公开(公告)号：AT454387T

公开(公告)日：2010-01-15

申请号：AT07787520

申请日：2007-07-13

Applicant: BASF SE

Inventor： SCHUBERT MARKUS ,  OEZKIRIM FARUK ,  KIENER CHRISTOPH ,  MUELLER ULRICH ,  TONIGOLD MARKUS

IPC: C07F1/00

Abstract: The present invention relates to a process for preparing a porous metal organic framework comprising a first and at least one second at least bidentate organic compound coordinated to at least one copper ion, which comprises the steps (a) reaction of a reaction mixture in the liquid phase comprising at least one copper compound and the first at least bidentate organic compound to form an intermediate complex comprising the at least one copper ion and the first at least bidentate organic compound, with the first at least bidentate organic compound being derived from a dicarboxylic acid and having a skeleton which is a hydrocarbon, and (b) reaction of the intermediate complex with the at least second at least bidentate organic compound, with the at least second at least bidentate organic compound being an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) comprises less than a 3-fold excess of formic acid based on the copper of the copper compound used.

公开(公告)号：MX2009000979A

公开(公告)日：2009-02-04

申请号：MX2009000979

申请日：2007-07-13

Applicant: BASF SE

Inventor： MUELLER ULRICH ,  SCHUBERT MARKUS ,  TONIGOLD MARKUS ,  KIENER CHRISTOPH ,  OEZKIRIM FARUK

IPC: C07F1/00

Abstract: La presente invención se relaciona a métodos para producir un material de entramado organometálico, poroso que contiene por lo menos un primero y por lo menos un segundo compuesto orgánico bidentado unido en forma coordinada a por lo menos un ión de cobre, incluyendo las siguientes etapas: (a) La reacción de una mezcla de reacción en la fase líquida que contiene por lo menos un compuesto de cobre y por lo menos el primer compuesto orgánico bidentado con formación de un complejo intermedio que contiene por lo menos un ión de cobre y por lo menos el primer compuesto orgánico bidentado, en donde por lo menos el primer compuesto orgánico bidentado se deriva de un ácido dicarboxílico y tiene un entramado de hidrocarburo, y (b) La reacción del complejo intermedio con por lo menos un segundo compuesto orgánico bidentado, en donde por lo menos el segundo compuesto orgánico bidentado es un hidrocarburo saturado o insaturado, monocíclico, bicíclico o policíclico, opcionalmente sustituido en el cual por lo menos dos átomos de carbono en el anillo se reemplazan por heteroátomos seleccionados del grupo que consiste de N, O y S, en donde la mezcla de reacción en la etapa (a) tiene menos de una cantidad triple en exceso de 25 del ácido fórmico con base en el cobre utilizado en el compuesto de cobre.

公开(公告)号：BRPI0715108A2

公开(公告)日：2013-03-19

申请号：BRPI0715108

申请日：2007-07-13

Applicant: BASF SE

Inventor： SCHUBERT MARKUS ,  OEZKIRIM FARUK ,  KIENER CRISTOPH ,  MUELLER ULRICH ,  TONIGOLD MARKUS

IPC: C07F1/00

Abstract: The present invention relates to a process for preparing a porous metal organic framework comprising a first and at least one second at least bidentate organic compound coordinated to at least one copper ion, which comprises the steps (a) reaction of a reaction mixture in the liquid phase comprising at least one copper compound and the first at least bidentate organic compound to form an intermediate complex comprising the at least one copper ion and the first at least bidentate organic compound, with the first at least bidentate organic compound being derived from a dicarboxylic acid and having a skeleton which is a hydrocarbon, and (b) reaction of the intermediate complex with the at least second at least bidentate organic compound, with the at least second at least bidentate organic compound being an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) comprises less than a 3-fold excess of formic acid based on the copper of the copper compound used.

公开(公告)号：DE502007002576D1

公开(公告)日：2010-02-25

申请号：DE502007002576

申请日：2007-07-13

Applicant: BASF SE

Inventor： SCHUBERT MARKUS ,  OEZKIRIM FARUK ,  KIENER CHRISTOPH ,  MUELLER ULRICH ,  TONIGOLD MARKUS

IPC: C07F1/00

Abstract: The present invention relates to a process for preparing a porous metal organic framework comprising a first and at least one second at least bidentate organic compound coordinated to at least one copper ion, which comprises the steps (a) reaction of a reaction mixture in the liquid phase comprising at least one copper compound and the first at least bidentate organic compound to form an intermediate complex comprising the at least one copper ion and the first at least bidentate organic compound, with the first at least bidentate organic compound being derived from a dicarboxylic acid and having a skeleton which is a hydrocarbon, and (b) reaction of the intermediate complex with the at least second at least bidentate organic compound, with the at least second at least bidentate organic compound being an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) comprises less than a 3-fold excess of formic acid based on the copper of the copper compound used.