Abstract:
PROBLEM TO BE SOLVED: To provide an improved method for manufacturing a polyvinyl pyrrolidone. SOLUTION: In the method for manufacturing the polyvinyl pyrrolidone by a polymerization initiated by a free radical in the presence of an initiator, the polymerization is carried out by spray polymerization or droplet polymerization. The initiator to be used is an organic or inorganic peroxide, a hydroperoxide, a persulfate, an azo compound, a photo-initiator or a redox initiator. The polymerization is carried out in a water solution at a polymerization temperature of 70-250°C by forming and spraying droplets in an inert gas flow or forming droplets and carrying out the polymerization in a spray tower. COPYRIGHT: (C)2009,JPO&INPIT
Abstract:
Process for producing polymers by spray polymerization wherein the aqueous monomer solution comprises from 0.01% to 0.2% by weight, based on the monomer, of at least one crosslinker, the use of the polymers for thickening liquids and also apparatus for producing polymers by spray polymerization.
Abstract:
In the spray condensation process for the preparation of dried resins in powder form from melamine, urea or a mixture thereof and at least one aldehyde, the morphology of the resin particles produced is influenced in a targeted manner with respect to their particle parameters.
Abstract:
Process for producing polymers by spray polymerization wherein the aqueous monomer solution comprises from 0.01% to 0.2% by weight, based on the monomer, of at least one crosslinker, the use of the polymers for thickening liquids and also apparatus for producing polymers by spray polymerization.
Abstract:
Monomer solutions with a water content of at least 55 wt% are used in a method for the spray polymerisation of monomer solutions containing radically-polymerisable monomers in an inert atmosphere. An independent claim is also included for water-swellable polymers obtained by this method.
Abstract:
Procedimiento para la obtención de partículas de polímero mediante polimerización de una emulsión, quecontiene al menos un monómero con insaturación etilénica, al menos un agente auxiliar dispersante, al menos uniniciador de polimerización y agua, estando dispersado en agua el monómero con insaturación etilénica,caracterizado porque la emulsión se dosifica en un espacio de reacción sólo en el caso de una conversión demonómeros con insaturación etilénica de un 1 a un 98 %, bajo formación de gotas discretas, y - atravesándose el reactor de polimerización por un gas, - calentándose previamente el gas a temperatura de reacción antes del reactor, - ascendiendo la temperatura de entrada de gas a 110-200ºC en el espacio de reacción, - ascendiendo la temperatura de salida de gas a 60 hasta 120ºC, y caracterizado porque el procedimiento depolimerización se lleva a cabo en dos etapas.
Abstract:
A process for preparing polyvinylpyrrolidones by free-radically initiated polymerization in the presence of an initiator found, which comprises performing the polymerization as a spray or droplet polymerization.
Abstract:
In the spray condensation process for the preparation of dried resins in powder form from melamine, urea or a mixture thereof and at least one aldehyde, the morphology of the resin particles produced is influenced in a targeted manner with respect to their particle parameters.