公开(公告)号：BRPI0710208A2

公开(公告)日：2011-05-24

申请号：BRPI0710208

申请日：2007-03-22

Applicant: BASF SE

Inventor： SCHUBERT MARKUS ,  MUELLER ULRICH ,  KIENER CRISTOPH ,  TEICH FRIEDHELM ,  CRONE SVEN ,  SIMON FALK ,  PASTRE JOERG

IPC: C07C7/13 ,  B01D53/02 ,  B01J20/22 ,  C07C11/06 ,  C10L3/10

Abstract: The invention relates to a method for commercially obtaining propene from a gas flow containing propene and at least one additional hydrocarbon. Said method comprises the following steps; (a) the gas flow is brought into contact with an adsorber containing a porous metalorganic framework material containing at least one at least bidentate organic compound which is co-ordinately bound to at least one metal ion, said adsorber being charged with propene; and (b) the propene is released from the adsorber charged with the propene. The invention further relates to the use of a porous metalorganic framework material for commercially obtaining propene from a gas flow containing propene and at least one additional hydrocarbon.

公开(公告)号：BRPI0715108A2

公开(公告)日：2013-03-19

申请号：BRPI0715108

申请日：2007-07-13

Applicant: BASF SE

Inventor： SCHUBERT MARKUS ,  OEZKIRIM FARUK ,  KIENER CRISTOPH ,  MUELLER ULRICH ,  TONIGOLD MARKUS

IPC: C07F1/00

Abstract: The present invention relates to a process for preparing a porous metal organic framework comprising a first and at least one second at least bidentate organic compound coordinated to at least one copper ion, which comprises the steps (a) reaction of a reaction mixture in the liquid phase comprising at least one copper compound and the first at least bidentate organic compound to form an intermediate complex comprising the at least one copper ion and the first at least bidentate organic compound, with the first at least bidentate organic compound being derived from a dicarboxylic acid and having a skeleton which is a hydrocarbon, and (b) reaction of the intermediate complex with the at least second at least bidentate organic compound, with the at least second at least bidentate organic compound being an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) comprises less than a 3-fold excess of formic acid based on the copper of the copper compound used.