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1.
公开(公告)号:WO2009007440A3
公开(公告)日:2009-08-27
申请号:PCT/EP2008059053
申请日:2008-07-11
Applicant: BASF SE , MAASE MATTHIAS , HUBER GUENTHER , RICHTER INGO , MALKOWSKY ITAMAR , FISCHER ANDREAS
Inventor: MAASE MATTHIAS , HUBER GUENTHER , RICHTER INGO , MALKOWSKY ITAMAR , FISCHER ANDREAS
Abstract: The present invention relates to a process for the electrochemical purification of aluminium, which comprises the steps (a) provision of an electrolysis apparatus having at least one anode and at least one cathode in an electrolysis space, where the at least one anode and the at least one cathode are connected by an electrolyte and the electrolyte is present in the form of an electrolyte stream; (b) oxidation at the at least one anode which contains aluminium and at least one of the additional metals antimony, lead, iron, bismuth, tin, zinc or copper, where aluminium and the at least one additional metal go at least partly into the electrolyte in the form of their ions; (c) discharge of part of the electrolyte stream from the electrolysis space, where the substream contains at least part of the ions of aluminium and of the at least one additional metal ion; (d) removal of at least part of the at least one additional metal ion from the substream; (e) introduction of the substream which has been depleted in additional metal ions in step (d) into the electrolysis space and (f) deposition of the aluminium from the substream fed in in step (e) on the at least one cathode, where the electric current density at the at least one cathode is at least 50 A/m2.
Abstract translation: 本发明涉及一种用于铝的电化学清洗力,包括以下步骤:(a)提供具有至少一个阳极和在电解室中,其中所述至少一个阳极和至少一个阴极通过电解质连接的至少一个阴极,和电解质的电解装置 是在电解质流的形式; (B)在含有铝的至少一个阳极和外来金属锑,铅,铁,铋,锡,锌或铜,铝和过渡至少一种异质金属至少部分地进入在它们的离子形式的电解质中的至少一种氧化; (C)排出从电解室中的电解质流的一部分,含有至少部分的铝离子和至少一种异质金属离子的部分流; (D)在部分流的至少一个外来金属离子的耗尽; (E)在步骤(d)馈送到Fremdmetallion耗尽的电流部分,以电解腔和(f)从在步骤(e)中铝的分离提供的至少一个阴极的部分流,所述至少一个阴极的电流密度至少 50 A /平方米施加。
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2.
公开(公告)号:WO2010003903A3
公开(公告)日:2010-07-15
申请号:PCT/EP2009058425
申请日:2009-07-03
Applicant: BASF SE , RICHTER INGO , KIENER CHRISTOPH , MALKOWSKY ITAMAR MICHAEL , ACHMANN SABINE , HAGEN GUNTHER , HAEMMERLE MARTIN , MOOS RALF
Inventor: RICHTER INGO , KIENER CHRISTOPH , MALKOWSKY ITAMAR MICHAEL , ACHMANN SABINE , HAGEN GUNTHER , HAEMMERLE MARTIN , MOOS RALF
IPC: C10G25/00
CPC classification number: C10G25/003
Abstract: The present invention relates to a method for removing compounds containing sulfur from fuels, characterized in that a fuel containing sulfur is brought into contact with a copper 1,3,5-benzenetricarboxylic acid MOF.
Abstract translation: 本发明涉及从燃料中除去含硫化合物的方法,其特征在于使含硫燃料与铜-1,3,5-苯三甲酸MOF接触。
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公开(公告)号:ES2334851T3
公开(公告)日:2010-03-16
申请号:ES07729020
申请日:2007-05-11
Applicant: BASF SE
Inventor: RICHTER INGO , SCHUBERT MARKUS , MULLER ULRICH
IPC: C25B3/13 , C25B3/23 , C07D233/54 , C07D235/22
Abstract: Proceso para la preparación de un material estructural metal orgánico poroso que contiene al menos un compuesto orgánico enlazado de manera coordinada con al menos un ión metálico, que comprende el paso de oxidación de al menos un ánodo que contiene un metal correspondiente a al menos un ión metálico en un medio de reacción en presencia del, al menos uno, compuesto orgánico, y el, al menos uno, compuesto orgánico es un sistema de anillo que se selecciona del grupo compuesto de **(Ver fórmula)** donde el sistema de anillo no está sustituido tiene uno o varios sustituyente seleccionados independientemente del grupo compuesto de halógeno, alquilo de C1-6, fenilo, NH2, NH(alquilo de C1-6), N(alquilo de C1-6)2, OH, Ofenilo y Oalquilo de C1-6, donde los sustituyentes alquilo de C1-6 y fenilo no están sustituidos o tienen uno o más sustituyentes seleccionados independientemente del grupo que se compone de halógeno, NH2, NH(alquilo de C1-6), N(alquilo de C1-6)2, OH, Ofenilo y Oalquilo de C1-6 y donde el metal es cinc.
