公开(公告)号：DE59709137D1

公开(公告)日：2003-02-20

申请号：DE59709137

申请日：1997-10-13

Applicant: BASF AG

Inventor： VOIT DR ,  DERNBACH DR ,  BECK KARL ,  HOLDERBAUM DR ,  WEYER DR

IPC: C07C249/02 ,  C07C251/24

Abstract: Water and ammonia are removed from crude benzophenone-imines obtained by the catalytic reaction of ammonia with benzophenones of formula (I), in which R , R = (a) halogen, hydroxyl, nitro or amino groups, (b) 1-12C linear, branched or cyclic alkyl or alkoxy, optionally substituted with 6-10C aryl, F, Cl or Br, (c) 6-10C aryl or aryloxy, optionally substituted with 1-12C alkyl or alkoxy, (d) heteroalkyl groups comprising alkyl groups as above with in-chain O, S and/or N atom(s), or (e) heteroaryl groups with 5-10 ring atoms containing 1-3 O, S and/or N atoms; m, n = 0-5. The process comprises removing the ammonia by distillation and removing the water by distillation or with a drying agent.

公开(公告)号：DE59608407D1

公开(公告)日：2002-01-24

申请号：DE59608407

申请日：1996-04-26

Applicant: BASF AG

Inventor： BREITSCHEIDEL DR ,  POLANEK DR ,  VOIT DR ,  WITZEL DR ,  LINDEN DR ,  HESSE MICHAEL DR

IPC: B01J23/78 ,  B01J23/889 ,  B01J27/185 ,  B01J27/187 ,  C07B61/00 ,  C07C209/48 ,  C07C209/52 ,  C07C211/03

Abstract: Cobalt catalysts (I) are claimed, in which the active material contains 55-98 wt% Co, 0.2-15 wt% P, 0.2-15 wt% Mn and 0.05-5 wt% alkali metal, calcd. as oxide. The calcined catalyst is reduced in a stream of hydrogen at final temps. of 200-400 degrees C and then surface-oxidised in a stream of air at final temps. of 20-60 degrees C. Also claimed is a process for the hydrogenation of organic nitriles and/or imines at 60-150 degrees C and 50-300 bar using (I) as catalyst.

公开(公告)号：DE59812284D1

公开(公告)日：2004-12-30

申请号：DE59812284

申请日：1998-03-04

Applicant: BASF AG

Inventor： VOIT DR ,  WITZEL DR ,  JULIUS DR

IPC: C07D211/12 ,  B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J31/02 ,  C07B61/00 ,  C07D211/58

公开(公告)号：DE59510031D1

公开(公告)日：2002-03-14

申请号：DE59510031

申请日：1995-11-03

Applicant: BASF AG

Inventor： HOLDERBAUM DR ,  AUMUELLER DR ,  TRAUTH HUBERT ,  VOIT DR ,  SPERLING DR ,  KRAUSE DR

IPC: C07D211/14 ,  C07B63/04 ,  C07C253/30 ,  C07C255/19 ,  C07C255/23 ,  C07C255/30 ,  C07C255/41 ,  C07C255/42 ,  C07D211/46 ,  C08K5/315 ,  C08K5/3435 ,  C09D7/12 ,  C09K3/00 ,  C09K15/16 ,  C09K15/20

Abstract: 2-Cyanoacrylic esters (I) of alpha , omega -bis(4-hydroxy-2,2,6,6-tetramethylpiperid-1-yl)alkanes or (cyclo)aliphatic polyols of the given formula (I) are new. R , R = the radical of an iso- or heterocyclic ring system with at least one iso- or heteroaromatic ring and ≥ 1 of R and R is not H, n = 2-10, if n = 2, X = a gp. of formula (II), m = 2-8; if n = 3-10, X = the radical of an n-hydric 3-20C (cyclo)aliphatic polyol, opt. with 1 or 2 heteroatoms in the cycloaliphatic gp. and up to 8 non-adjacent O or S atoms or -NH- or 1-4C alkylimino gps. in the aliphatic chain. Also claimed are various materials stabilised against the action of light, O2 and heat with (I).