STORAGE OF ACETYLENE-CONTAINING GASES BY MEANS OF METAL-ORGANIC FRAMEWORK MATERIALS
    2.
    发明申请
    STORAGE OF ACETYLENE-CONTAINING GASES BY MEANS OF METAL-ORGANIC FRAMEWORK MATERIALS 审中-公开
    乙炔气体的STORAGE使用金属有机骨架

    公开(公告)号:WO2008000694A3

    公开(公告)日:2008-02-28

    申请号:PCT/EP2007056231

    申请日:2007-06-22

    CPC classification number: F17C11/002 B01J20/226

    Abstract: The invention relates to methods for storing an acetylene-containing gas in a porous metal-organic framework material, said metal-organic framework material containing at least one, at least bidentate compound that is coordinately bound to at least one metal ion. The method according to the invention comprises the step of contacting the acetylene-containing gas with the metal-organic framework material, the metal-organic framework material being copper-free. The invention also relates to a porous metal-organic framework material which contains the acetylene-containing gas and to a corresponding acetylene gas-pressure container and the use thereof.

    Abstract translation: 本发明涉及到用于存储含乙炔的气体到多孔金属 - 有机骨架材料的方法中,有机金属骨架材料含有至少一种配位到至少一种金属,至少双齿有机化合物,含所述含乙炔气体与金属 - 有机骨架材料相接触的步骤, 其中所述金属 - 有机骨架材料是不含铜。 此外,本发明涉及一种多孔金属有机骨架材料,含乙炔的含有和相应的乙炔气体的压力容器,以及它们的用途的气体。

    METHOD FOR PRODUCING AN DMC CATALYST
    3.
    发明申请
    METHOD FOR PRODUCING AN DMC CATALYST 审中-公开
    用于生产DMC催化剂

    公开(公告)号:WO2006094979A2

    公开(公告)日:2006-09-14

    申请号:PCT/EP2006060517

    申请日:2006-03-07

    CPC classification number: B01J27/26 C08G65/2663

    Abstract: The invention relates to a method for producing DMC catalysts by reacting cyanometallate compounds, preferably cyanometallate salts, in particular, alkali or alkaline earth salts, with metal salts, wherein the inventive method is characterised in that it is carried out in the presence of a Bronsted acid.

    Abstract translation: 本发明涉及一种用于通过反应氰制备DMC催化剂的方法,优选碱金属或碱土金属盐Cyanometallatsalzen特别地,与金属的盐,其特征在于,在布朗斯台德酸的存在下反应进行。

    4.
    发明专利
    未知

    公开(公告)号:DE102005016152A1

    公开(公告)日:2006-10-12

    申请号:DE102005016152

    申请日:2005-04-07

    Applicant: BASF AG

    Abstract: The present invention relates to a process for preparing polyol alkyl ethers by reacting compounds comprising at least three hydroxyl functionalities with olefins in the presence of acidic catalysts at temperatures of from 20 to 250° C. and pressures of from 0.5 to 10 bar, wherein the olefins correspond to the general formula (I) in which R1 is hydrogen and R2 is a linear or branched carbon radical having from 7 to 28 carbon atoms, or R1 and R2 are each linear or branched carbon radicals having from 1 to 27 carbon atoms, the sum of the carbon number of R1 and R2 being at most 28, to polyol alkyl ethers derived from compounds having at least three hydroxyl functionalities, not more than all but one hydroxyl functionality being replaced by a moiety of the general formula (VIII) to the use of these polyol alkyl ethers as surfactants and to laundry detergents and cleaning compositions comprising these polyol alkyl ethers.

