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公开(公告)号:WO2015004566A2
公开(公告)日:2015-01-15
申请号:PCT/IB2014062730
申请日:2014-06-30
Applicant: BASF SE , BASF CHINA CO LTD
Inventor: CUNNINGHAM ALLAN FRANCIS , MISTELI KATHARINA , DIETLIKER KURT , GRIMM BEAT
CPC classification number: C07F9/5337 , C08F2/50 , C09D4/00 , G03F7/027 , G03F7/029
Abstract: A photoinitiator mixture comprising the components (a) a compound of the Formula (I), wherein Ar1 and Ar2 independently of each other are Formula (IV) or naphthyl which is unsubstituted or substituted one or more times by R1, R2, R3 or R'; R1 and R3 independently of each other are C1-C4alkyl, C1-C4alkoxy or halogen; R2 is hydrogen, C1-C4alkyl, halogen, C1-C4alkoxy or C2-C20alkoxy which is interrupted by one or more O; Q is C1-C4alkylene; R4 is methyl or ethyl; R' and R" independently of each other are hydrogen or PG-Y-R'''-X-; PG is a polymerizable group or methyl or ethyl; Y is a direct bond, O or S; X is a direct bond, O or S; R''' is a direct bond, C1-C20alkylene or C2-C20alkylene which is interrupted by one or more O; (b) one or more compounds of the Formula (II), wherein Ar1, Ar2 and Q are as defined above, and R5 is for example C3-C30alkyl which is unsubstituted or substituted and (c) optionally a compound of the Formula (III), wherein R5 is as defined above; provides a liquid photoinitiator.
Abstract translation: (a)其中Ar1和Ar2彼此独立地为式(IV)的化合物或未被取代或被R1,R2,R3或R取代一次或多次的萘基的光引发剂混合物 “; R1和R3彼此独立地为C1-C4烷基,C1-C4烷氧基或卤素; R2是氢,被一个或多个O间隔的C1-C4烷基,卤素,C1-C4烷氧基或C2-C20烷氧基; Q是C1-C4亚烷基; R4是甲基或乙基; R'和R“彼此独立地为氢或PG-Y-R”' - X-; PG为可聚合基团或甲基或乙基; Y为直接键,O或S; X为直接键, O或S; R“'为被一个或多个O间隔的直接键,C1-C20亚烷基或C2-C20亚烷基;(b)一种或多种式(II)化合物,其中Ar1,Ar2和Q为 如上所定义,并且R 5为例如未被取代或被取代的C 3 -C 30烷基和(c)任选地其中R 5如上定义的式(III)化合物;提供液体光引发剂。
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公开(公告)号:WO2010103087A3
公开(公告)日:2011-02-24
申请号:PCT/EP2010053136
申请日:2010-03-11
Applicant: BASF SE , CUNNINGHAM ALLAN FRANCIS , HOSSENLOPP CELINE , SCHNEIDER HEINZ , TRABER RAINER HANS , HERRMANN HORST , JACQUIER MICHAEL
Inventor: CUNNINGHAM ALLAN FRANCIS , HOSSENLOPP CELINE , SCHNEIDER HEINZ , TRABER RAINER HANS , HERRMANN HORST , JACQUIER MICHAEL
CPC classification number: C09B67/0041 , C09B67/0073 , C09B67/0083 , D21H21/28 , D21H23/04
Abstract: The present invention relates to an aqueous direct dye formulation, comprising (a) 5 to 25 % by weight of a dye composition comprising (a1) 50-99 % by weight of one or more dyes obtainable by reduction or thermal treatment of Direct Yellow 11, and (a2) 1 -50 % by weight of a blue, black and/or red direct dye, (all based on the dye composition); (b) up to 0.9 % by weight of a saturated, cyclic or acyclic water-soluble amine comprising a primary, secondary or tertiary amino group and at least one further functional group selected from primary, secondary and tertiary amino groups, OH groups and ether groups; and (c) up to 0.9 % by weight of urea; and (d) water, wherein the percentages for (a), (b), and (c) relate to the total weight of the aqueous direct dye formulation. The invention moreover relates to a process for their preparation and the use thereof for the dyeing, in particular of paper, as well as paper which has been dyed with this aqueous direct dye formulation.