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公开(公告)号:CA2728314A1
公开(公告)日:2010-01-28
申请号:CA2728314
申请日:2009-07-17
Applicant: BASF SE
Inventor: SCHUBERT MARKUS , RICHTER INGO , MUELLER ULRICH , POPLOW FRANK , DOLAN WILLIAM , KIENER CHRISTOPH
IPC: C07C7/12
Abstract: The present invention relates to a method for technical extraction of propene from a gas stream containing at least propene and propane, the step comprising bringing the gas stream into contact with an adsorbent material comprising a porous metal-organic structural material containing at least one at least bidentate organic compound that is coordinatively bonded to at least one metal ion, wherein the adsorbent material becomes loaded up with propane and the gas stream thereby exhibits an elevated propene content, wherein the at least bidentate organic component is an imidazolate that is unsubstituted or that contains one or more substituents independently selected from the group consisting of halogen, C1-6 alkyl, phenyl, NH2, NH(C1-6 alkyl), N(C1-6 alkyl)2, OH, O-phenyl and O-C1-6 alkyl. The present invention also relates to the use of such a porous metal-organic structural material for technical extraction of propene from a gas stream containing at least propene and propane by way of propane depletion of the gas stream.
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公开(公告)号:DE502007001988D1
公开(公告)日:2009-12-24
申请号:DE502007001988
申请日:2007-05-11
Applicant: BASF SE
Inventor: RICHTER INGO , SCHUBERT MARKUS , MUELLER ULRICH
IPC: C25B3/13 , C25B3/23 , C07D233/54 , C07D235/22
Abstract: Processes comprising: (i) providing an anode comprising zinc; and (ii) oxidizing the anode in a reaction medium in the presence of at least one organic compound to form a porous metal organic framework comprising the least one organic compound coordinated to at least one zinc ion; wherein the at least one organic compound comprises a ring system selected from the group consisting of compounds corresponding to the following structures wherein the ring system optionally bears one or more substituents selected independently from the group consisting of halogens, C1-6-alkyls, phenyl, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls, and wherein each C1-6-alkyl and phenyl substituent may independently and optionally bear one or more substituents selected independently from the group consisting of halogens, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls.
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公开(公告)号:AT448334T
公开(公告)日:2009-11-15
申请号:AT07729020
申请日:2007-05-11
Applicant: BASF SE
Inventor: RICHTER INGO , SCHUBERT MARKUS , MUELLER ULRICH
IPC: C25B3/13 , C25B3/23 , C07D233/54 , C07D235/22
Abstract: Processes comprising: (i) providing an anode comprising zinc; and (ii) oxidizing the anode in a reaction medium in the presence of at least one organic compound to form a porous metal organic framework comprising the least one organic compound coordinated to at least one zinc ion; wherein the at least one organic compound comprises a ring system selected from the group consisting of compounds corresponding to the following structures wherein the ring system optionally bears one or more substituents selected independently from the group consisting of halogens, C1-6-alkyls, phenyl, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls, and wherein each C1-6-alkyl and phenyl substituent may independently and optionally bear one or more substituents selected independently from the group consisting of halogens, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls.
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公开(公告)号:ZA201004814B
公开(公告)日:2011-09-28
申请号:ZA201004814
申请日:2010-07-08
Applicant: BASF SE
Inventor: SIEMER MICHAEL , MAASE MATTHIAS , RICHTER INGO
IPC: C07D20060101
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公开(公告)号:CA2693761A1
公开(公告)日:2009-01-15
申请号:CA2693761
申请日:2008-06-30
Applicant: BASF SE
Inventor: SCHUBERT MARKUS , MULLER ULRICH , KIENER CHRISTOPH , RICHTER INGO , WILLIAM DOLAN , POPLOW FRANK
Abstract: The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of - contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.
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公开(公告)号:ES2333915T3
公开(公告)日:2010-03-02
申请号:ES07729006
申请日:2007-05-11
Applicant: BASF SE
Inventor: PUTTER HERMANN , SCHUBERT MARKUS , RICHTER INGO , MULLER ULRICH , TRUKHAN NATALIA
IPC: C25B3/13
Abstract: Procedimiento para la obtención de un material estructurante organometálico, poroso, que contiene, al menos, dos compuestos orgánicos, enlazados por coordinación, sobre, al menos, un ión metálico, que comprende las etapas de (a) la oxidación de, al menos, un ánodo, que contiene el metal, que corresponde al ión metálico, al menos único, en un medio de reacción en presencia de, al menos, un primer compuesto orgánico, siendo el primer compuesto orgánico un hidrocarburo saturado o no saturado, monocíclico, bicíclico o policíclico, en caso dado substituido, en el cual están reemplazados, al menos, dos átomos de carbono del anillo por heteroátomos elegidos entre el grupo constituido por N, O y S, con la formación de un producto intermedio de la reacción, que contiene el ión metálico, al menos único, y el primer compuesto orgánico; y (b) la reacción del producto intermedio de la reacción, a una temperatura predeterminada, con, al menos, un segundo compuesto orgánico, que se enlaza por coordinación sobre el ión metálico, al menos único, derivándose el segundo compuesto orgánico de un ácido dicarboxílico, tricarboxílico o tetracarboxílico.
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公开(公告)号:DE102009027094A1
公开(公告)日:2009-12-31
申请号:DE102009027094
申请日:2009-06-23
Applicant: BASF SE
Inventor: MALKOWSKY ITAMAR MICHAEL , RICHTER INGO , FISCHER ANDREAS , HUBER GUENTHER
Abstract: Method for the cementation of nickel and/or cobalt on copper comprises contacting an object having a copper surface with a liquid phase containing nickel and/or cobalt ions and an ionic liquid containing anions and cations and depositing nickel and/or cobalt on the copper surface in a currentless manner.
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