGEN ,  KAHL ROLF-DIETER ,  BOEHN ROLAND ,  STUTZ SUSANNE ,  NOERENBERG RALF

IPC: C07C43/11 ,  C09K23/42 ,  C11D1/72 ,  C11D1/722 ,  C11D1/825

Abstract: The alkoxylate mixtures comprise alkoxylates of the formula (I) C5H11CH(C3H7)CH2O(B)p(A)n(B)m(A)qH(I) where A is ethyleneoxy, B, in each case independently, are C3-10-alkyleneoxy or mixtures thereof, groups A and B being present in the form of blocks in the stated sequence, p is a number from 0 to 10, n is a number greater than 0 to 20, m is a number greater than 0 to 20, q is a number greater than 0 to 10, p+n+m+q is at least 1, from 70 to 99% by weight of alkoxylates A1, in which C5H11 is n-C5H11, and from 1 to 30% by weight of alkoxylates A2, in which C5H11 is C2H5CH(CH3)CH2 and/or CH3CH(CH3)CH2CH2, being present in the mixture.

公开(公告)号：ES2133986T3

公开(公告)日：1999-09-16

申请号：ES96927693

申请日：1996-08-06

Applicant: BASF AG

Inventor： HEIDER MARC ,  RUHL THOMAS ,  HENKELMANN JOCHEM ,  STUTZ SUSANNE ,  PREISS THOMAS ,  RUTTER HEINZ

IPC: C07D307/33 ,  B01J31/20 ,  C07B61/00 ,  C07D307/32 ,  C07D307/58 ,  C07D315/00 ,  C07F7/08

Abstract: PCT No. PCT/EP96/03472 Sec. 371 Date Feb. 12, 1998 Sec. 102(e) Date Feb. 12, 1998 PCT Filed Aug. 6, 1996 PCT Pub. No. WO97/07111 PCT Pub. Date Feb. 27, 1997A process for the preparation of butyrolactones of the formula I where the substituents R1 and R2 are hydrogen, alkyl or hydroxyalkyl groups, or aryl and trialkylsilyl groups, if appropriate carrying inert: substituents, is described in which an alkyne of the formula IIR1-C 3BOND C-R2IIwhere the substituents have the meanings indicated above, is reacted under reducing conditions at elevated pressure and elevated temperature with carbon monoxide CO and hydrogen in the presence of a transition metal catalyst or with carbon monoxide and water in the presence of a transition metal catalyst.