FLUORINATED ACRYLATE BLOCK COPOLYMERS WITH LOW DYNAMIC SURFACE TENSION
    1.
    发明申请
    FLUORINATED ACRYLATE BLOCK COPOLYMERS WITH LOW DYNAMIC SURFACE TENSION 审中-公开
    具有低动态表面张力的氟化丙烯酸酯嵌段共聚物

    公开(公告)号:WO2013124421A9

    公开(公告)日:2013-12-19

    申请号:PCT/EP2013053567

    申请日:2013-02-22

    Applicant: BASF SE

    Abstract: The present invention relates to a composition, comprising a binder resin, a block copolymer which comprises at least a block A and a block B, wherein the block A comprises monomer units derived from a compound selected from (meth)acrylic acid, a (meth)acrylic acid ester, a (meth)acrylamide, a vinyl aromatic compound, or any mixture thereof, the block B comprises monomer units derived from a compound selected from a fluorinated (meth)acrylic ester having the following formula (I): H2C=C(R1)(C(0)ORF-1), wherein R1 is H or methyl; and RF-1 is an organic residue containing a perfluorinated C4-6 alkyl group, a fluorinated alpha-olefm having the following formula (II): H2C=CH(RF-2) (II) wherein RF-2 is an organic residue containing a perfluorinated C4-6 alkyl group, i.e. -(CF2)3-5-CF3 or any mixture thereof.

    Abstract translation: 本发明涉及包含粘合剂树脂,至少包含嵌段A和嵌段B的嵌段共聚物的组合物,其中嵌段A包含衍生自选自(甲基)丙烯酸,(甲基)丙烯酸, )丙烯酸酯,(甲基)丙烯酰胺,乙烯基芳族化合物或其任何混合物,嵌段B包含衍生自选自具有下式(I)的氟化(甲基)丙烯酸酯的化合物的单体单元:H 2 C = C(R 1)(C(O)ORF-1),其中R 1为H或甲基; 并且RF-1是含有全氟化C 4-6烷基的有机残基,具有下式(II)的氟化α-烯烃:H 2 C = CH(RF-2)(II)其中RF-2是含有 全氟化C 4-6烷基,即 - (CF 2)3-5-CF 3或其任何混合物。

    NOVEL POLYMER DISPERSANTS
    2.
    发明申请
    NOVEL POLYMER DISPERSANTS 审中-公开
    新型聚合物分散剂

    公开(公告)号:WO2013124830A9

    公开(公告)日:2013-10-31

    申请号:PCT/IB2013051454

    申请日:2013-02-22

    Abstract: The present invention relates to novel polymer dispersants and to a liquid compositions containing solid fine particles, such as organic or inorganic pigments and fillers, and the polymer dispersants. The polymer dispersants have at least one functional moiety of the formula I, which is bound to one of the termini or to the backbone of the polymer: (I) where # indicates the point of attachment to the terminus and/or to the polymer backbone; k is 0, 1, 2, 3 or 4, m is 0, 1, 2, 3, 4, 5, 6, 7, 8 or 9, A is a chemical bond or a divalent moiety selected from the group consisting of C1-C6 alkylene, -O-(C2-C6 alkylene), -C(=O-O-(C2-C6 alkylene), -N R3-(C2-C6 alkylene) and C(=O)-NR3-(C2-C6 alkylene), where the C2-C6 alkylene part is attached to Q; Q is a divalent moiety selected from the group consisting of -O-, -N H- and -S-; R1 is independently selected from the group consisting of -OH, -COOH, -COOCH3, -NH2, -NH( C1-C6 alkyl), -N(C1-C6 alkyl)2, -NO2, -S(=O)2R4, C1-C20 alkyl, C1-C4 alkoxy, halogen, aryloxy, aryl, heteroaryl; R2 is selected from the group consisting of hydrogen, -S(=O)2R4, C1-C20 alkyl, C3-C10 cycloalkyl, aryl, heteroaryl, aryl-C1-C4-alkyl and heteroaryl-C1-C4- alkyl; R3 is selected from the group consisting of hydrogen, -S(=O)2R4, C1-C20 alkyl, C3-C10 cycloalkyl, aryl and heteroaryl; R4 is selected from the group consisting of OH, -NH2, -NH(C1-C6 alkyl), -N(C1- C6 alkyl)2, C1-C4 alkyl, C1-C4 alkoxy, aryl and heteroaryl.

