公开(公告)号：DE59804038D1

公开(公告)日：2002-06-13

申请号：DE59804038

申请日：1998-11-24

Applicant: BASF AG

Inventor： FRIEDRICH WOLFGANG ,  KNEUPER DR ,  ELLER DR ,  WITZEL DR

IPC: C07D487/04 ,  C07D239/06 ,  C07D471/04

Abstract: Preparation of bicyclic amidine derivatives with continual removal of water during reaction. Bicyclic amidine derivatives of formula (1) are prepared by reacting a lactone of formula (2) with a diamine of formula (3), during which water is removed while the reaction is taking place. Rx, Ry, Ra, Rb = independently H, or 1-10C alkyl, 2-10C alkenyl, 2-10C alkynyl or 6-12C aryl, optionally substituted by OH, NH2, 1-4C alkylamino or SH; m, n = 2-12; a, b, x and y actually = number of carbon atoms in the R groups, which correspond to values of n+1 or m+1. Independent claims are also included for the following: (I) A diazacycloalkane of formula (4); (II) Preparation of diazacycloalkane (4); and (III) Use of diazacycloalkane (4) as an intermediate in production of bicyclic amines of formula (1). Rx, Ry, Ra, Rb = independently H, or 1-10C alkyl, 2-10C alkenyl, 2-10C alkynyl or 6-12C aryl, optionally substituted by OH, NH2, 1-4C alkylamino or SH; m, n = 2-12; a, b, x and y actually = number of carbon atoms in the R groups, which correspond to values of n+1 or m+1.

公开(公告)号：DE59608407D1

公开(公告)日：2002-01-24

申请号：DE59608407

申请日：1996-04-26

Applicant: BASF AG

Inventor： BREITSCHEIDEL DR ,  POLANEK DR ,  VOIT DR ,  WITZEL DR ,  LINDEN DR ,  HESSE MICHAEL DR

IPC: B01J23/78 ,  B01J23/889 ,  B01J27/185 ,  B01J27/187 ,  C07B61/00 ,  C07C209/48 ,  C07C209/52 ,  C07C211/03

Abstract: Cobalt catalysts (I) are claimed, in which the active material contains 55-98 wt% Co, 0.2-15 wt% P, 0.2-15 wt% Mn and 0.05-5 wt% alkali metal, calcd. as oxide. The calcined catalyst is reduced in a stream of hydrogen at final temps. of 200-400 degrees C and then surface-oxidised in a stream of air at final temps. of 20-60 degrees C. Also claimed is a process for the hydrogenation of organic nitriles and/or imines at 60-150 degrees C and 50-300 bar using (I) as catalyst.

公开(公告)号：DE59812284D1

公开(公告)日：2004-12-30

申请号：DE59812284

申请日：1998-03-04

Applicant: BASF AG

Inventor： VOIT DR ,  WITZEL DR ,  JULIUS DR

IPC: C07D211/12 ,  B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J31/02 ,  C07B61/00 ,  C07D211/58