Abstract:
PROBLEM TO BE SOLVED: To provide a method for the long term operation of a heterogeneously catalysed gas phase partial oxidation of propene in order to form acrolein. SOLUTION: A gas mixture (G) consisting of molecular oxygen, inert gas, and optionally steam, is introduced through the fixed catalyst bed at 250-550°C by increasing over time the temperature of a fixed heterogenous catalyst bed in which acrolein is produced from propene, and interrupting the gas phase partial oxidation at least once in 4,000 hour. COPYRIGHT: (C)2011,JPO&INPIT
Abstract:
The invention relates to a method for starting a heterogeneously catalyzed partial gas phase oxidation of acrolein into acrylic acid or of methacrolein into methacrylic acid at a fixed catalyst bed that is located in a shell-and-tube reactor cooled with a heat exchanger means, wherein the temperature of the heat exchanger means is = 290°C, and wherein the temperature of the reactor bottom surface facing the reactor gas inlet mixture and the temperature of the reaction gas inlet mixture are = 285°C.
Abstract:
A lubricant composition having improved non-Newtonian viscometrics includes at least 85 weight percent of a base oil and 1 to 15 weight percent of a lubricant additive. The additive itself includes 10 to 80 weight percent of a diluent oil and 30 to 80 weight percent of a random co-polymeric viscosity index improver. The viscosity index improver is the free-radical polymerization product of at least 5 to 15 weight percent methyl methacrylate and 5 to 95 weight percent of a C8-C10 alkyl (meth)acrylate. The additive is formed using a method that includes the step of providing the diluent oil, the methyl methacrylate, the C8-C10 alkyl (meth)acrylate, and a free-radical initiator. The method also includes the steps of flowing the diluent oil into a reactor, flowing the methyl methacrylate and the C8-C10 alkyl (meth)acrylate into the reactor independently from the free-radical initiator, and flowing the free-radical initiator into the reactor.
Abstract:
A process for preparing an ester of (meth)acrylic acid or a derivative thereof comprises reacting (meth)acrylic acid or a derivative thereof with glycerol carbonate at a reaction temperature of 10 to 150° C. without a solvent in the presence of at least one enzyme catalyzing the esterification reaction.
Abstract:
69Method for producing geometric catalyst molded bodies Abstract5 A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide of stoichiometry[BiaZ1bOx]p[BicM012FedZ2eZ3R49Z5i2610y]i,10 in which a finely divided oxide BiaZ1b0„ and, formed from element sources, a finely divided mixture of stoichiometry BicMol2Fe,22,Z3tZ49Z5hZ61 are mixed in a ratio of p:1,this mixture is used to form shaped bodies and these are treated thermally, where 0
Abstract:
Una composición lubricante que tiene propiedades viscométricas no newtonianas mejoradas incluye por lo menos 85 por ciento en peso de un aceite de base y 1 a 15 por ciento en peso de un aditivo lubricante. El aditivo mismo incluye 10 a 80 por ciento en peso de un aceite diluyente y 30 a 80 por ciento en peso de un mejorador de índice de viscosidad co-polimérico aleatorio. El mejorador de índice de viscosidad es el producto de polimerización por radicales libres de por lo menos 5 a 15 por ciento en peso de metacrilato de metilo y 5 a 95 por ciento en peso de un (met)acrilato de alquilo de C8-C10. El aditivo se forma usando un método que incluye el paso de hacer fluir el aceite diluyente, el metacrilato de metilo, el (met)acrilato de alquilo de C8-C10, y un iniciador de radicales libres. El método también incluye los pasos de hacer fluir el aceite diluyente en un reactor, hacer fluir el metacrilato de metilo y el (met)acrilato de alquilo de C8-C10 en el reactor independientemente del iniciador de radicales libres, y hacer fluir el iniciador de radicales libres en el reactor.
Abstract:
Disclosed is a method for producing catalytically active multielement oxide materials containing at least one of the elements Nb and W as well as elements Mo, V, and Cu. According to the inventive method, an intimate dry mixture containing ammonium ions is produced and is thermally treated at a raised temperature in an atmosphere that is low in molecular oxygen. A partial quantity of the ammonium ions contained in the intimate dry mixture is decomposed so as to release ammonia while the oxygen concentration of the thermal treatment atmosphere is increased in the course of the thermal treatment.
Abstract:
A process for the heterogeneously catalyzed gas-phase partial oxidation of an organic compound over a fixed catalyst bed present in a fixed-bed reactor having a plurality of catalyst tubes, in which the reduction of the quality of the catalyst load with increasing duration of operation is restored by a partial catalyst change, is described.
Abstract:
The invention relates to a method for the heterogenically catalysed partial gas phase oxidation of propene to form acrylic acid. According to said method, the reaction starting mixture with a propene charge of