    6.
    发明专利
    未知

    公开(公告)号:DE102004038108A1

    公开(公告)日:2006-03-16

    申请号:DE102004038108

    申请日:2004-08-05

    Applicant: BASF AG

    Abstract: The present invention relates to a process for preparing alkylaromatics by reacting aromatic compounds with C1-C14-alkanes in the presence of a heterogeneous catalyst, which comprises using as the catalyst a crystalline, micro- and/or mesoporous solid comprising silicon and at least one father element selected from the group consisting of the transition metals and the main group elements gallium and tin, and activating said catalysts by a reducing pretreatment. Furthermore, the present invention relates to a process for preparing alkylarylsulfonates by sulfonating and neutralizing the alkyl aromatic compounds.

    PRODUCCION DE (CO) AGENTES TENSIOACTIVOS AL HACER REACCIONAR POLIOLES CON OLEFINAS.

    公开(公告)号:MX2007012263A

    公开(公告)日:2007-10-12

    申请号:MX2007012263

    申请日:2006-04-05

    Applicant: BASF AG

    Abstract: La invencion se refiere a un metodo para producir eteres de poliolalquilo al hacer reaccionar al menos tres compuestos teniendo funciones de hidroxi con olefinas en presencia de catalizadores acidos a temperaturas de entre 20 - 250 degree C y presiones de entre 0.5 - 10 bar. Las olefinas corresponden a la formula general (I), en donde R1 representa hidrogeno y R2 es radicales de carbono lineales o ramificados teniendo 7 - 28 atomos de carbono, o R1 y R2 respectivamente representan radicales de carbono lineales o ramificados teniendo 1 - 27 atomos de carbono, por lo que el numero de atomos de carbono de R1 y R2 es, a lo mucho, 28. La invencion tambien se refiere a eteres de poliolalquilo que se derivan de compuestos que tienen al menos tres funciones de hidroxi, o todas las funciones de hidroxi hasta que una es reemplazada por un grupo de la formula general (VIII). La invencion se refiere ademas a dichos eteres de polioalquilo como agentes tensioactivos y dichos agentes de lavado y limpieza conteniendo eteres de polioalquilo (ver formulas (I) y (VIII)).

    Preparing multi-metal cyanide compound, useful to prepare e.g. polyetherpolyol, comprises reacting aqueous solution of a metal salt and -cyanometallate compound to give a multi-metal cyanide compound followed by reacting with a salt

