公开(公告)号：US09617447B2

公开(公告)日：2017-04-11

申请号：US14403824

申请日：2013-06-04

Applicant: BASF SE

Inventor： Ekkehard Jahns ,  Hans-Juergen Denu ,  Sebastian Roller ,  Alexander Kurek

IPC: B32B15/08 ,  C09D151/00 ,  C04B41/00 ,  C08F265/06 ,  B05D1/14 ,  B05D1/36 ,  E04D1/18 ,  E04D1/22 ,  E04D13/00 ,  C08F2/24 ,  E04D1/00

CPC classification number: C09D151/003 ,  B05D1/14 ,  B05D1/36 ,  C04B41/00 ,  C08F2/24 ,  C08F265/06 ,  E04D1/18 ,  E04D1/22 ,  E04D13/00 ,  E04D2001/005 ,  Y10T428/31692 ,  C08F220/58 ,  C08F220/18 ,  C08F2220/1825 ,  C08F2220/585

Abstract: The present invention relates to the use of aqueous multistage polymer dispersions obtainable by free-radically initiated aqueous emulsion polymerization, having a soft phase and a hard phase and having a hard-to-soft stage ratio of 25% to 95% by weight to 75% to 5% by weight, the glass transition temperature (Tg) of the soft phase, as first stage, being −30 to 0° C. and that of the hard phase, as second stage, being 20 to 60° C., comprising at least one monomer of the general formula I in which the variables have the following definitions: n=0 to 2, R1, R2, R3=independently of one another hydrogen or methyl group, X═O or NH, Y═H, alkali metal or NH4, to coat metal sheets.

公开(公告)号：US09926452B2

公开(公告)日：2018-03-27

申请号：US14440503

申请日：2013-11-06

Applicant: BASF SE

Inventor： Ekkehard Jahns ,  Sebastian Roller ,  Alexander Kurek ,  Ivan Cabrera ,  Xavier Mollat Du Jourdin ,  Nicolas Tissier

IPC: C09D4/00 ,  C09D133/00 ,  C08F220/14 ,  C08K3/00

CPC classification number: C09D4/00 ,  C08F220/14 ,  C08K3/013 ,  C09D133/00

Abstract: The present invention provides the use of aqueous polymer dispersions comprising (a) at least two monomers M1 having a glass transition temperature ≥25° C., (b) at least two monomers M2 having a glass transition temperature

公开(公告)号：US20150104658A1

公开(公告)日：2015-04-16

申请号：US14403824

申请日：2013-06-04

Applicant: BASF SE

Inventor： Ekkehard Jahns ,  Hans-Juergen Denu ,  Sebastian Roller ,  Alexander Kurek

IPC: C09D151/00 ,  E04D1/22 ,  E04D13/00 ,  E04D1/18 ,  B05D1/36 ,  B05D1/14

CPC classification number: C09D151/003 ,  B05D1/14 ,  B05D1/36 ,  C04B41/00 ,  C08F2/24 ,  C08F265/06 ,  E04D1/18 ,  E04D1/22 ,  E04D13/00 ,  E04D2001/005 ,  Y10T428/31692 ,  C08F220/58 ,  C08F220/18 ,  C08F2220/1825 ,  C08F2220/585

Abstract: The present invention relates to the use of aqueous multistage polymer dispersions obtainable by free-radically initiated aqueous emulsion polymerization, having a soft phase and a hard phase and having a hard-to-soft stage ratio of 25% to 95% by weight to 75% to 5% by weight, the glass transition temperature (Tg) of the soft phase, as first stage, being −30 to 0° C. and that of the hard phase, as second stage, being 20 to 60° C., comprising at least one monomer of the general formula I in which the variables have the following definitions: n=0 to 2, R1, R2, R3=independently of one another hydrogen or methyl group, X═O or NH, Y═H, alkali metal or NH4, to coat metal sheets.

Abstract translation: 本发明涉及通过自由基引发的水性乳液聚合获得的含水多阶段聚合物分散体的使用，其具有软相和硬相，并且具有25％至95％重量至75％的硬 - 软级比 ％至5重量％，作为第一阶段的软相的玻璃化转变温度（Tg）为-30〜0℃，硬相的玻璃化转变温度（Tg）为20〜60℃， 包括至少一种通式I的单体，其中变量具有以下定义：n = 0至2，R 1，R 2，R 3彼此独立地为氢或甲基，X = O或NH，Y = H， 碱金属或NH4，以涂覆金属片。