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    FLUORINATED ACRYLATE BLOCK COPOLYMERS WITH LOW DYNAMIC SURFACE TENSION
    1.
    发明申请
    FLUORINATED ACRYLATE BLOCK COPOLYMERS WITH LOW DYNAMIC SURFACE TENSION 审中-公开
    具有低动态表面张力的氟化丙烯酸酯嵌段共聚物

    公开(公告)号：WO2013124421A9

    公开(公告)日：2013-12-19

    申请号：PCT/EP2013053567

    申请日：2013-02-22

    Applicant: BASF SE

    Inventor： THOMSON MARY ,  KNISCHKA RALF ,  AUSCHRA CLEMENS ,  ENGELBRECHT LOTHAR

    IPC: C08L53/00 ,  C09D7/47 ,  C08L27/12 ,  C08L33/14 ,  C08L33/16 ,  C08L75/04 ,  C09D11/00 ,  C09D133/16 ,  C09D153/00 ,  C09J133/16 ,  C09J153/00

    CPC classification number: C08L53/00 ,  C08F2438/02 ,  C08G18/6225 ,  C08G18/6275 ,  C09D7/47 ,  C09D11/00 ,  C09D11/106 ,  C09D11/107 ,  C09D11/108 ,  C09D153/00 ,  C09J153/00 ,  C08L75/04

    Abstract: The present invention relates to a composition, comprising a binder resin, a block copolymer which comprises at least a block A and a block B, wherein the block A comprises monomer units derived from a compound selected from (meth)acrylic acid, a (meth)acrylic acid ester, a (meth)acrylamide, a vinyl aromatic compound, or any mixture thereof, the block B comprises monomer units derived from a compound selected from a fluorinated (meth)acrylic ester having the following formula (I): H2C=C(R1)(C(0)ORF-1), wherein R1 is H or methyl; and RF-1 is an organic residue containing a perfluorinated C4-6 alkyl group, a fluorinated alpha-olefm having the following formula (II): H2C=CH(RF-2) (II) wherein RF-2 is an organic residue containing a perfluorinated C4-6 alkyl group, i.e. -(CF2)3-5-CF3 or any mixture thereof.

    Abstract translation: 本发明涉及包含粘合剂树脂，至少包含嵌段A和嵌段B的嵌段共聚物的组合物，其中嵌段A包含衍生自选自（甲基）丙烯酸，（甲基）丙烯酸， ）丙烯酸酯，（甲基）丙烯酰胺，乙烯基芳族化合物或其任何混合物，嵌段B包含衍生自选自具有下式（I）的氟化（甲基）丙烯酸酯的化合物的单体单元：H 2 C = C（R 1）（C（O）ORF-1），其中R 1为H或甲基; 并且RF-1是含有全氟化C 4-6烷基的有机残基，具有下式（II）的氟化α-烯烃：H 2 C = CH（RF-2）（II）其中RF-2是含有 全氟化C 4-6烷基，即 - （CF 2）3-5-CF 3或其任何混合物。

    CURABLE COMPOSITION COMPRISING A THERMOLATENT BASE
    2.
    发明申请
    CURABLE COMPOSITION COMPRISING A THERMOLATENT BASE 审中-公开
    包含热固性基料的可固化组合物

    公开(公告)号：WO2010057922A1

    公开(公告)日：2010-05-27

    申请号：PCT/EP2009065394

    申请日：2009-11-18

    Applicant: BASF SE ,  NESVADBA PETER ,  BUGNON FOLGER LUCIENNE ,  KNISCHKA RALF

    Inventor： NESVADBA PETER ,  BUGNON FOLGER LUCIENNE ,  KNISCHKA RALF

    IPC: C07D213/74 ,  C07D215/38 ,  C08G59/68

    CPC classification number: C07D213/74 ,  C07D215/38 ,  C08G59/4246 ,  C08G59/686 ,  C08L63/00

    Abstract: The present invention relates to curable compositions comprising a thermolatent amidine base and an organic material which is polymerisable or crosslinkable with a basic or nucleophilic catalyst. In particular, the invention relates to curable coating compositions, especially powder coating compositions, and curable adhesive compositions, as well as to the use a thermolatent amidine base as a curing catalyst for thermally induced base- catalyzed polymerisation or crosslinking reactions.

    Abstract translation: 本发明涉及可固化组合物，其包含热潜伏脒基质和可与碱性或亲核性催化剂聚合或交联的有机材料。 特别地，本发明涉及可固化涂料组合物，特别是粉末涂料组合物和可固化粘合剂组合物，以及涉及使用热潜在脒碱作为用于热诱导的碱催化聚合或交联反应的固化催化剂。

    BLOCK COPOLYMERS HAVING A POLYDIMETHYLSILOXANE BLOCK
    6.
    发明申请
    BLOCK COPOLYMERS HAVING A POLYDIMETHYLSILOXANE BLOCK 审中-公开
    WITH A聚二甲基硅氧烷嵌段的嵌段共聚物

    公开(公告)号：WO2014111503A3

    公开(公告)日：2014-10-09

    申请号：PCT/EP2014050874

    申请日：2014-01-17

    Applicant: BASF SE

    Inventor： ENGELBRECHT LOTHAR ,  PIRRUNG FRANK ,  AUSCHRA CLEMENS ,  KNISCHKA RALF ,  KRANWETVOGEL REINER

    IPC: C08G77/442 ,  C08J3/20 ,  C08L83/10

    CPC classification number: C08G81/027 ,  C08G77/442 ,  C08L83/10 ,  C09D163/00 ,  C09D175/04 ,  C09D183/10

