MANUFACTURE OF SHEAR-RESISTANT AQUEOUS COPOLYMER EMULSIONS

    公开(公告)号:CA1035074A

    公开(公告)日:1978-07-18

    申请号:CA238879

    申请日:1975-11-03

    Applicant: BASF AG

    Abstract: Shear-resistant aqueous copolymer emulsions which can be used for sizing paper are manufactured by first copolymerizing, in the aqueous phase of an aqueous emulsion, using conventional polymerization initiators which form free radicals, (A) from 0.5 to 15 per cent by weight of monomers containing a polymerizable C=C bond and at least one carboxyl and/or sulfonic acid or phosphate or phosphite group with (B) from 5 to 30 per cent by weight of monomers containing a C=C bond and a tertiary or quaternary amino group, or a nitrogen-containing heterocyclic group, and then adding, while continuing the copolymerization, (C) from 0 to 94.5 per cent by weight of styrene and/or acrylonitrile and (D) from 0 to 94.5 per cent by weight of acrylic or methacrylic acid esters of alkanols of 1 to 8 carbon atoms as well as (E) from 0 to 30 per cent by weight of further olefinically unsaturated monomers, and completing the polymerization, the pH during the polymerization being less than 7 and the amount of monomers (C) and (D) together being at least 25 per cent by weight.

    THERMOPLASTIC MOLDING COMPOSITIONS

    公开(公告)号:AU7389487A

    公开(公告)日:1987-12-10

    申请号:AU7389487

    申请日:1987-06-05

    Applicant: BASF AG

    Abstract: Thermoplastic moulding compositions containing, as essential components, A) 5 - 95% by weight of a polyamide, B) 5 - 95% by weight of a modified polyphenylene ether prepared from b1) 4.95 - 99.95% by weight of a polyphenylene ether, b2) 0 - 90% by weight of a vinyl aromatic polymer b3) 0.05 - 10% by weight of b31) fumaric acid and/or b32) a maleimide of the formula I in which R , R and R are hydrogen, alkyl, alkoxy, cycloalkyl, alkenyl, aryl, arylene or alkylene groups having 1 - 12 carbon atoms, and/or b33) an amide-containing monomer having a polymerisable double bond, and/or b34) a lactam-containing monomer having a polymerisable double bond, and/or b35) a monoester or monoamide of an alpha , beta -unsaturated dicarboxylic acid, b4) 0 - 80% by weight of further graft-active monomers, and b5) 0 - 20% by weight of a free-radical initiator, C) 0 - 90% by weight of an unmodified polyphenylene ether, D) 0 - 45% by weight of a vinylaromatic polymer, and E) 0 - 40% by weight of an impact-modifying rubber.

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