Abstract:
PROBLEM TO BE SOLVED: To provide a method for depositing copper layers on substrates without the aid of an electroless plating method and a dispersion liquid method including metallic particulates. SOLUTION: The copper layers are deposited on the substrates by bringing the substrate into contact with a product mixture composed of copper (II) formate and alkoxyalkylamines of formula I: R 1 -O-(CH 2 ) n -CHR 2 -NH 2 (R 1 is methyl or ethyl, R 2 is hydrogen or methyl and n is 1, 2, 3 or 4) at 80-200°C and under a pressure of 0.1-5 bar. COPYRIGHT: (C)2005,JPO&NCIPI
Abstract:
Disclosed is a method for purifying caprolactam made from lysin by treating caprolactam with an acid or an acidic ion exchanger. Also disclosed is the use for producing high-molecular polyamide (polyamide 6).
Abstract:
Copper (I) formate complexes of general formula LnCu(HCOO) . x COOH are decomposed in order to separate metallic copper, wherein x is a number from 0 to 10, n amounts to, 2, 3 or 4 and the n ligands L represent, independent of one another, one of the following ligands: a phosphane of formula R R R P; a phosphite of formula (R O)(R O)(R O)P; an isocyanide of formula R -NC; an alkene of general formula R R C=CR R ; or an alkyne of general formula R C=CR ; wherein R , R , R and R represent, independent of one another, hydrogen, a linear or branched, optionally partly or fully fluorinated alkyl, aminoalkyl, alkyoxialkyl, hydroxialkyl, phosphinoalkyl or aryl radical having up to 20 carbon atoms, with the exception of triphenylphosphino-copper (I) formate and 1,1,1-tris(diphenylphosphinomethyl)ethane-copper (I) formate.
Abstract:
Copper (I) formate complexes of general formula LnCu(HCOO).x COOH are decomposed in order to separate metallic copper, wherein x is a number from 0 to 10, n amounts to, 2, 3 or 4 and the n ligands L represent, independent of one another, one of the following ligands: a phosphane of formula R1R2R3P; a phosphite of formula (R1O)(R2O)(R3O)P; an isocyanide of formula R1—NC; an alkene of general formula R1R2C═CR3R4; or an alkyne of general formula R1C═CR2; wherein R1, R2, R3 and R4 represent, independent of one another, hydrogen, a linear or branched, optionally partly or fully fluorinated alkyl, aminoalkyl, alkyoxialkyl, hydroxialkyl, phosphinoalkyl or aryl radical having up to 20 carbon atoms, with the exception of triphenylphosphino-copper (I) formate and 1,1,1-tris(diphenylphosphinomethyl)ethane-copper (I) formate.
Abstract:
Process for depositing copper layers on a substrate comprises contacting the substrate with a compound consisting of copper-II-formate and alkoxyalkylamines of formula: R1O(CH2)nCHR2NH2 (where R1 = methyl or ethyl; R2 = hydrogen or methyl; and n = 1-4) at 80-200[deg] C and 0.1-5 bar. An independent claim is also included for a mixture containing compounds consisting of copper-II-formate and the above alkoxyalkylamines.
Abstract:
A process for preparing N,N-dihydrocarbylhydroxylamines of the general formula (I) where R 1 , R 2 , R 3 and R 4 are selected independently from among hydrogen, aliphatic, cycloaliphatic, heteroaromatic and aromatic radicals, or R 1 and R 2 and/or R 3 and R 4 are joined to form a ring, and not more than one radical among R 1 , R 2 , R 3 and R 4 is hydrogen, which comprises the steps a) reaction of hydroxylamine H 2 NOH or a salt of hydroxylamine with a compound of the general formula (II) or (III) where R 1 , R 2 , R 3 and R 4 are as defined in formula (I), b) hydrogenation of the compound formed in step a) in the presence of a catalyst, c) further reaction of the compound formed in step b) with a compound of the general formula (II) or (III) and hydrogenation of the reaction mixture in the presence of a catalyst and d), if appropriate, reaction of the salt of the dihydrocarbylhydroxylamine formed in step c) with a base.
Abstract:
The invention relates to the use of 1, 3 substituted imidazolium salts of the formula (I), R1 and R3 independently representing an organic group having 1 to 20 C atoms, R2, R4, and R5 independently representing a H atom or an organic group having 1 to 20 C atoms, R4 and R5 also together being able to form an aliphatic or aromatic ring, X representing an anion having a pK B value of less than 13 (measured at 25°C, 1 bar in water or dimethylsulfoxide), and n representing 1, 2 or 3, where 1-ethyl-2,3-dimethylimidazolium acetate and 1-ethyl-2,3-dimethylimidazoliumacetate-acetic acid complex are excluded as the imidazolium salt, as a latent catalyst for curing compositions comprising epoxy compounds.
Abstract:
Copper(I)perfluorocarboxylate-complex (I), is new. Copper(I)perfluorocarboxylate-complex (I) of formula ([L 1>nCuL 2>] m), is new. L 1>P(OR 1>) 3or PR 2>3; R 1>optionally fluoro-substituted 1-4C alkyl; R 2>CH 3, C 2H 5, n-C 3H 7, iso-C 3H 7, n-C 4H 9, i-C 4H 9, t-C 4H 9, cyclopropyl, cyclobutyl or cyclopentyl; L 2>R 3>-COO ->; R 3>perfluorinated 1-4C alkyl (when n is 1, m is 1 and L 1>is P(OR 1>) 3); n : 1-4; and m : 1-6. Provided that R 1>is not CH 3or C 4H 9. Independent claims are included for: (1) the preparation of (I); and (2) a procedure for separating metallic copper on a substrate comprising applying a complex on the substrate and decomposing the complex.