HALOGEN-FREE, PHOSPHOROUS-CONTAINING, FLAME-PROTECTED POLYMER FOAMS
    1.
    发明申请
    HALOGEN-FREE, PHOSPHOROUS-CONTAINING, FLAME-PROTECTED POLYMER FOAMS 审中-公开
    无卤素,无磷阻燃聚合物泡沫

    公开(公告)号:WO2011095540A2

    公开(公告)日:2011-08-11

    申请号:PCT/EP2011051550

    申请日:2011-02-03

    CPC classification number: C08J9/0038 C08J9/0066 C08J2325/04 C08K5/53

    Abstract: The invention relates to a polymer foam having a density in the range between 5 and 120 kg/m3, containing a) a polymer component, containing at least one styrene polymer, b) 0.1 to 5 parts by weight (relative to 100 parts by weight of component a)) of a flame retardant mixture, containing b1) at least one phosphorus compound of formula (I) having a phosphorus content in the range between 5 and 80% by weight, relative to the phosphorus compound, (X1)s =PR1R2R3 (I), where the symbols and indices in formula (I) have the following meanings: R1 is C1-C16-alkyl, C1-C10-hydroxyalkyl, C2-C16-alkenyl, C1-C16-alkoxy, C2-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9, COR10, COOR11, CONR12R13; R2 is C1-C16-alkyl, C1-C10-hydroxyalkyl, C2-C16-alkenyl, C1-C16-alkoxy, C2-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryl-C1-C16-alkyl,C6-C10-aryl-C1-C16-alkoxy, SR9, COR10, COOR11, CONR12R13;R3 is H, SH, SR4, OH, OR5 or a group 30 -(Y1)n-[P(= X2)uR6 -(Y2)n]m-P(= X3)tR7R8; or two groups R1, R2, R3 together with the phosphorus atom to which they are bound form a ring system; X1, X2 and X3 are independently of each other identically or differently O or S; Y1, Y2 are identically or differently O or S; R4, R5, R9, R10, R11, R12,R13 are identically or differently C1-C12-alkyl, C3-C8-cycloalkyl, which is unsubstituted or substituted by one or more C1-C4-alkyl groups, C2-C12-alkenyl, C2-C12-alkinyl, C6-C10-aryl or C6-C10-aryl C1-C4-alkyl; R6, R7, R8 are independently of each other identically or differently C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9, COR10, COOR11, CONR12R13; n is 1, if Y1 or Y2 is O, and 1, 2, 3, 4, 5, 6, 7 or 8, if Y1 or Y2 is S; m is a whole number between 0 and 100; s, t and u are independently of each other 0 or 1; and b2) elementary sulphur.

    Abstract translation: 阻燃剂混合物,其包含b1的一)),其包括含有至少一种苯乙烯聚合物的聚合物组分,B)(基于具有在5〜120千克/米3范围内的密度,A聚合物泡沫)0.1至5重量份每100重量份组分的) 在式(I)具有在5的范围内的磷含量到80重量%的至少一种磷化合物,基于磷化合物(X1)S = PR1R2R3(I),其中,在式(I)中的符号和指数具有以下含义 有:R1是C1-C16烷基,C1-C10羟基烷基,C2-C16烯基,C1-C16烷氧基,C2-C16-链烯氧基,C3-C10环烷基,C3-C10环烷氧基,C6-C10 芳基,C6-C10芳氧基,C6-C10芳基C1-C16烷基,C6-C10芳基C1-C16烷氧基,SR9,COR 10,COOR 11,CONR 12 R 13; R2是C1-C16烷基,C1-C10羟基烷基,C2-C16烯基,C1-C16烷氧基,C2-C16-链烯氧基,C3-C10环烷基,C3-C10环烷氧基,C6-C10芳基, C6-C10芳基C1-C16烷基,C6-C10芳基C1-C16烷氧基,SR9,COR 10,COOR 11,CONR 12 R 13; R 3是H,SH,SR 4,OH,OR 5或Gruppe30 - (Y1) N- [P(= X2)UR6 - (Y2)N] MP(= X3)tR7R8;或两个基团R1,R2,与磷原子R3一起形成它们所连接形成环系统; X 1,X 2和X 3相同或不同且彼此独立地为O或S; Y1,Y2是相同或不同的O或S; R4,R5,R9,R10,R11,R12,R13为相同或不同的C1-C12烷基,C3-C8环烷基,其未被取代或者被一个或多个C1-C4烷基取代,C2-C12链烯基, C 2 -C 12炔基,C 6 -C 10芳基或C 6 -C 10芳基-C 1 -C 4烷基; R6,R7,R8是相同的或彼此独立地C1-C16烷基,C1-C16链烯基,C1-C16烷氧基,C1-C16-链烯氧基,C3-C10环烷基,C3-C10环烷氧基,C6-C10的不同 芳基,C6-C10芳氧基,C6-C10芳基C1-C16烷基,C6-C10芳基C1-C16烷氧基,SR9,COR 10,COOR 11,CONR 12 R 13; 如果Y1或Y2是O,n是1,如果Y1或Y1是1,则为1,2,3,4,5,6,7或8。 Y2是S; m是0至100的整数; s,t和u独立地为0或1; 和b2)元素硫。

    Procedimiento para la preparación de metacrilato de carbonato de glicerol.

