公开(公告)号：JP2011225608A

公开(公告)日：2011-11-10

申请号：JP2011162360

申请日：2011-07-25

Applicant: Basf Se ,  ビーエーエスエフ ソシエタス・ヨーロピアBasf Se

Inventor： KOENEMANN MARTIN ,  BOEHM ARNO ,  BIDLINGMAIER HERMANN ,  RIEGER REINHOLD ,  BLASCHKA PETER ,  REICHELT HELMUT ,  KRIEGER MATTHIAS

IPC: C07D471/06

CPC classification number: C07D471/06 ,  C09B5/62

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing quaterrylene-3,4:13,14-tetracarboxy diimide in which blemishes of a prior art are corrected, and which is enabled by an advantageous and economical way.SOLUTION: The method for producing quaterrylene-3,4:13,14-tetracarboxy diimide of general formula I, wherein a variable region has an implication written in the specification comprises as follows. perylene-3,4-dicarboxy imide of general formula IIa is made to react with perylene-3,4-dicarboxy imide of general formula IIb, wherein X denotes hydrogen, bromine or chlorine under the presence of an organic solvent of high boiling point nature of base stability and a base containing an alkali metal or alkaline earth metal.

Abstract translation: 待解决的问题：提供一种生产现有技术的瑕疵被校正的季戊四烯-3,4：13,14-四羧基二酰亚胺的方法，并且通过有利且经济的方式实现。 解决方案：用于制备通式I的四亚甲基-3,4：13,14-四羧基二酰亚胺的方法，其中可变区具有在说明书中描述的含义如下。 使通式IIa的苝-3,4-二羧酰亚胺与通式IIb的苝-3,4-二羧酰亚胺反应，其中X表示氢，溴或氯，在高沸点有机溶剂的存在下 的碱稳定性和含有碱金属或碱土金属的碱。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：DE50309848D1

公开(公告)日：2008-06-26

申请号：DE50309848

申请日：2003-06-04

Applicant: BASF SE ,  MAX PLANCK GESELLSCHAFT

Inventor： BOEHM ARNO ,  KRIEGER MATTHIAS ,  REUTHER ERIK ,  MUELLEN KLAUS

IPC: C07D471/06 ,  C09B5/62 ,  C09K11/06

Abstract: New 1,6,9,14-tetra-substituted terrylenetetracarbodiimides (I) are claimed, in which the 1,6-positions and 9,14-positions independently are substituted by bromo, cyano, (het)aryloxy, (het)arylthio, optionally substituted (hetero)-alk(en)yl or -alkynyl, N-heterocyclyleth(en)yl, N-heterocyclylethynyl or (substituted) amino. 1,6,9,14-Tetra-substituted terrylenetetracarbodiimides of formula (I) are new X, Y = Br, CN, (het)aryloxy or (het)arylthio (optionally mono- or poly-substituted by 1-12C alkyl, 1-12C alkoxy, -COOR1, -SO3R1, halogen, COOH, carboxy, CN, -CONHR2 and/or -NHCOR2), -L-R3, -N(R2)2; R, R' = H, 1-30C alkyl (optionally with -O-, -S-, -NR1-, -CO- and/or -SO2- group(s) in the chain and optionally mono- or poly-substituted by CN, 1-6 C alkoxy, aryl (optionally substituted by 1-18 C alkyl or 1-6 C alkoxy) and/or a 5-7-N-heterocyclic group, which may contain other hetero-atoms and may be aromatic), 5-8 C cycloalkyl (optionally with -O-, -S- and/or -NR1- group(s) in the C skeleton and/or mono- or poly-substituted by 1-6 C alkyl), (het)aryl (optionally mono- or poly-substituted by 1-18 C alkyl, 1-6 C alkoxy, CN, -CONHR2, -NHCOR2 and/or (het)arylazo, which may be substituted by 1-10 C alkyl, 1-6 C alkoxy or CN); L = 1,2-ethylene, 1,2-ethenylene or 1,2-ethynylene; R1 = H or 1-6C alkyl; R2 = H, 1-18C alkyl or (het)aryl, optionally substituted by 1-6 C alkyl, 1-6 C alkoxy, halogen, OH, carboxy or CN); R3 = 1-18C alkyl (optionally with -O-, -S-, -NR1-, -CO- and/or -SO2- group(s) in the chain and optionally substituted by -COOR1, -SO3R1, OH, CN, 1-6C alkoxy, aryl (optionally substituted by 1-18 C alkyl or 1-6 C alkoxy) and/or a 5-7-N-heterocyclic group, which may contain other hetero-atoms and may be aromatic). Independent claims are also included for methods of preparing (I).