    Abstract: The present invention relates to novel block copolymers of general formula (I). The invention further relates to a method for producing such block copolymers and to the use of such block copolymers, particularly as additives in liquid coating-agent compositions. A{X-[O-C(O)NH-Y-NH-C(O)-O-M-B]k}n (I). In formula (I), the variables have the following meanings: n is a number in the range from 1 to 40 or 2 to 40, particularly 1 to 10 or 2 to 10 and especially 2 to 5; k is 1 or 2; A is a poly(dimethylsiloxane) block; B is a polymer block constructed of ethylenically unsaturated monomers, which optionally comprises a terminal group different from hydrogen; X is a bivalent or trivalent group having 2 to 20 C atoms, which is saturated or unsaturated and which optionally bears 1, 2, 3, or 4 substituents selected from among OH, COOH, CONH2, C1-C4 alkoxy, C1-C4 alkoxycarbonyl, and halogen; Y is a bivalent hydrocarbon group having 2 to 20 C atoms, which is saturated or unsaturated, and M is a chemical bond or C2-C10 alkylene, which can be interrupted by one or two groups not directly adjacent, selected from among O, C(=O)O, and (C=O)NH and which optionally bears 1, 2, 3, or 4 substituents selected from among OH, COOH, CONH2, C1-C4 alkoxy, C1-C4 alkoxycarbonyl, and phenyl.

    Abstract translation: 本发明涉及通式（I）的新型嵌段共聚物。 本发明还涉及用于制备这种嵌段共聚物和它们的用途，尤其是作为在液体涂料组合物的添加剂的方法。 A {X- [-O-C（O）NH-Y-NH-C（O）-O-M-B]ķ} n的（I）。 在式（I）中，变量具有以下含义：n是数字从1至40，或2至40个，尤其是1至10或2至10，尤其是2到5; k是1或2; A表示的聚（二甲基硅氧烷）嵌段; B代表从烯不饱和单体聚合物嵌段的建成，任选具有除氢之外的末端基团; X代表的二价或具有其为饱和或不饱和的2〜20个碳原子和任选1，2，3或4个取代基，其中OH，COOH，CONH 2，C 1 -C 4 - 烷氧基，C 1 -C三价基 C4烷氧羰基和卤素; Y是具有其为饱和或不饱和的2〜20个碳原子的二价烃基，和M代表，其中（由一个或两个不直接相邻的基团选自O，C中选择一个化学键或C2-C10亚烷基 = O）O和（C = O）NH可以被中断并任选地含有1，2，3或4个取代基，其被选自OH，COOH，CONH 2，C1-C4烷氧基，C1-C4烷氧羰基和苯基 ，

    Composición curable que comprende una base termolatente
    9.
    发明专利
    Composición curable que comprende una base termolatente 未知

    公开(公告)号：ES2400633T3

    公开(公告)日：2013-04-11

    申请号：ES09755900

    申请日：2009-11-18

    Applicant: BASF SE

    Inventor： NESVADBA PETER ,  BUGNON FOLGER LUCIENNE ,  KNISCHKA RALF

    IPC: C07D213/74 ,  C07D215/38 ,  C08G59/68

    Abstract: Una composición curable que comprende (A) un material orgánico que se puede polimerizar y entrecruzar con un catalizador básico o nucleófilo y (B) un compuesto de la fórmula **Fórmula** en donde R1 forma junto con el átomo de carbono y el nitrógeno, que se une a, un sistema de anillo C2-C20 mono-o policícico, quepuede contener adicionalmente uno o más heteroátomos de O, S y/o N y/o que es no sustituido o sustituido poralquilo C1-C18; alquilo C1-C18, que se sustituye por E y/o interrumpe por D: cicloalquilo C5-C12, que se sustituye por E y/ointerrumpe por D; cicloalquenilo C5-C12; alquenilo C2-C18; alquinilo C2-C18; arilo C6-C18; arilo C8-C18, que se sustituye porG; heteroarilo C2-C18; heteroarilo C2-C18, que se sustituye por G; alcoxi C1-C18; alcoxi C1-C18 que se sustituye por E y/ointerrumpe por D; alquiltio C1-C18; alquiltio C1-C18, que se sustituye por E y/o interrumpe por D; aralquilo C7-C18; aralquiloC7-C18, que se sustituye por G; halógeno; oxo; OH; SH; CN; NH2; NO2; COOH; NHR6; NR7R8; CONH2; CONR9R10; COR11; C(O)OR12; SO2R13; SO3R14;SO2NHR15; SO2NR16R17; o dicho sistema de anillo se sustituye por uno o más grupos de la fórmula **Fórmula**

    10.
    发明专利
    未知

    公开(公告)号：AT535581T

    公开(公告)日：2011-12-15

    申请号：AT09713532

    申请日：2009-02-03

    Applicant: BASF SE

    Inventor： MOECK ANDREAS ,  KNISCHKA RALF ,  AUSCHRA CLEMENS

    IPC: C09D133/00 ,  C09D7/47

    Abstract: The invention relates to a coating composition comprising short chain fluorinated acrylates and to the use of short chain fluorinated acrylates as levelling agents for pigmented and unpigmented coating compositions. The coating composition comprises a) a film forming binder resin, and b) a copolymer made by controlled polymerization or by conventional radical polymerization comprising a monomer (M1x) selected from unsaturated monomers out of the group of (meth)acrylates, styrenic monomers or (meth)acrylamides whereby the copolymer contains at least >30 wt % (meth)acrylates; and a monomer (M2y) selected from C1-C4-fluoralkyl(meth)acrylates; x denotes the total number of monomers M1 within the structural element (M1x): x>5, preferred, 10-1000, most preferred, 10-500; y denotes the total number of monomers M2 within the structural element (M2y): y>1, preferred, 2-20, most preferred 2-10; c) optional other conventional coating components and/or additives.

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