    公开(公告)号:ES2912349T3

    公开(公告)日:2022-05-25

    申请号:ES18829226

    申请日:2018-12-07

    Applicant: BASF SE

    Abstract: Procedimiento para la preparación de metacrilato de carbonato de glicerol, en el que el metacrilato de glicidilo se hace reaccionar en presencia de un catalizador y un disolvente con dióxido de carbono, caracterizado porque el catalizador es yoduro de potasio, el disolvente es acetonitrilo, uno o más monoalcoholes, o una mezcla cualquiera de acetonitrilo y uno o más monoalcoholes y la reacción del metacrilato de glicidilo con dióxido de carbono se lleva a cabo a una presión de 0,5 a 5 bares.

    PROCESS FOR PREPARING ISOSORBIDE DL(METH)ACRYLATE

    公开(公告)号:MY185533A

    公开(公告)日:2021-05-19

    申请号:MYPI2017001241

    申请日:2016-02-24

    Applicant: BASF SE

    Abstract: A process for preparing isosorbide di(meth)acrylate by transesterifying alkyl (meth)acrylate with isosorbide, comprising the steps of: (i) reacting alkyl (meth)acrylate with isosorbide in the presence of a catalyst comprising titanium(IV) or zirconium(IV) and a stabilizer in the presence of an azeotroping agent which forms an azeotrope with the alcohol bound in the alkyl (meth)acrylate, (ii) continuously distilling off the azeotrope of azeotroping agent and alcohol, wherein steps (i) and (ii) are conducted simultaneously until the isosorbide has been essentially fully converted, (iii) adding water to the product mixture which comprises isosorbide (meth)acrylate and is obtained in steps (i) and (ii) and removing the hydrolyzate of the catalyst comprising titanium(IV) or zirconium(IV), (iv) distilling unconverted alkyl (meth)acrylate and azeotroping agent out of the product mixture, (v) distilling off water from the product mixture, wherein step (iv) can also be conducted before step (iii) and steps (iv) and (v) can also be conducted in one distillation step.

    Methods for producing (meth)acrylic acid norbornyl esters

    公开(公告)号:AU2018213816B2

    公开(公告)日:2020-01-02

    申请号:AU2018213816

    申请日:2018-01-22

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as a catalyst, characterised in that e) boron trifluoride is added to (meth)acrylic acid, f) the mixture is heated to a temperature of 75 to 110°C, g) norbornene is added, and h) the norbornyl-(meth)acrylate obtained is isolated from the reaction mixture. The invention further relates to a method for producing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as a catalyst, characterised in that e) boron trifluoride is added to an organic solvent, f) the mixture is heated to a temperature of 75 to 110°C, g) a mixture containing norbornene and (meth)acrylic acid is added, and h) the norbornyl-(meth)acrylate obtained is isolated from the reaction mixture.

    ACRYLATE-BASED MONOMERS FOR USE AS REACTIVE DILUENTS IN PRINTING FORMULATIONS

    公开(公告)号:CA3053037A1

    公开(公告)日:2018-08-16

    申请号:CA3053037

    申请日:2018-02-09

    Applicant: BASF SE

    Abstract: The invention relates to compositions, comprising. a)1.00 to 65.00% by weight of at least one compound of formula (I), wherein R1, R2, R3, R4 are each independently H, C1-C6-alkyl, C1-C6-alkoxy, or C1-C6-alkoxy-C1-C6-alkyl; R is H or C1-C6-alkyl; X is CR6R7, O, or NR8; R6R7 are each independently H, C1-C6-alkyl, C1-C6-alkoxy, or C1-C6-alkoxy-C1-C6-alkyl; R8 is H, C1-C6-alkyl, or C1-C6-alkoxy-C1-C6-alkyl; k is 1, 2, 3, 4 or 5, as component A; b) 1.00 to 60.00% by weight of at least one monomer having two (meth)acrylate groups and having a molecular weight of no more than 500 Dalton, as component B; c) 0 to 25% by weight of at least one monomer having at least three (meth)acrylate groups and having a molecular weight of no more than 600 Dalton, as component C; and d) 1.00 to 30.00% by weight of at least one polymer having at least two (meth)acrylate groups and having a molecular weight of at least 700 Dalton, as component D; with the proviso that the amount of components A + B is at least 50% by weight, as well as the use of these compositions as printing inks, in particular inkjet printing inks.

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