PROCESS FOR THE ELECTROCHEMICAL PURIFICATION OF ALUMINIUM
    1.
    发明申请
    PROCESS FOR THE ELECTROCHEMICAL PURIFICATION OF ALUMINIUM 审中-公开
    方法电化学清洁铝的

    公开(公告)号:WO2009007440A3

    公开(公告)日:2009-08-27

    申请号:PCT/EP2008059053

    申请日:2008-07-11

    CPC classification number: C25C3/24 C25C3/06

    Abstract: The present invention relates to a process for the electrochemical purification of aluminium, which comprises the steps (a) provision of an electrolysis apparatus having at least one anode and at least one cathode in an electrolysis space, where the at least one anode and the at least one cathode are connected by an electrolyte and the electrolyte is present in the form of an electrolyte stream; (b) oxidation at the at least one anode which contains aluminium and at least one of the additional metals antimony, lead, iron, bismuth, tin, zinc or copper, where aluminium and the at least one additional metal go at least partly into the electrolyte in the form of their ions; (c) discharge of part of the electrolyte stream from the electrolysis space, where the substream contains at least part of the ions of aluminium and of the at least one additional metal ion; (d) removal of at least part of the at least one additional metal ion from the substream; (e) introduction of the substream which has been depleted in additional metal ions in step (d) into the electrolysis space and (f) deposition of the aluminium from the substream fed in in step (e) on the at least one cathode, where the electric current density at the at least one cathode is at least 50 A/m2.

    Abstract translation: 本发明涉及一种用于铝的电化学清洗力,包括以下步骤:(a)提供具有至少一个阳极和在电解室中,其中所述至少一个阳极和至少一个阴极通过电解质连接的至少一个阴极,和电解质的电解装置 是在电解质流的形式; (B)在含有铝的至少一个阳极和外来金属锑,铅,铁,铋,锡,锌或铜,铝和过渡至少一种异质金属至少部分地进入在它们的离子形式的电解质中的至少一种氧化; (C)排出从电解室中的电解质流的一部分,含有至少部分的铝离子和至少一种异质金属离子的部分流; (D)在部分流的至少一个外来金属离子的耗尽; (E)在步骤(d)馈送到Fremdmetallion耗尽的电流部分,以电解腔和(f)从在步骤(e)中铝的分离提供的至少一个阴极的部分流,所述至少一个阴极的电流密度至少 50 A /平方米施加。

    MATERIAL ESTRUCTURAL POROSO METALO-ORGANICO A BASE DE PIRROLES Y PIRIDINONAS.

    公开(公告)号:ES2334851T3

    公开(公告)日:2010-03-16

    申请号:ES07729020

    申请日:2007-05-11

    Applicant: BASF SE

    Abstract: Proceso para la preparación de un material estructural metal orgánico poroso que contiene al menos un compuesto orgánico enlazado de manera coordinada con al menos un ión metálico, que comprende el paso de oxidación de al menos un ánodo que contiene un metal correspondiente a al menos un ión metálico en un medio de reacción en presencia del, al menos uno, compuesto orgánico, y el, al menos uno, compuesto orgánico es un sistema de anillo que se selecciona del grupo compuesto de **(Ver fórmula)** donde el sistema de anillo no está sustituido tiene uno o varios sustituyente seleccionados independientemente del grupo compuesto de halógeno, alquilo de C1-6, fenilo, NH2, NH(alquilo de C1-6), N(alquilo de C1-6)2, OH, Ofenilo y Oalquilo de C1-6, donde los sustituyentes alquilo de C1-6 y fenilo no están sustituidos o tienen uno o más sustituyentes seleccionados independientemente del grupo que se compone de halógeno, NH2, NH(alquilo de C1-6), N(alquilo de C1-6)2, OH, Ofenilo y Oalquilo de C1-6 y donde el metal es cinc.

