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公开(公告)号：US08889905B2
公开(公告)日：2014-11-18
申请号：US13721392
申请日：2012-12-20
Applicant: BASF SE
Inventor： Peter Bassler , Stefan Rittinger , Daniel Schneider , Donata Maria Fries , Klaus-Dieter Mohl , Joaquim Henrique Teles , Martin Schäfer , Jürgen Paschold
Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid and tertiary amine (I) is produced by combining tertiary amine (I) and a formic acid source, secondary components comprised therein are separated off, formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, where the bottom output from the distillation apparatus is separated into two liquid phases, and the upper liquid phase is recirculated to the formic acid source and the lower liquid phase is recirculated to the separation of the secondary components and/or to the distillation apparatus, wherein low boilers are removed by distillation from the upper liquid phase and recirculated to the depleted stream.
Abstract translation: 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中包含甲酸和叔胺（I）的液体流通过将叔胺（I）和甲酸源 ，其中包含的次要组分被分离出来，在蒸馏装置中从所得液流中蒸馏除去甲酸，其中蒸馏装置的底部输出分离成两个液相，上部液相再循环到甲酸 酸源和下液相再循环至次级组分和/或蒸馏装置的分离，其中通过蒸馏从上液相除去低锅炉并再循环至贫化物流。
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公开(公告)号：US20140148617A1
公开(公告)日：2014-05-29
申请号：US14088805
申请日：2013-11-25
Applicant: BASF SE
Inventor： Donata Maria Fries , Klaus-Dieter Mohl , Martin Schäfer , Daniel Schneider , Peter Bassler , Stefan Rittinger , Joaquim Henrique Teles
IPC: C07C51/44
Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which, in step (a), a liquid stream comprising formic acid, methanol, water and tertiary amine (I) is produced by combining methyl formate, water and tertiary amine (I), from there in step (b), methanol is separated off and in step (c), formic acid is removed by distillation from the liquid stream obtained in a distillation apparatus, wherein, when methyl formate, water and tertiary amine (I) are combined, methyl formate, water and optionally tertiary amine (I) are first introduced in step (a1) in a molar ratio of 0≦n(amine to a1)/n(mefo to a1)≦0.1, and from 70 to 100% of the hydrolysis equilibrium possible is set and then, in step (a2), tertiary amine (I) is introduced in a molar ratio of 0.1≦n(amine to a2)/n(mefo to a1)≦2, and the mixture is reacted.
Abstract translation: 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中在步骤（a）中，包含甲酸，甲醇，水和叔胺（I）的液体流由 在步骤（b）中从甲酸甲酯，水和叔胺（I）组合，分离出甲醇，在步骤（c）中，通过蒸馏从蒸馏设备中得到的液体物流除去甲酸，其中，当 甲酸甲酯，水和叔胺（I）组合，首先在步骤（a1）中以甲酸甲酯，水和任选的叔胺（I）以0和nlE; n（胺至a1）/ n（mefo至 a1）＆nlE; 0.1和70〜100％的水解平衡是可能的，然后在步骤（a2）中，以0.1和nlE的摩尔比引入叔胺（I）; n（胺与a2）/ n（mefo to a1）＆nlE; 2，使混合物反应。
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公开(公告)号：US09493405B2
公开(公告)日：2016-11-15
申请号：US14941167
申请日：2015-11-13
Applicant: BASF SE
Inventor： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Tobias Aechtner , Peter Pfab , Petra Deckert , Wolfgang Siegel , Peter Bassler
IPC: C07C253/30 , C07C253/10
CPC classification number: C07C253/30 , C07C253/10 , Y02P20/582 , C07C255/07
Abstract: A process is described for preparing 3-pentenenitrile, characterized by the following process steps: (a) isomerizing a reactant stream which comprises 2-methyl-3-butenenitrile over at least one dissolved or dispersed isomerization catalyst to give a stream 1 which comprises the at least one isomerization catalyst, 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile, (b) distilling stream 1 to obtain a stream 2 as the top product which comprises 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile, and a stream 3 as the bottom product which comprises the at least one isomerization catalyst, (c) distilling stream 2 to obtain a stream 4 as the top product which, compared to stream 2, is enriched in (Z)-2-methyl-2-butenenitrile, based on the sum of all pentenenitriles in stream 2, and a stream 5 as the bottom product which, compared to stream 2, is enriched in 3-pentenenitrile and 2-methyl-3-butenenitrile, based on the sum of all pentenenitriles in stream 2, (d) distilling stream 5 to obtain a stream 6 as the bottom product which comprises 3-pentenenitrile and a stream 7 as the top product which comprises 2-methyl-3-butenenitrile.