公开(公告)号：AT490255T

公开(公告)日：2010-12-15

申请号：AT05772974

申请日：2005-08-04

Applicant: BASF SE

Inventor： KOENEMANN MARTIN ,  BOEHM ARNO ,  BIDLINGMAIER HERMANN ,  RIEGER REINHOLD ,  BLASCHKA PETER ,  REICHELT HELMUT ,  KRIEGER MATTHIAS

IPC: C07D471/06 ,  C09B5/62

Abstract: A process for preparing quaterrylene-3,4:13,14-tetracarboximides of the general formula I in which R, R′ are each independently hydrogen or optionally substituted C1-C30-alkyl, C5-C8-cycloalkyl or aryl or hetaryl; which comprises reacting a perylene-3,4-dicarboximide of the general formula IIa in the presence of a base-stable, high-boiling, organic solvent and of an alkali metal base or alkaline earth metal base, with a perylene-3,4-dicarboximide of the general formula IIb in which X is hydrogen, bromine or chlorine.

公开(公告)号：DE502005010629D1

公开(公告)日：2011-01-13

申请号：DE502005010629

申请日：2005-08-04

Applicant: BASF SE

Inventor： KOENEMANN MARTIN ,  BOEHM ARNO ,  BIDLINGMAIER HERMANN ,  RIEGER REINHOLD ,  BLASCHKA PETER ,  REICHELT HELMUT ,  KRIEGER MATTHIAS

IPC: C07D471/06 ,  C09B5/62

公开(公告)号：AT395347T

公开(公告)日：2008-05-15

申请号：AT03735536

申请日：2003-06-04

Applicant: BASF SE

Inventor： BOEHM ARNO ,  KRIEGER MATTHIAS ,  REUTHER ERIK ,  MUELLEN KLAUS

IPC: C07D471/06 ,  C09B5/62 ,  C09K11/06

Abstract: New 1,6,9,14-tetra-substituted terrylenetetracarbodiimides (I) are claimed, in which the 1,6-positions and 9,14-positions independently are substituted by bromo, cyano, (het)aryloxy, (het)arylthio, optionally substituted (hetero)-alk(en)yl or -alkynyl, N-heterocyclyleth(en)yl, N-heterocyclylethynyl or (substituted) amino. 1,6,9,14-Tetra-substituted terrylenetetracarbodiimides of formula (I) are new X, Y = Br, CN, (het)aryloxy or (het)arylthio (optionally mono- or poly-substituted by 1-12C alkyl, 1-12C alkoxy, -COOR1, -SO3R1, halogen, COOH, carboxy, CN, -CONHR2 and/or -NHCOR2), -L-R3, -N(R2)2; R, R' = H, 1-30C alkyl (optionally with -O-, -S-, -NR1-, -CO- and/or -SO2- group(s) in the chain and optionally mono- or poly-substituted by CN, 1-6 C alkoxy, aryl (optionally substituted by 1-18 C alkyl or 1-6 C alkoxy) and/or a 5-7-N-heterocyclic group, which may contain other hetero-atoms and may be aromatic), 5-8 C cycloalkyl (optionally with -O-, -S- and/or -NR1- group(s) in the C skeleton and/or mono- or poly-substituted by 1-6 C alkyl), (het)aryl (optionally mono- or poly-substituted by 1-18 C alkyl, 1-6 C alkoxy, CN, -CONHR2, -NHCOR2 and/or (het)arylazo, which may be substituted by 1-10 C alkyl, 1-6 C alkoxy or CN); L = 1,2-ethylene, 1,2-ethenylene or 1,2-ethynylene; R1 = H or 1-6C alkyl; R2 = H, 1-18C alkyl or (het)aryl, optionally substituted by 1-6 C alkyl, 1-6 C alkoxy, halogen, OH, carboxy or CN); R3 = 1-18C alkyl (optionally with -O-, -S-, -NR1-, -CO- and/or -SO2- group(s) in the chain and optionally substituted by -COOR1, -SO3R1, OH, CN, 1-6C alkoxy, aryl (optionally substituted by 1-18 C alkyl or 1-6 C alkoxy) and/or a 5-7-N-heterocyclic group, which may contain other hetero-atoms and may be aromatic). Independent claims are also included for methods of preparing (I).