    Abstract translation: 本发明涉及新型聚合物分散剂和含有固体微粒例如有机或无机颜料和填料以及聚合物分散剂的液体组合物。 聚合物分散剂具有至少一个式I的功能部分,其结合到聚合物的末端或主链之一:(I)其中#表示与末端和/或与聚合物骨架的连接点 ; k为0,1,2,3或4,m为0,1,2,3,4,5,6,7,8或9,A为化学键或选自C1 -C(O) - (C 2 -C 6亚烷基),-C(= O)-NR 3 - (C 2 -C 6亚烷基) 亚烷基),其中C 2 -C 6亚烷基部分连接到Q; Q是选自-O - , - NH-和-S-的二价基团; R 1独立地选自-OH ,-COOH,-COOCH 3,-NH 2,-NH(C 1 -C 6烷基),-N(C 1 -C 6烷基)2,-NO 2,-S(= O)2 R 4,C 1 -C 20烷基,C 1 -C 4烷氧基, 卤素,芳氧基,芳基,杂芳基; R 2选自氢,-S(= O)2 R 4,C 1 -C 20烷基,C 3 -C 10环烷基,芳基,杂芳基,芳基-C 1 -C 4烷基和杂芳基 - C 1 -C 4烷基; R 3选自氢,-S(= O)2 R 4,C 1 -C 20烷基,C 3 -C 10环烷基,芳基和杂芳基; R 4选自OH,-NH 2 ,-NH(C 1 -C 6烷基),-N(C 1 -C 6烷基)2,C 1 -C 4烷基,C 1 -C 4烷氧基,芳基和t eroaryl。

    BLOCK COPOLYMERS HAVING A POLYDIMETHYLSILOXANE BLOCK
    3.
    发明申请
    BLOCK COPOLYMERS HAVING A POLYDIMETHYLSILOXANE BLOCK 审中-公开
    WITH A聚二甲基硅氧烷嵌段的嵌段共聚物

    公开(公告)号:WO2014111503A3

    公开(公告)日:2014-10-09

    申请号:PCT/EP2014050874

    申请日:2014-01-17

    Applicant: BASF SE

    Abstract: The present invention relates to novel block copolymers of general formula (I). The invention further relates to a method for producing such block copolymers and to the use of such block copolymers, particularly as additives in liquid coating-agent compositions. A{X-[O-C(O)NH-Y-NH-C(O)-O-M-B]k}n (I). In formula (I), the variables have the following meanings: n is a number in the range from 1 to 40 or 2 to 40, particularly 1 to 10 or 2 to 10 and especially 2 to 5; k is 1 or 2; A is a poly(dimethylsiloxane) block; B is a polymer block constructed of ethylenically unsaturated monomers, which optionally comprises a terminal group different from hydrogen; X is a bivalent or trivalent group having 2 to 20 C atoms, which is saturated or unsaturated and which optionally bears 1, 2, 3, or 4 substituents selected from among OH, COOH, CONH2, C1-C4 alkoxy, C1-C4 alkoxycarbonyl, and halogen; Y is a bivalent hydrocarbon group having 2 to 20 C atoms, which is saturated or unsaturated, and M is a chemical bond or C2-C10 alkylene, which can be interrupted by one or two groups not directly adjacent, selected from among O, C(=O)O, and (C=O)NH and which optionally bears 1, 2, 3, or 4 substituents selected from among OH, COOH, CONH2, C1-C4 alkoxy, C1-C4 alkoxycarbonyl, and phenyl.

    Abstract translation: 本发明涉及通式(I)的新型嵌段共聚物。 本发明还涉及用于制备这种嵌段共聚物和它们的用途,尤其是作为在液体涂料组合物的添加剂的方法。 A {X- [-O-C(O)NH-Y-NH-C(O)-O-M-B]ķ} n的(I)。 在式(I)中,变量具有以下含义:n是数字从1至40,或2至40个,尤其是1至10或2至10,尤其是2到5; k是1或2; A表示的聚(二甲基硅氧烷)嵌段; B代表从烯不饱和单体聚合物嵌段的建成,任选具有除氢之外的末端基团; X代表的二价或具有其为饱和或不饱和的2〜20个碳原子和任选1,2,3或4个取代基,其中OH,COOH,CONH 2,C 1 -C 4 - 烷氧基,C 1 -C三价基 C4烷氧羰基和卤素; Y是具有其为饱和或不饱和的2〜20个碳原子的二价烃基,和M代表,其中(由一个或两个不直接相邻的基团选自O,C中选择一个化学键或C2-C10亚烷基 = O)O和(C = O)NH可以被中断并任选地含有1,2,3或4个取代基,其被选自OH,COOH,CONH 2,C1-C4烷氧基,C1-C4烷氧羰基和苯基 ,

    NOVEL POLYMER DISPERSANTS
    4.
    发明公开
    NOVEL POLYMER DISPERSANTS 审中-公开
    新型聚合物分散剂

