Joint separation of acetylene and ethylene from cracked gases
    1.
    发明授权
    Joint separation of acetylene and ethylene from cracked gases 失效
    乙烯和乙烯从裂缝气体的联合分离

    公开(公告)号:US3635038A

    公开(公告)日:1972-01-18

    申请号:US3635038D

    申请日:1969-05-16

    Applicant: BASF AG

    Abstract: A gas mixture (obtained by thermal cracking of hydrocarbons followed by quenching of the cracked gas and freed from carbon dioxide and water) is separated into a gas mixture containing hydrogen, carbon monoxide and methane and another gas mixture containing ethylene, acetylene and higher hydrocarbons by (a) cooling the gas mixture which is at superatmospheric pressure in at least one condensation stage to a temperature which is above the solidification temperature of acetylene mixed with the other condensed constituents, (b) separating the condensate thus obtained and subdividing it in a rectifying column into a first mixture containing C2 hydrocarbons and a second mixture containing C3 and higher hydrocarbons, and (c) freeing the residual gas remaining from (a) from residual acetylene and ethylene in a scrubber by treatment with some of the mixture consisting of C3 and higher hydrocarbons from (b).

    Abstract translation: 将气体混合物(通过烃的热裂化,然后淬灭裂化气体并从二氧化碳和水中除去)分离成含有氢气,一氧化碳和甲烷的气体混合物,以及含有乙烯,乙炔和高级烃的另一气体混合物 (a)在至少一个冷凝阶段将高于大气压的气体混合物冷却至高于其他冷凝组分混合的乙炔凝固温度的温度,(b)将由此获得的冷凝物分离,并将其细分为精馏 塔进入含有C 2烃和含有C 3和更高级烃的第二混合物的第一混合物,和(c)通过用一些由C 3和C 3组成的混合物处理将来自(a)残留的残余气体从残留的乙炔和乙烯中释出的第一混合物 (b)的高级烃。

    2.
    发明专利
    未知

    公开(公告)号:NO801034L

    公开(公告)日:1980-10-13

    申请号:NO801034

    申请日:1980-04-10

    Applicant: BASF AG

    Abstract: Anhydrous or substantially anhydrous formic acid is obtained by hydrolysis of methyl formate, in a process wherein (a) methyl formate is hydrolyzed, (b) the methanol and excess methyl formate are distilled from the hydrolysis mixture obtained, (c) the bottom product of distillation (b), consisting of formic acid and water, is extracted, in a liquid-liquid extraction, with an extractant which in the main takes up the formic acid, (d) the resulting extract phase, consisting of formic acid, the extractant and a part of the water, is subjected to distillation, (e) the top product obtained from this distillation and consisting of all or part of the water introduced into the distillation, and part of the formic acid, is recycled, as vapor, into the lower part of the distillation column of stage (b), (f) the bottom product of distillation stage (d), consisting of the extractant, with or without part of the water, and the greater part of the formic acid, is separated by distillation into anhydrous or substantially anhydrous formic acid and the extractant, and (g) the extractant leaving stage (f) is recycled to the process.

    PRODUCTION OF ANHYDROUS FORMIC ACID

    公开(公告)号:AU528657B2

    公开(公告)日:1983-05-05

    申请号:AU5729680

    申请日:1980-04-10

    Applicant: BASF AG

    Abstract: Anhydrous or substantially anhydrous formic acid is obtained by hydrolysis of methyl formate, in a process wherein (a) methyl formate is hydrolyzed, (b) the methanol and excess methyl formate are distilled from the hydrolysis mixture obtained, (c) the bottom product of distillation (b), consisting of formic acid and water, is extracted, in a liquid-liquid extraction, with an extractant which in the main takes up the formic acid, (d) the resulting extract phase, consisting of formic acid, the extractant and a part of the water, is subjected to distillation, (e) the top product obtained from this distillation and consisting of all or part of the water introduced into the distillation, and part of the formic acid, is recycled, as vapor, into the lower part of the distillation column of stage (b), (f) the bottom product of distillation stage (d), consisting of the extractant, with or without part of the water, and the greater part of the formic acid, is separated by distillation into anhydrous or substantially anhydrous formic acid and the extractant, and (g) the extractant leaving stage (f) is recycled to the process.

    10.
    发明专利
    未知

    公开(公告)号:NO152371C

    公开(公告)日:1985-09-18

    申请号:NO801034

    申请日:1980-04-10

    Applicant: BASF AG

    Abstract: Anhydrous or substantially anhydrous formic acid is obtained by hydrolysis of methyl formate, in a process wherein (a) methyl formate is hydrolyzed, (b) the methanol and excess methyl formate are distilled from the hydrolysis mixture obtained, (c) the bottom product of distillation (b), consisting of formic acid and water, is extracted, in a liquid-liquid extraction, with an extractant which in the main takes up the formic acid, (d) the resulting extract phase, consisting of formic acid, the extractant and a part of the water, is subjected to distillation, (e) the top product obtained from this distillation and consisting of all or part of the water introduced into the distillation, and part of the formic acid, is recycled, as vapor, into the lower part of the distillation column of stage (b), (f) the bottom product of distillation stage (d), consisting of the extractant, with or without part of the water, and the greater part of the formic acid, is separated by distillation into anhydrous or substantially anhydrous formic acid and the extractant, and (g) the extractant leaving stage (f) is recycled to the process.

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