    公开(公告)号:DE102005057895A1

    公开(公告)日:2007-06-06

    申请号:DE102005057895

    申请日:2005-12-02

    Applicant: BASF AG

    Abstract: Preparation of multi-metal cyanide compound comprises reacting an aqueous solution of a metal salt (I) with an aqueous solution of a cyanometallate compound (II), optionally in the presence of an organic ligand, organic additive and/or surface active agent to give a multi-metal cyanide compound (III); and reacting (III) with a metal salt (IV), which is different from (II). Preparation of multi-metal cyanide compound comprises reacting an aqueous solution of a metal salt (I) of formula (M 1> gX n) with an aqueous solution of a cyanometallate compound (II) of formula (M 3> r[M 2>(CN) b] d), optionally in the presence of an organic ligand, organic additive and/or surface active agent to give a multi-metal cyanide compound (III) of formula (M 1> a[M 2>(CN) b] dfM 1> jX kh(H 2O)eLzP 1>); and reacting (III) with a metal salt (IV) of formula (M 4> sY 1> t), which is different from (II). M 1>a metal ion such as Zn 2+>, Fe 2+>, Fe 3+>, Co 2+>, Co 3+>, Ni 2+>, Mn 2+>, Sn 2+>, Sn 4+>, Pb 2+>, Al 3+>, Sr 2+>, Cr 3+>, Cd 2+>, Cu 2+>, La 3+>, Ce 3+>, Ce 4+>, Eu 3+>, Mg 2+>, Ti 4+>, Ag +>, Rh 2+>, Ru 2+>, Ru 3+> or Pd 2+>; M 2>a metal ion such as Fe 2+>, Fe 3+>, Co 2+>, Co 3+>, Mn 2+>, Mn 3+>, Ni 2+>, Cr 2+>, Cr 3+>, Rh 3+>, Ru 2+> or Ir 3+>; X : an anion such as halogenide, OH, sulfate, hydrogensulfate, carbonate, hydrogencarbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate, nitrate and/or nitrite (NO 2 ->) or uncharged species such as CO, H 2O or NO; Y 1>an anion such as halogenide, sulfate, hydrogensulfate, disulfate, sulfite, sulfonate (=RSO 3 ->, where R is 1-20C alkyl, aryl or 1-20C alkylaryl), carbonate, hydrogencarbonate, cyanide, thiocyanate, isocyanate, isothiocyanate, cyanate, carboxylate, oxalate, nitrate, nitrite, phosphate, hydrogenphosphate, dihydrogenphosphate, diphosphate, borate, tetraborate, perchlorate, tetrafluoroborate, hexafluorophosphate or tetraphenylborate; L : a ligand, mixable with water, such as alcohol, aldehyde, ketone, ether, polyether, ester, polyester, polycarbonate, urea, amide, nitrile and/or sulfide; P 1>an organic additives such as polyether, polyester, polycarbonate, polyalkyleneglycolsorbitaneester, polyalkyleneglycolglycidylether, polyacrylamide, poly(acrylamide-co-acrylic acid), polyacrylic acid, poly(acrylamide-co-maleic acid), polyacrylnitrile, polyalkylacrylate, polyalkylmethacrylate, polyvinylmethylether, polyvinylethylether, polyvinylacetate, polyvinylalcohol, poly-N-vinylpyrrolidone, poly(N-vinylpyrrolidone-co-acrylic acid), polyvinylmethylketone, poly(4-vinylphenol), poly(acrylic acid-co-styrene), oxazoline polymer, polyalkyl imine, maleic acid, maleic acid anhydride copolymer, hydroxyethylcellulose, polyacetate, ionic surfaces and surface area active compound, gallic acid or its salt, ester, amide, carbonic acid ester of polyvalent alcohols or glycoside; M 3>H or an alkali- or alkaline earth metal; M 4>alkalimetal ion or an ammonium ion (NH 4 +>) or alkylammonium ion (R 4N +>, R 3NH +>, R 2NH 2 +>, RNH 3 +> (where R is 1-20C alkyl)); and a, b, d-g, n, r, s, j, k, t : a whole or fractional number that is greater than zero (where a, b, d, g, n, j, k, r, s and t are selected such that the electro neutrality is assured); and e, f, h, z : greater than or equal to 0. Provided that M 1> and M 2> are same or different. Independent claims are included for: (1) a multi-metal cyanide compound (V) of formula (M 1> a[M 2>(CN) b] dfM 1> uX vY 1> mh(H 2O)eLzP) that is prepared from the above process; and (2) the preparation of polyetheralcoholene comprising adding an alkylene oxide to a hydrogen functionalized starting substance, where multi-metal cyanide compound is used as a catalyst. u, v, m : whole or fractional numbers that are greater than zero, where the electro neutrality is assured.

    10.
    发明专利
    未知

    公开(公告)号:BRPI0607908A2

    公开(公告)日:2010-03-30

    申请号:BRPI0607908

    申请日:2006-04-05

    Applicant: BASF AG

    Abstract: The present invention relates to a process for preparing polyol alkyl ethers by reacting compounds comprising at least three hydroxyl functionalities with olefins in the presence of acidic catalysts at temperatures of from 20 to 250° C. and pressures of from 0.5 to 10 bar, wherein the olefins correspond to the general formula (I) in which R1 is hydrogen and R2 is a linear or branched carbon radical having from 7 to 28 carbon atoms, or R1 and R2 are each linear or branched carbon radicals having from 1 to 27 carbon atoms, the sum of the carbon number of R1 and R2 being at most 28, to polyol alkyl ethers derived from compounds having at least three hydroxyl functionalities, not more than all but one hydroxyl functionality being replaced by a moiety of the general formula (VIII) to the use of these polyol alkyl ethers as surfactants and to laundry detergents and cleaning compositions comprising these polyol alkyl ethers.

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