    公开(公告)号:EP2817358A4

    公开(公告)日:2015-10-14

    申请号:EP13752512

    申请日:2013-02-22

    Applicant: BASF SE

    Abstract: The present invention relates to novel polymer dispersants and to a liquid compositions containing solid fine particles, such as organic or inorganic pigments and fillers, and the polymer dispersants. The polymer dispersants have at least one functional moiety of the formula I, which is bound to one of the termini or to the backbone of the polymer: (I) where # indicates the point of attachment to the terminus and/or to the polymer backbone; k is 0, 1, 2, 3 or 4, m is 0, 1, 2, 3, 4, 5, 6, 7, 8 or 9, A is a chemical bond or a divalent moiety selected from the group consisting of C1-C6 alkylene, —O—(C2-C6 alkylene), —C(═O—O—(C2-C6 alkylene), —NR3—(C2-C6 alkylene) and C(═O)—NR3—(C2-C6 alkylene), where the C2-C6 alkylene part is attached to Q; Q is a divalent moiety selected from the group consisting of —O—, —NH— and —S—; R1 is independently selected from the group consisting of —OH, —COOH, —COOCH3, —NH2, —NH(C1-C6 alkyl), —N(C1-C6 alkyl)2, —NO2, —S(═O)2R4, C1-C20 alkyl, C1-C4 alkoxy, halogen, aryloxy, aryl, heteroaryl; R2 is selected from the group consisting of hydrogen, —S(═O)2R4, C1-C20 alkyl, C3-C10 cycloalkyl, aryl, heteroaryl, aryl-C1-C4-alkyl and heteroaryl-C1-C4-alkyl; R3 is selected from the group consisting of hydrogen, —S(═O)2R4, C1-C20 alkyl, C3-C10 cycloalkyl, aryl and heteroaryl; R4 is selected from the group consisting of OH, —NH2, —NH(C1-C6 alkyl), —N(C1-C6 alkyl)2, C1-C4 alkyl, C1-C4 alkoxy, aryl and heteroaryl.

    MEZCLA DE FOTOINICIADOR LIQUIDO.
    5.
    发明专利

    公开(公告)号:MX2011007229A

    公开(公告)日:2011-08-03

    申请号:MX2011007229

    申请日:2010-01-04

    Applicant: BASF SE

    Abstract: La presente invención se refiere a una mezcla líquida homogénea que comprende un fotoiniciador y un agente t.ensioactivo de alcoxilato para incorporación en sistemas curables por radiación con base acuosa y basados en solventes. En particular la invención se refiere a una mezcla liquida homogénea que es líquida a temperatura ambiente que comprende por lo menos 30% en peso con respecto a la mezcla completa de un fotoinciador sólido del tipo de radicales y 1-70% en peso de por lo menos un agente de superficie activa líquida alcoxilada y opcionalmente un diluyente orgánico.

    Combinación líquida de fotoiniciador

    公开(公告)号:ES2556341T3

    公开(公告)日:2016-01-15

    申请号:ES10700103

    申请日:2010-01-04

    Applicant: BASF SE

    Abstract: Combinación líquida homogénea que es líquida a temperatura ambiente que comprende al menos el 30% en peso con respecto a la combinación total de un fotoiniciador del tipo radicalario que es sólido a temperatura ambiente y el 1-70% en peso de al menos un agente tensioactivo líquido alcoxilado y opcionalmente un diluyente orgánico, en la que el fotoiniciador se selecciona de 1-hidroxi-ciclohexil-fenil-cetona (IRGACURE® 184), 1-[4-(2- hidroxietoxi)-fenil]-2-hidroxi-2-metil-1-propan-1-ona (IRGACURE® 2959), 2-hidroxi-1-{4-[4-(2-hidroxi-2-metilpropionil)- bencil]-fenil}-2-metil-propan-1-ona (IRGACURE® 127), (4-metiltiobenzoil)-1-metil-1-morfolinoetano (IRGACURE® 907), (4-morfolinobenzoil)-1-bencil-1-dimetilaminopropano (IRGACURE® 369), (4-morfolinobenzoil)-1- (4-metilbencil)-1-dimetilaminopropano (IRGACURE® 379), óxido de (2,4,6-trimetilbenzoil)difenilfosfina (DAROCUR® TPO), óxido de bis(2,6-dimetoxi-benzoil)-(2,4,4-trimetil-pentil)fosfina, óxido de bis(2,4,6-trimetilbenzoil)-fenilfosfina (IRGACURE® 819) y 2-hidroxi-1-{1-[4-(2-hidroxi-2-metil-propionil)-fenil]-1,3,3-trimetil-indan-5-il}-2-metil-propan-1- ona, (ESACURE ONE®), 1-[4-(feniltio)fenil]-2-(O-benciloxima) de 1,2-octanodiona (IRGACURE® OXE01).

    ENCAPSULATED DISPERSIONS COMPRISING ELECTROPHORETICALLY MOBILE ORGANIC COLORANTS

    公开(公告)号:CA2698832A1

    公开(公告)日:2009-03-12

    申请号:CA2698832

    申请日:2008-08-28

    Applicant: BASF SE

    Abstract: The invention relates to an electrophoretic display, comprising electrodes and cells containing at least one kind of ionic, monochrome particles, a non-polar liquid and a dispersant, wherein the ionic, monochrome particles of at least one kind are essentially aggregates consisting of a carbon containing pigment and a cationic pigment orcationic pigment derivative, and the dispersantis selected from the group consisting of polyacrylates, polyesters, polyurethanes and copolymers, with the proviso that the cationic pigment or cationic pigment derivative is not a reaction product of carbonblack with diazotated procaine hydrochloride. In general, the whole quantity of the pigment and the main part, preferably at least 80%, most preferred from 95% to 100%, of the whole cationic pigment or cationic pigment derivativepresent within the cells is comprised in the aggregates, with essentially no pigment and only a minor part of the cationic pigment or cationic pigment derivative physically distinct from the aggregates.

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