Abstract:
Un procedimiento de preparación de una estructura organometálica porosa que comprende al menos un compuesto orgánico al menos bidentado coordinado a al menos un ión metálico, en el que el al menos un ión metálico es a base de un ión de aluminio y el al menos un compuesto orgánico al menos bidentado es a base de ácido fumárico, que comprende la etapa de hacer reaccionar al menos un compuesto de aluminio con al menos ácido fumárico en un medio acuoso alcalino, opcionalmente en presencia de al menos una base, a una temperatura en el intervalo de 20 ºC a 100 ºC a una presión absoluta no superior a 200 kPa durante 0,2 a 4 horas, en el que la base es un hidróxido de un metal alcalino o una mezcla de una pluralidad de diferentes hidróxidos de metales alcalinos.
Abstract:
The present invention relates to a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is based on an aluminum ion and the at least one at least bidentate organic compound is based on fumaric acid, by reacting at least one aluminum compound with at least fumaric acid in an alkaline aqueous medium, optionally in the presence of at least one base, at a temperature in the range from 20°C to 100°C at an absolute pressure of not more than 2 bar for from 0.2 to 4 hours.
Abstract:
Procedimiento de recuperación de un compuesto orgánico al menos bidentado comprendido en un material estructural organometálico poroso, el material comprendiendo el compuesto orgánico al menos bidentado coordinado con al menos un ion metálico, el procedimiento comprendiendo las etapas de (a) tratar el material estructural organometálico con un líquido ácido o alcalino; (b) opcionalmente separar el residuo sólido; (c) aislar el compuesto orgánico al menos bidentado.
Abstract:
The present invention relates to a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is based on an aluminum ion and the at least one at least bidentate organic compound is based on fumaric acid, by reacting at least one aluminum compound with at least fumaric acid in an alkaline aqueous medium, optionally in the presence of at least one base, at a temperature in the range from 20°C to 100°C at an absolute pressure of not more than 2 bar for from 0.2 to 4 hours.
Abstract:
The present invention relates to a process for the recovery of an at least bidentate organic compound comprised in a porous metal-organic framework material, the material comprising the at least bidentate organic compound coordinated to at least one metal ion, the process comprising the steps of (a) treating the metal-organic framework material with an acidic or alkaline liquid; (b) optionally separating off solid residue; and (c) isolating the at least bidentate organic compound.