Abstract:
PROBLEM TO BE SOLVED: To provide a method for producing quaterrylene-3,4:13,14-tetracarboxy diimide in which blemishes of a prior art are corrected, and which is enabled by an advantageous and economical way.SOLUTION: The method for producing quaterrylene-3,4:13,14-tetracarboxy diimide of general formula I, wherein a variable region has an implication written in the specification comprises as follows. perylene-3,4-dicarboxy imide of general formula IIa is made to react with perylene-3,4-dicarboxy imide of general formula IIb, wherein X denotes hydrogen, bromine or chlorine under the presence of an organic solvent of high boiling point nature of base stability and a base containing an alkali metal or alkaline earth metal.
Abstract:
A process for preparing quaterrylene-3,4:13,14-tetracarboximides of the general formula I in which R, R′ are each independently hydrogen or optionally substituted C1-C30-alkyl, C5-C8-cycloalkyl or aryl or hetaryl; which comprises reacting a perylene-3,4-dicarboximide of the general formula IIa in the presence of a base-stable, high-boiling, organic solvent and of an alkali metal base or alkaline earth metal base, with a perylene-3,4-dicarboximide of the general formula IIb in which X is hydrogen, bromine or chlorine.
Abstract:
Processes for manufacturing nitrogen oxide storage materials and lean NOx trap catalysts are disclosed. Also disclosed are nitrogen oxide storage material made by processes comprising barium carbonate (BaCO3) and ceria (CeO2) by using Ba(OH)2 instead of most or all Ba(OOCH3)2 to reduce cost and reduce harmful byproducts. Aspects of the present invention also relate generally to lean NOx trap (LNT) comprising nitrogen oxide storage materials.