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公开(公告)号：US09428438B2
公开(公告)日：2016-08-30
申请号：US14088805
申请日：2013-11-25
Applicant: BASF SE
Inventor： Donata Maria Fries , Klaus-Dieter Mohl , Martin Schäfer , Daniel Schneider , Peter Bassler , Stefan Rittinger , Joaquim Henrique Teles
Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which, in step (a), a liquid stream comprising formic acid, methanol, water and tertiary amine (I) is produced by combining methyl formate, water and tertiary amine (I), from there in step (b), methanol is separated off and in step (c), formic acid is removed by distillation from the liquid stream obtained in a distillation apparatus, wherein, when methyl formate, water and tertiary amine (I) are combined, methyl formate, water and optionally tertiary amine (I) are first introduced in step (a1) in a molar ratio of 0≦n(amine to a1)/n(mefo to a1)≦0.1, and from 70 to 100% of the hydrolysis equilibrium possible is set and then, in step (a2), tertiary amine (I) is introduced in a molar ratio of 0.1≦n(amine to a2)/n(mefo to a1)≦2, and the mixture is reacted.
Abstract translation: 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中在步骤（a）中，包含甲酸，甲醇，水和叔胺（I）的液体流由 在步骤（b）中从甲酸甲酯，水和叔胺（I）组合，分离出甲醇，在步骤（c）中，通过蒸馏从蒸馏设备中得到的液体物流除去甲酸，其中，当 甲酸甲酯，水和叔胺（I）的组合，首先在步骤（a1）中以0≤n（胺与a1）/ n（mefo与n = 1）的摩尔比引入甲酸甲酯，水和任选的叔胺（I） a1）≤0.1，可以设定70〜100％的水解平衡，然后在步骤（a2）中，导入叔胺（I），摩尔比为0.1≤n（胺与a2）/ n（ mefo至a1）≤2，并使混合物反应。
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Patent Agency Ranking
公开(公告)号：US20140018456A1
公开(公告)日：2014-01-16
申请号：US13721392
申请日：2012-12-20
Applicant: BASF SE
Inventor： Peter Bassler , Stefan Rittinger , Daniel Schneider , Donata Maria Fries , Klaus-Dieter Mohl , Joaquim Henrique Teles , Martin Schäfer , Jürgen Paschold
IPC: C07C51/44
Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid and tertiary amine (I) is produced by combining tertiary amine (I) and a formic acid source, secondary components comprised therein are separated off, formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, where the bottom output from the distillation apparatus is separated into two liquid phases, and the upper liquid phase is recirculated to the formic acid source and the lower liquid phase is recirculated to the separation of the secondary components and/or to the distillation apparatus, wherein low boilers are removed by distillation from the upper liquid phase and recirculated to the depleted stream.
Abstract translation: 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中包含甲酸和叔胺（I）的液体流通过将叔胺（I）和甲酸源 ，其中包含的次要组分被分离出来，在蒸馏装置中从所得液流中蒸馏除去甲酸，其中蒸馏装置的底部输出分离成两个液相，上部液相再循环到甲酸 酸源和下液相再循环至次级组分和/或蒸馏装置的分离，其中通过蒸馏从上液相除去低锅炉并再循环至贫化物流。
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公开(公告)号：US09725428B2
公开(公告)日：2017-08-08
申请号：US14907998
申请日：2014-07-16
Applicant: BASF SE , Dow Global Technologies LLC
Inventor： Joaquim Henrique Teles , Bianca Seelig , Dominic Riedel , Philip Kampe , Daniel Urbanczyk , Markus Weber , Ulrich Mueller , Andrei-Nicolae Parvulescu , Kai Gumlich , Peter Bassler , Christian Bartosch , Richard Jacubinas , Meinolf Weidenbach , Werner Witzl
IPC: C07D303/00 , C07D301/12 , B01J29/70 , B01J35/00 , B01J35/10 , B01J27/18 , B01J27/188
CPC classification number: C07D301/12 , B01J27/18 , B01J27/188 , B01J29/7038 , B01J29/7088 , B01J35/002 , B01J35/1019 , B01J2229/186 , Y02P20/52
Abstract: A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt of a phosphorus oxyacid wherein the molar ratio of potassium relative to phosphorus in the at least one potassium salt of a phosphorus oxyacid is in the range of from 0.6 to 1.4; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW comprising zinc, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane.