Abstract translation: 本发明涉及一种水性直接染料配方,其包含(a)5至25重量%的染料组合物,其包含(a1)50-99重量%的一种或多种可通过还原或热处理直接黄11 ,和(a2)1〜50重量%的蓝色,黑色和/或红色直接染料(均基于染料组合物); (b)至多0.9重量%的饱和,环状或无环状水溶性胺,其包含伯,仲或叔氨基和至少一个选自伯,仲和叔氨基的另外的官能团,OH基团和醚 组; 和(c)至多0.9重量%的尿素; 和(d)水,其中(a),(b)和(c)的百分比与水性直接染料制剂的总重量有关。 此外,本发明涉及其制备方法及其用于染色,特别是纸的用途,以及已经用该水性直接染料配方染色的纸。
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3.
公开(公告)号:EP3019508A4
公开(公告)日:2017-04-12
申请号:EP14822691
申请日:2014-06-30
Applicant: BASF SE
Inventor: CUNNINGHAM ALLAN FRANCIS , MISTELI KATHARINA , DIETLIKER KURT , GRIMM BEAT
CPC classification number: C07F9/5337 , C08F2/50 , C09D4/00 , G03F7/027 , G03F7/029
Abstract: A photoinitiator mixture comprising the components (a) a compound of the formula (I) wherein Ar and Ar2 independently of each other are or naphthyl which is unsubstituted or substituted one or more times by R1, R2, R3 or R′; R1 and R3 in-dependently of each other are C1-C4alkyl, C1-C4alkoxy or halogen; R2 is hydrogen, C1-C4alkyl, halogen, C1-C4alkoxy or C2-C20alkoxy which is interrupted by one or more O; Q is C1-C4alkylene; R4 is methyl or ethyl; R′ and R″ independently of each other are hydrogen or PG-Y-R′″—X—; PG is a polymerizable group or methyl or ethyl; Y is a direct bond, O or S; X is a direct bond, O or S; R′″ is a direct bond, C1-C20alkylene or C2-C20alkylene which is interrupted by one or more O; (b) one or more compounds of the formula (II) wherein Ar1, Ar2 and Q are as defined above, and R5 is for example C3-C30alkyl which is unsubstituted or substituted and (c) optionally a compound of the formula (III) R5—OH (III), wherein R5 is as defined above; provides a liquid photointiator.
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公开(公告)号:MX2011009081A
公开(公告)日:2011-09-27
申请号:MX2011009081
申请日:2010-03-11
Applicant: BASF SE
Inventor: TRABER RAINER HANS , CUNNINGHAM ALLAN FRANCIS , SCHNEIDER HEINZ , HOSSENLOPP CELINE , HERRMANN HORST , JACQUIER MICHAEL
Abstract: La presente invención se relaciona con una formulación acuosa de tinte directo, que comprende (a) 5 a 25% en peso de una composición de tinte que comprende (al) 50-99% en peso de uno o más tintes obtenibles mediante reducción o tratamiento térmico de Amarillo Directo 11, y (a2) 1-50% en peso de un tinte directo azul, negro y/o rojo, (todo basado en la composición de tinte; (b) hasta 0.9% en peso de una amina saturada, cíclica o acíclica soluble en agua que comprende un grupo amino primario, secundario o terciario y cuando menos un grupo funcional adicional seleccionado de grupos amino primario, secundario o terciario, grupos OH y grupos de éter, y (c) hasta 0.9% en peso de urea; y (d) agua, en donde los porcentajes para (a), (b), y (c) se relacionan con el peso total dela formulación acuosa de tinte directo. La invención se relaciona además con un proceso para su preparación y al uso de las mismas para el teñido, en particular de papel, así como el papel que se ha teñido con esta formulación acuosa de tinte directo.