    PROCESS FOR THE INDUSTRIAL ISOLATION OF PROPENE

    公开(公告)号:CA2728314A1

    公开(公告)日:2010-01-28

    申请号:CA2728314

    申请日:2009-07-17

    Applicant: BASF SE

    Abstract: The present invention relates to a method for technical extraction of propene from a gas stream containing at least propene and propane, the step comprising bringing the gas stream into contact with an adsorbent material comprising a porous metal-organic structural material containing at least one at least bidentate organic compound that is coordinatively bonded to at least one metal ion, wherein the adsorbent material becomes loaded up with propane and the gas stream thereby exhibits an elevated propene content, wherein the at least bidentate organic component is an imidazolate that is unsubstituted or that contains one or more substituents independently selected from the group consisting of halogen, C1-6 alkyl, phenyl, NH2, NH(C1-6 alkyl), N(C1-6 alkyl)2, OH, O-phenyl and O-C1-6 alkyl. The present invention also relates to the use of such a porous metal-organic structural material for technical extraction of propene from a gas stream containing at least propene and propane by way of propane depletion of the gas stream.

    5.
    发明专利
    未知

    公开(公告)号:DE502007001988D1

    公开(公告)日:2009-12-24

    申请号:DE502007001988

    申请日:2007-05-11

    Applicant: BASF SE

    Abstract: Processes comprising: (i) providing an anode comprising zinc; and (ii) oxidizing the anode in a reaction medium in the presence of at least one organic compound to form a porous metal organic framework comprising the least one organic compound coordinated to at least one zinc ion; wherein the at least one organic compound comprises a ring system selected from the group consisting of compounds corresponding to the following structures wherein the ring system optionally bears one or more substituents selected independently from the group consisting of halogens, C1-6-alkyls, phenyl, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls, and wherein each C1-6-alkyl and phenyl substituent may independently and optionally bear one or more substituents selected independently from the group consisting of halogens, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls.

    6.
    发明专利
    未知

    公开(公告)号:AT448334T

    公开(公告)日:2009-11-15

    申请号:AT07729020

    申请日:2007-05-11

    Applicant: BASF SE

    Abstract: Processes comprising: (i) providing an anode comprising zinc; and (ii) oxidizing the anode in a reaction medium in the presence of at least one organic compound to form a porous metal organic framework comprising the least one organic compound coordinated to at least one zinc ion; wherein the at least one organic compound comprises a ring system selected from the group consisting of compounds corresponding to the following structures wherein the ring system optionally bears one or more substituents selected independently from the group consisting of halogens, C1-6-alkyls, phenyl, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls, and wherein each C1-6-alkyl and phenyl substituent may independently and optionally bear one or more substituents selected independently from the group consisting of halogens, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls.

    PROCESS FOR THE SEPARATION OF UNBRANCHED HYDROCARBONS FROM THEIR BRANCHED ISOMERS

    公开(公告)号:CA2693761A1

    公开(公告)日:2009-01-15

    申请号:CA2693761

    申请日:2008-06-30

    Applicant: BASF SE

    Abstract: The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of - contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.

    PROCEDIMIENTO PARA LA OBTENCION DE MATERIALES ESTRUCTURANTES ORGANOMETALICOS.

    公开(公告)号:ES2333915T3

    公开(公告)日:2010-03-02

    申请号:ES07729006

    申请日:2007-05-11

    Applicant: BASF SE

    Abstract: Procedimiento para la obtención de un material estructurante organometálico, poroso, que contiene, al menos, dos compuestos orgánicos, enlazados por coordinación, sobre, al menos, un ión metálico, que comprende las etapas de (a) la oxidación de, al menos, un ánodo, que contiene el metal, que corresponde al ión metálico, al menos único, en un medio de reacción en presencia de, al menos, un primer compuesto orgánico, siendo el primer compuesto orgánico un hidrocarburo saturado o no saturado, monocíclico, bicíclico o policíclico, en caso dado substituido, en el cual están reemplazados, al menos, dos átomos de carbono del anillo por heteroátomos elegidos entre el grupo constituido por N, O y S, con la formación de un producto intermedio de la reacción, que contiene el ión metálico, al menos único, y el primer compuesto orgánico; y (b) la reacción del producto intermedio de la reacción, a una temperatura predeterminada, con, al menos, un segundo compuesto orgánico, que se enlaza por coordinación sobre el ión metálico, al menos único, derivándose el segundo compuesto orgánico de un ácido dicarboxílico, tricarboxílico o tetracarboxílico.

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