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    HYDROGENATION OF POLYENE TO MONOENE
    1.
    发明专利
    HYDROGENATION OF POLYENE TO MONOENE 失效

    公开(公告)号：JP2000169402A

    公开(公告)日：2000-06-20

    申请号：JP34746099

    申请日：1999-12-07

    Applicant: BASF AG

    Inventor： PINKOS ROLF

    IPC: B01J31/24 ,  C07B61/00 ,  C07C5/05 ,  C07C5/09 ,  C07C13/263 ,  C07C13/275

    Abstract: PROBLEM TO BE SOLVED: To provide a method for hydrogenating a polyene by which the reaction can be carried out without using a large amount of expensive catalyst and without using a solvent or at least by using the solvent in the minimum amount with extremely high yield from quantitative conversion by carrying out the hydrogenation in the presence of a carboxylic acid. SOLUTION: The hydrogenation is carried out in the presence of (C) a carboxylic acid when hydrogenating (B) a polyene to a corresponding monoene by using (A) a homogeneous system of a ruthenium catalyst. Preferably, the component A is generated in situ in the presence of CO or formaldehyde, and the hydrogenation is carried out in the presence of triphenylphosphine at 50-300 deg.C under 1-300 bar. The component B is preferably 1,5,9-cyclododecatriene or cyclooctadiene, and 0.1-2,000 mg ruthenium (expressed in terms of metal) is used based on 1 kg component B. Further the component C is preferably a 1-20C monocarboxylic acid or the like.

    Method for producing tetrahydrofuran-copolymer
    2.
    发明专利
    Method for producing tetrahydrofuran-copolymer 审中-公开
    生产四氢呋喃共聚物的方法

    公开(公告)号：JP2005179673A

    公开(公告)日：2005-07-07

    申请号：JP2004363611

    申请日：2004-12-15

    Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフト

    Inventor： HAUBNER MARTIN ,  PINKOS ROLF ,  WOHLFARTH MICHAEL ,  WECK ALEXANDER

    IPC: C08G65/26 ,  C08G65/20 ,  C08G65/28

    CPC classification number: C08G65/20 ,  C08G65/34

    Abstract: PROBLEM TO BE SOLVED: To provide a method for copolymerizing THF with an α, ω-diol in the presence of heteropolyacid, more economically, at a higher polymerization conversion, and more accurately in control of average-molecular weight.
    SOLUTION: The method for continuously producing tetrahydrofuran-copolymer comprises copolymerizing tetrahydrofuran with an α, ω-diol in a reaction cascade in the presence of a heteropolyacid and a telogen, wherein the telogen and/or the α, ω-diol are added in the first reactor of the cascade and water is distilled away from at least one reactor to outside the polymerization reaction.
    COPYRIGHT: (C)2005,JPO&NCIPI

    Abstract translation: 待解决的问题：为了提供在杂多酸存在下，更经济地，更高的聚合转化率，更准确地控制平均分子量的THF与THF，THF的共聚方法。 解决方案：连续生产四氢呋喃共聚物的方法包括在杂多酸和脱氨基的存在下，在反应级联中使四氢呋喃与α，ω-二醇共聚，其中前体和/或α，ω-二醇是 加入到级联的第一反应器中，并将水从至少一个反应器蒸馏除去聚合反应。 版权所有（C）2005，JPO＆NCIPI

    PROCESS FOR THE PREPARATION OF AN N-ALKYL LACTAM WITH IMPROVED COLOUR QUALITY
    8.
    发明申请
    PROCESS FOR THE PREPARATION OF AN N-ALKYL LACTAM WITH IMPROVED COLOUR QUALITY 审中-公开
    方法用于生产N-烷基酰胺类抗生素与改善颜色质量

    公开(公告)号：WO2007115943A3

    公开(公告)日：2008-03-27

    申请号：PCT/EP2007053008

    申请日：2007-03-29

    Applicant: BASF AG ,  WABNITZ TOBIAS ,  PINKOS ROLF ,  OTT KARL

    Inventor： WABNITZ TOBIAS ,  PINKOS ROLF ,  OTT KARL

    IPC: C07D201/18 ,  C07D207/26 ,  C07D211/76 ,  C07D223/10

    CPC classification number: C07D201/18 ,  C07D207/267 ,  C07D211/76 ,  C07D223/10

    Abstract: Process for the preparation of an N-alkyl lactam with improved colour quality, where 0.01 to 10% by weight of a C 1-10 -alcohol or a compound which releases 0.01 to 10% by weight of a C 1-10 -alcohol is added to the N-alkyl lactam. Mixture comprising at least 99.0% by weight of an N-alkyl lactam and in the range from 100 to 5000 ppm by weight of a C 1-10 -alcohol or of an acetal, aminal or an ortho ester which releases in the range from 100 to 5000 ppm by weight of a C 1-10 -alcohol.

    Abstract translation: 一种制备N-烷基内酰胺过程具有改善的颜色质量，这是N-烷基内酰胺为0.01〜10重量是C 1-10 醇的％或含0的化合物 01至10重量是C 的1-10％释放醇，加入。 混合物包含按重量计为C 1-10 醇或缩醛，缩醛胺，或原酸酯的N-烷基内酰胺类的和在100〜5000ppm的范围内的至少99.0重量％， 按重量计为C 1-10 的/释放在100至5000ppm的范围内的醇。

    METHOD FOR THE PRODUCTION OF TETRAHYDROFURAN COPOLYMERS
    10.
    发明申请
    METHOD FOR THE PRODUCTION OF TETRAHYDROFURAN COPOLYMERS 审中-公开
    用于生产四氢呋喃的共聚物

    公开(公告)号：WO2004087787A3

    公开(公告)日：2005-01-06

    申请号：PCT/EP2004003345

    申请日：2004-03-30

    Applicant: BASF AG ,  HAUBNER MARTIN ,  PINKOS ROLF ,  SCHLITTER STEPHAN

    Inventor： HAUBNER MARTIN ,  PINKOS ROLF ,  SCHLITTER STEPHAN

    IPC: C08G65/20

    CPC classification number: C08G65/20 ,  C08G2650/08 ,  C08G2650/68

    Abstract: The invention relates to a method for single-step production of polyoxyalkylene glycols by copolymerization of THF and neopentyl glycol in the presence of a heteropoly acid, characterized in that the overall amount of all impurities of general formula (I), wherein R and R represent hydrogen when R is an oxyformyl or isopropionate radical, R represents hydrogen and R represents hydroxy when R is an isopropyl radical and R represents hydrogen when R and R together represent an OCH2-C(CH3)-CH2 radical, in the neopentyl glycol is less than 1000 ppm.

    Abstract translation: 本发明是一种用于单级制备聚氧化烯二醇的通过THF和在杂多酸的存在下的新戊二醇的共聚发现，其特点是在一个过程，在通式（I）的所有杂质的总量，其中R <1>和R <2 意味着>氢，当R <3>是Oxyformyl-或Isopropionatrest，R <2>的羟基<1>是氢并且R，当R <3>表示异丙基团和R <1>是氢，当R <2> 且R <3>一起形成-OCH 2 C（CH 3）-CH 2残基，新戊基二醇是小于1000ppm。

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