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公开(公告)号:AU2008225921A1
公开(公告)日:2008-09-18
申请号:AU2008225921
申请日:2008-03-05
Applicant: BASF SE
Inventor: FONDEKAR KAMALESH PAI , BIRBAUM JEAN-LUC , CUNNINGHAM ALLAN FRANCIS , EHLIS THOMAS , HAYOZ PASCAL
IPC: C09D5/26 , B41M5/333 , C07D251/14 , C07D251/24 , C08K5/3492 , C09D7/00
Abstract: The present invention provides heat-sensitive coating compositions, which comprise a color developer of formula (1) or mixtures thereof wherein R1 can be hydrogen, C1-20-alkyl, C3-8-cycloalkyl, C2-10-alkenyl, aryl or SO3H, and R2 and R3 can be the same or different and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8, SR9, SO3H or COOR10 and R4 and R5 can be the same or different, and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8 or SR9, R6, R7, R8, R9 and R10 can be the same or different and can be hydrogen, C1-30-alkyl, C3-8-cycloalkyl, C2-10-alkenyl or aryl, wherein C1-20-alkyl can be unsubstituted or substituted with one or more C3-8-cycloalkyl, C2-10-alkenyl, phenyl, halogen, OR11, NR12R13, SR14, SO3H or COOR15, and aryl can be unsubstituted or substituted with one or more halogen, C1-10-alkyl, halogenated C1-10-alkyl, C3-8-cycloalkyl C2-10-alkenyl, phenyl, OR11, NR12R13, SR14, SO3H or COOR15, wherein R11, R12, R13, R14 and R15 can be the same or different and can be hydrogen, C1-10-alkyl, C3-8-cycloalkyl or C2-10-alkenyl, a process for the preparation of these compositions, a process of coating substrates with these compositions, substrates coated with these compositions, a process for preparing marked substrates using these compositions, marked substrates obtainable by the latter process, and certain color developers.
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6.
公开(公告)号:MX2009009394A
公开(公告)日:2009-09-11
申请号:MX2009009394
申请日:2008-03-05
Applicant: BASF SE
Inventor: BIRBAUM JEAN-LUC , HAYOZ PASCAL , CUNNINGHAM ALLAN FRANCIS , EHLIS THOMAS , FONDEKAR KAMALESH PAI
IPC: C09D5/26 , B41M5/333 , C07D251/14 , C07D251/24 , C08K5/3492 , C09D7/00
Abstract: La presente invención proporciona composiciones de revestimiento termosensibles las cuales contienen un revelador de color de fórmula (I) o mezclas de éste, en donde R1 puede ser hidrógeno, alquilo de C1-20, cicloalquilo de C3-8, alquenilo de C2-10, arilo ó SO3H, y R2 y R3 pueden ser iguales o diferentes y pueden ser hidrógeno, halógeno, alquilo de C2-10, cicloalquilo de C3..8, alquenilo de C2-10, arilo, 0R6, NR7R8, SR9, SO3H ó COOR'°, y R4 y R5 pueden ser iguales o diferentes, y pueden ser hidrógeno, halógeno, alquilo de C,..20, cicloalquilo de C3-8, alquenilo de C2-10, arilo, 0R6., NR7R8 6 SR9, R6, R7, R8, R9 y R'° pueden ser iguales o diferentes y pueden ser hidrógeno, alquilo C3-8, cicloalquilo de C38, alquenilo de C2-10 o arilo, en donde alquilo C2-10 puede estar no sustituido o sustituido con uno o más cicloalquilo de C3-8, alquenilo de C2-10, fenilo, halógeno, OR", NR12R13, SR14, SO3H ó COOR15, y arilo puede estar no sustituido o sustituido con uno o más halógeno, alquilo de el_lo, alquilo de C1-10 halogenado, cicloalquilo de C3-8, alquenilo de C2-10, fenilo, OR", NR12R13, SR'4, SO3H ó COOR'5, en donde R11, R12, R13, R14 y R15 pueden ser iguales o diferentes, y pueden ser hidrógeno, alquilo de el_lo, cicloalquilo de C3-8 6 alquenilo de C2-10, un proceso para la preparación de estas composiciones, un proceso de revestimiento de sustratos con estas composiciones, los sustratos revestidos con estas composiciones, un proceso para preparar sustratos marcados utilizando estas composiciones, sustratos marcados que pueden obtenerse por el proceso anterior y ciertos reveladores de color.