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公开(公告)号：US09260402B2
公开(公告)日：2016-02-16
申请号：US14302046
申请日：2014-06-11
Applicant: BASF SE
Inventor： Benoit Blank , Alois Kindler , Peter Bassler , Markus Piepenbrink , Ortmund Lang , Carmen Feldner
IPC: C07D307/46 , C07D307/48 , B01D3/00
CPC classification number: C07D307/46 , B01D3/009 , C07D307/48 , Y02P20/127
Abstract: A process is described for the preparation of 5-hydroxymethylfurfural (HMF), which comprises the following steps: provision or preparation of a starting mixture, comprising one, two or more starting compounds selected from the group consisting of hexoses, oligosaccharides comprising hexose units, and polysaccharides comprising hexose units, one, two or more organic salts with a melting point 200° C. at 1013.25 hPa, optionally additionally one or more catalysts for the conversion of the one starting compound or at least one of the two or more starting compounds to 5-hydroxymethylfurfural (HMF), optionally water, optionally further substances, adjustment of reaction conditions such that an amount of the starting compound or starting compounds converts to HMF.
Abstract translation: 描述了用于制备5-羟甲基糠醛（HMF）的方法，其包括以下步骤：提供或制备起始混合物，其包含一种，两种或更多种选自己糖，包含己糖单元的寡糖， 和多糖，其包含己糖单元，一种，两种或更多种在1013.25hPa的熔点<180℃和沸点> 200℃的有机盐，任选地另外一种或多种用于转化一种起始化合物的催化剂或 两种或更多种起始化合物中的至少一种至5-羟甲基糠醛（HMF），任选的水，任选的其它物质，调节反应条件使得起始化合物或起始化合物的量转化为HMF。
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公开(公告)号：US20140371473A1
公开(公告)日：2014-12-18
申请号：US14302046
申请日：2014-06-11
Applicant: BASF SE
Inventor： Benoit Blank , Alois Kindler , Peter Bassler , Markus Piepenbrink , Ortmund Lang , Carmen Feldner
IPC: C07D307/46 , B01D3/00
CPC classification number: C07D307/46 , B01D3/009 , C07D307/48 , Y02P20/127
Abstract: A process is described for the preparation of 5-hydroxymethylfurfural (HMF), which comprises the following steps: provision or preparation of a starting mixture, comprising one, two or more starting compounds selected from the group consisting of hexoses, oligosaccharides comprising hexose units, and polysaccharides comprising hexose units, one, two or more organic salts with a melting point 200° C. at 1013.25 hPa, optionally additionally one or more catalysts for the conversion of the one starting compound or at least one of the two or more starting compounds to 5-hydroxymethylfurfural (HMF), optionally water, optionally further substances, adjustment of reaction conditions such that an amount of the starting compound or starting compounds converts to HMF.
Abstract translation: 描述了用于制备5-羟甲基糠醛（HMF）的方法，其包括以下步骤：提供或制备起始混合物，其包含一种，两种或更多种选自己糖，包含己糖单元的寡糖， 和多糖，其包含己糖单元，一种，两种或更多种在1013.25hPa的熔点<180℃和沸点> 200℃的有机盐，任选地另外一种或多种用于转化一种起始化合物的催化剂或 两种或更多种起始化合物中的至少一种至5-羟甲基糠醛（HMF），任选的水，任选的其它物质，调节反应条件使得起始化合物或起始化合物的量转化为HMF。
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公开(公告)号：US08835683B2
公开(公告)日：2014-09-16
申请号：US13721296
申请日：2012-12-20
Applicant: BASF SE
Inventor： Daniel Schneider , Klaus-Dieter Mohl , Martin Schäfer , Donata Maria Fries , Joaquim Henrique Teles , Peter Bassler , Stefan Rittinger , Thomas Schaub
Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid, tertiary amine (I) and water is produced by combining tertiary amine (I) and a formic acid source in the presence of water, water and organic decomposition products of the tertiary amine (I) are removed and formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, wherein the stream comprising water and organic decomposition products of the tertiary amine (I) which have been separated off is separated into two liquid phases, the upper liquid phase is removed and the lower, water-comprising liquid phase is recirculated to the formic acid source.
Abstract translation: 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中包含甲酸，叔胺（I）和水的液体流通过将叔胺（I）和甲酸 在水，水和叔胺（I）的有机分解产物存在下，酸源，在蒸馏装置中从所得液流中蒸馏除去甲酸，其中包含水和有机分解产物的流 已经分离出的叔胺（I）分离成两个液相，去除上部液相，将含较低水的液相再循环至甲酸源。
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