公开(公告)号：WO2015004566A2

公开(公告)日：2015-01-15

申请号：PCT/IB2014062730

申请日：2014-06-30

Applicant: BASF SE ,  BASF CHINA CO LTD

Inventor： CUNNINGHAM ALLAN FRANCIS ,  MISTELI KATHARINA ,  DIETLIKER KURT ,  GRIMM BEAT

CPC classification number: C07F9/5337 ,  C08F2/50 ,  C09D4/00 ,  G03F7/027 ,  G03F7/029

Abstract: A photoinitiator mixture comprising the components (a) a compound of the Formula (I), wherein Ar1 and Ar2 independently of each other are Formula (IV) or naphthyl which is unsubstituted or substituted one or more times by R1, R2, R3 or R'; R1 and R3 independently of each other are C1-C4alkyl, C1-C4alkoxy or halogen; R2 is hydrogen, C1-C4alkyl, halogen, C1-C4alkoxy or C2-C20alkoxy which is interrupted by one or more O; Q is C1-C4alkylene; R4 is methyl or ethyl; R' and R" independently of each other are hydrogen or PG-Y-R'''-X-; PG is a polymerizable group or methyl or ethyl; Y is a direct bond, O or S; X is a direct bond, O or S; R''' is a direct bond, C1-C20alkylene or C2-C20alkylene which is interrupted by one or more O; (b) one or more compounds of the Formula (II), wherein Ar1, Ar2 and Q are as defined above, and R5 is for example C3-C30alkyl which is unsubstituted or substituted and (c) optionally a compound of the Formula (III), wherein R5 is as defined above; provides a liquid photoinitiator.

Abstract translation: （a）其中Ar1和Ar2彼此独立地为式（IV）的化合物或未被取代或被R1，R2，R3或R取代一次或多次的萘基的光引发剂混合物 “; R1和R3彼此独立地为C1-C4烷基，C1-C4烷氧基或卤素; R2是氢，被一个或多个O间隔的C1-C4烷基，卤素，C1-C4烷氧基或C2-C20烷氧基; Q是C1-C4亚烷基; R4是甲基或乙基; R'和R“彼此独立地为氢或PG-Y-R”' - X-; PG为可聚合基团或甲基或乙基; Y为直接键，O或S; X为直接键， O或S; R“'为被一个或多个O间隔的直接键，C1-C20亚烷基或C2-C20亚烷基;（b）一种或多种式（II）化合物，其中Ar1，Ar2和Q为 如上所定义，并且R 5为例如未被取代或被取代的C 3 -C 30烷基和（c）任选地其中R 5如上定义的式（III）化合物;提供液体光引发剂。

公开(公告)号：AU2014288876A1

公开(公告)日：2016-02-04

申请号：AU2014288876

申请日：2014-06-30

Applicant: BASF SE

Inventor： CUNNINGHAM ALLAN FRANCIS ,  MISTELI KATHARINA ,  DIETLIKER KURT ,  GRIMM BEAT

IPC: C07F9/50 ,  C08F2/24 ,  C09D4/00

Abstract: A photoinitiator mixture comprising the components (a) a compound of the Formula (I), wherein Ar

公开(公告)号：EP3019508A4

公开(公告)日：2017-04-12

申请号：EP14822691

申请日：2014-06-30

Applicant: BASF SE

Inventor： CUNNINGHAM ALLAN FRANCIS ,  MISTELI KATHARINA ,  DIETLIKER KURT ,  GRIMM BEAT

IPC: C07F9/53 ,  G03F7/029

CPC classification number: C07F9/5337 ,  C08F2/50 ,  C09D4/00 ,  G03F7/027 ,  G03F7/029

Abstract: A photoinitiator mixture comprising the components (a) a compound of the formula (I) wherein Ar and Ar2 independently of each other are or naphthyl which is unsubstituted or substituted one or more times by R1, R2, R3 or R′; R1 and R3 in-dependently of each other are C1-C4alkyl, C1-C4alkoxy or halogen; R2 is hydrogen, C1-C4alkyl, halogen, C1-C4alkoxy or C2-C20alkoxy which is interrupted by one or more O; Q is C1-C4alkylene; R4 is methyl or ethyl; R′ and R″ independently of each other are hydrogen or PG-Y-R′″—X—; PG is a polymerizable group or methyl or ethyl; Y is a direct bond, O or S; X is a direct bond, O or S; R′″ is a direct bond, C1-C20alkylene or C2-C20alkylene which is interrupted by one or more O; (b) one or more compounds of the formula (II) wherein Ar1, Ar2 and Q are as defined above, and R5 is for example C3-C30alkyl which is unsubstituted or substituted and (c) optionally a compound of the formula (III) R5—OH   (III), wherein R5 is as defined above; provides a liquid photointiator.