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公开(公告)号:CA3089381A1
公开(公告)日:2019-09-06
申请号:CA3089381
申请日:2019-02-28
Applicant: BASF SE
Inventor: NESVADBA PETER , CUNNINGHAM ALLAN FRANCIS , HINDALEKAR SHIRANG , POTHI TEJAS , NAVE BARBARA , WALLQUIST OLOF , WISSEMEIER ALEXANDER
Abstract: The present invention relates to novel nitrification inhibitors of formula (I), which are pyrazole propargyl ether compounds. Moreover, the invention relates to the use of compounds of formula (I) as nitrification inhibitors, i.e. for reducing nitrification, as well as agrochemical mixtures and compositions comprising the nitrification inhibitors of formula (I).
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公开(公告)号:CA3043443A1
公开(公告)日:2018-06-07
申请号:CA3043443
申请日:2017-11-21
Applicant: BASF SE
Inventor: JENEWEIN STEFAN , FISCHER MAX-PHILIPP , HOEFFKEN HANS WOLFGANG , ACHENBACH JANOSCH HARALD , SPANGENBERG OLIVER , CUNNINGHAM ALLAN FRANCIS , NIELSEN JESPER
Abstract: A composition comprising component (a) at least one phenyl boronic acid and component (b) pentane-1,2-diol and optionally one or more further diols wherein the composition is liquid at 20°C and 101.3 kPa. Said composition stabilizes serine protease.
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公开(公告)号:AU2014288876A1
公开(公告)日:2016-02-04
申请号:AU2014288876
申请日:2014-06-30
Applicant: BASF SE
Inventor: CUNNINGHAM ALLAN FRANCIS , MISTELI KATHARINA , DIETLIKER KURT , GRIMM BEAT
Abstract: A photoinitiator mixture comprising the components (a) a compound of the Formula (I), wherein Ar
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公开(公告)号:BRPI0808446A2
公开(公告)日:2014-08-05
申请号:BRPI0808446
申请日:2008-03-05
Applicant: BASF SE
Inventor: CUNNINGHAM ALLAN FRANCIS , EHLIS THOMAS , BIRBAUM JEAN-LUC , HAYOZ PASCAL , FONDEKAR KAMALESH PAI
IPC: C09D5/26 , B41M5/333 , C07D251/14 , C07D251/24 , C08K5/3492 , C09D7/00
Abstract: The present invention provides heat-sensitive coating compositions, which comprise a color developer of formula (1) or mixtures thereof wherein R1 can be hydrogen, C1-20-alkyl, C3-8-cycloalkyl, C2-10-alkenyl, aryl or SO3H, and R2 and R3 can be the same or different and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8, SR9, SO3H or COOR10 and R4 and R5 can be the same or different, and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8 or SR9, R6, R7, R8, R9 and R10 can be the same or different and can be hydrogen, C1-30-alkyl, C3-8-cycloalkyl, C2-10-alkenyl or aryl, wherein C1-20-alkyl can be unsubstituted or substituted with one or more C3-8-cycloalkyl, C2-10-alkenyl, phenyl, halogen, OR11, NR12R13, SR14, SO3H or COOR15, and aryl can be unsubstituted or substituted with one or more halogen, C1-10-alkyl, halogenated C1-10-alkyl, C3-8-cycloalkyl C2-10-alkenyl, phenyl, OR11, NR12R13, SR14, SO3H or COOR15, wherein R11, R12, R13, R14 and R15 can be the same or different and can be hydrogen, C1-10-alkyl, C3-8-cycloalkyl or C2-10-alkenyl, a process for the preparation of these compositions, a process of coating substrates with these compositions, substrates coated with these compositions, a process for preparing marked substrates using these compositions, marked substrates obtainable by the latter process, and certain color developers.
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