公开(公告)号：SG176041A1

公开(公告)日：2011-12-29

申请号：SG2011083516

申请日：2010-05-05

Applicant: BASF SE ,  DOW CHEMICAL CO

Inventor： KAMPE PHILIP ,  RESCH PETER ,  CHIN SOO YIN ,  BASLER PETER ,  MUELLER ULRICH ,  SCHINDLER GOETZ-PETER ,  GOEBBEL HANS-GEORG ,  TELES JOAQUIM HENRIQUE ,  GUMLICH KAI ,  GRASLER THOMAS ,  BARTOSCH CHRISTIAN ,  JACUBINAS RICHARD ,  WEIDENBACH MEINOLF

Abstract: A process for producing propylene oxide comprising reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (Gl) comprising propylene oxide, unreacted propene, and oxygen; separating propylene oxide from mixture (Gl) to give a mixture (GII) comprising propene and oxygen; and adding hydrogen to mixture (GII) and reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising copper in elemental and/or oxidic form on a support, wherein copper is present on the support in an amount of 30 to 80 wt.-% based on the whole catalyst and calculated as CuO.

公开(公告)号：SG178027A1

公开(公告)日：2012-03-29

申请号：SG2012002499

申请日：2010-07-16

Applicant: BASF SE ,  DOW CHEMICAL CO

Inventor： TELES JOAQUIM HENRIQUE ,  GOEBBEL HANS-GEORG ,  BASLER PETER ,  KAMPE PHILIP ,  GUMLICH KAI ,  BARTOSCH CHRISTIAN ,  MUELLER ULRICH ,  JACUBINAS RICHARD ,  TRUKHAN NATALIA ,  WEIDENBACH MEINOLF ,  COGSWELL MARTIN

Abstract: A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile : water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene : propane of 7:3; (iii) subjecting S2 to a temperature of 92 °C at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase 12 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile : water in L2 is less than 1; (iv) separating L1 from L2.

公开(公告)号：AT497491T

公开(公告)日：2011-02-15

申请号：AT03773710

申请日：2003-11-11

Applicant: BASF SE

Inventor： FISCHER ROLF-HARTMUTH ,  LUYKEN HERMANN ,  ANSMANN ANDREAS ,  BASLER PETER ,  BENISCH CHRISTOPH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER

IPC: C07D201/16 ,  C07D201/08

Abstract: A process for removing high boilers from crude caprolactam which comprises high boilers, caprolactam and in some cases low boilers, and which has been obtained by a) reacting 6-aminocapronitrile with water to give a reaction mixture b) removing ammonia and unconverted water from the reaction mixture to obtain crude caprolactam, which comprises c) feeding the crude caprolactam to a distillation apparatus to obtain a first substream via the top as a product and a second substream via the bottom, by setting the pressure in the distillation in such a way that the bottom temperature does not go below 170° C., and adjusting the second substream in such a way that the caprolactam content of the second substream is not less than 10% by weight, based on the entire second substream.

公开(公告)号：ES2436625T3

公开(公告)日：2014-01-03

申请号：ES10715902

申请日：2010-05-05

Applicant: BASF SE ,  DOW CHEMICAL CO

Inventor： KAMPE PHILIP ,  RESCH PETER ,  CHIN SOO YIN ,  BASLER PETER ,  MUELLER ULRICH ,  SCHINDLER GOETZ-PETER ,  GOEBBEL HANS-GEORG ,  TELES JOAQUIM HENRIQUE ,  GUMLICH KAI ,  GRASLER THOMAS ,  BARTOSCH CHRISTIAN ,  JACUBINAS RICHARD ,  WEIDENBACH MEINOLF

IPC: C07D301/12

Abstract: Un proceso para producir óxido de propileno que comprende (I) hacer reaccionar propeno con peróxido de hidrógeno en la presencia de un catalizador para dar una mezcla (GI) quecomprende óxido de propileno, propeno sin reaccionar y oxígeno; (II) separar óxido de propileno de la mezcla (GI) para dar una mezcla (GII) que comprende propeno y oxígeno; (III) agregar hidrógeno a la mezcla (GII) y reducir el oxígeno contenido en la mezcla (GII) al menos parcialmente porreacción con hidrógeno en presencia de un catalizador que comprende cobre en forma elemental y/o oxidada sobre unsoporte, en donde el cobre está presente sobre el soporte en una cantidad de 30 a 80% en peso, con base en elcatalizador completo calculado como CuO.

公开(公告)号：DE50313458D1

公开(公告)日：2011-03-17

申请号：DE50313458

申请日：2003-11-11

Applicant: BASF SE

Inventor： FISCHER ROLF-HARTMUTH ,  LUYKEN HERMANN ,  ANSMANN ANDREAS ,  BASLER PETER ,  BENISCH CHRISTOPH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER

IPC: C07D201/16 ,  C07D201/08