公开(公告)号：EP3186226A4

公开(公告)日：2018-05-23

申请号：EP15835348

申请日：2015-08-13

Applicant: BASF SE

Inventor： KUNIMOTO KAZUHIKO ,  SAMESHIMA KAORI ,  KURA HISATOSHI ,  MATSUOKA YUKI

IPC: C07C327/58 ,  C07D209/48 ,  C08F20/10 ,  C09D133/10 ,  G03F7/00 ,  G03F7/031 ,  G03F7/40

CPC classification number: C07C327/58 ,  C07C2601/20 ,  C07D209/48 ,  G02B1/14 ,  G02B5/201 ,  G02B5/223 ,  G02F1/133516 ,  G02F1/1339 ,  G02F2001/133519 ,  G03F7/0007 ,  G03F7/031 ,  G03F7/162 ,  G03F7/168 ,  G03F7/2002 ,  G03F7/38 ,  G03F7/40

Abstract: Oxime sulfonate compounds of the formula (I), wherein R 1 is O(CO)R 4, COOR 5 or CONR 6R 7; n is 1 or 2; R 2 for example is C 1-C 8alkyl, C 3-C 6cycloalkyl or benzyl; R 3 is for example C 1-C 8alkyl, C 3-C 6cycloalkyl, C 1-C 8haloalkyl, C 2-C 8alkenyl, benzyl, phenyl or naphthyl, which optionally are substituted; R 4 is for example C 1-C 8alkyl, C 3-C 6cycloalkyl, C 1-C 8haloalkyl, C 2-C 8alkenyl, benzyl, phenyl or naphthyl, which optionally are substituted; R 5 is for example C 3-C 20alkyl, C 3-C 14cycloalkyl, C 2-C 8alkenyl, C 1-C 12alkyl which is substituted for example by one or more halogen; or R 5 is phenyl or naphthyl, which are unsubstituted; R 6 and R 7 each independently of one another for example are hydrogen, C 1-C 12alkyl, C 1-C 4haloalkyl, phenyl-C 1-C 4alkyl, C 2-C 8alkenyl or C 3-C 6cycloalkyl, phenyl or naphthyl; or R 6 and R 7, together with the N-atom to which they are attached, form a 5- or 6-membered ring; are suitable as thermal radical initiators.

公开(公告)号：EP3019473A4

公开(公告)日：2016-12-21

申请号：EP14822764

申请日：2014-06-30

Applicant: BASF SE

Inventor： TANAKA KEITA ,  KURA HISATOSHI ,  KUNIMOTO KAZUHIKO ,  SAMESHIMA KAORI

IPC: C07D409/14 ,  C07D209/86 ,  G03F7/00

CPC classification number: G03F7/031 ,  C07D209/86 ,  C07D409/14 ,  C08F22/20 ,  G02B5/201 ,  G03F7/0007 ,  G03F7/027 ,  G03F7/032 ,  G03F7/033 ,  G03F7/0388 ,  G03F7/20 ,  G03F7/322

Abstract: Compounds of the formula (I) n, wherein Q is a direct bond or an n-valent linking group; n is an integer 2, 3, or 4; Z is for example C1-C20alkylene, C2-C20alkenylene,C5-C8 cycloalkylene or C5-C8 cycloalkenylene; Y is for example C6-C20aryl or C3-C20heteroaryl; R1 is for example hydrogen, C2-C5alkenyl, C3-C8cycloalkyl, C1-C12alkyl, phenyl, naphthyl, C3-C20heteroaryl, C1-C8alkoxy, benzyloxy or phenoxy; R2 is for example C1-C20alkyl, C2-C12alkenyl, C4-C8cycloalkenyl, C2-C12alkinyl, C3-C10cycloalkyl, phenyl or naphthyl; R15, R16, R17, R18, R19 and R20 independently of each other for example are hydrogen, halogen, C1-C20alkyl, C6-C20aryl or C4-C20heteroaryl; provided that a compound wherein R15, R16, R17, R18, R19 and R20 are hydrogen, Y is thienyl, R1 is methyl, R2 is ethyl, n is 2, Q is a direct bond and Z is n-propylene and a compound wherein R15, R16, R17, R18, R19 and R20 are hydrogen, Y is thienyl, R1 is methyl, R2 is ethyl, n is 2, Q as an n-valent linking group is methylene and Z is methylene are excluded; are reactive photoinitiators in particular in electronic applications.

Abstract translation: 式（I）n的化合物，其中Q是直接键或n价连接基团; n是整数2，3或4; Z是例如C 1 -C 20亚烷基，C 2 -C 20亚烯基，C 5 -C 8亚环烷基或C 5 -C 8环亚烯基; Y为例如C 6 -C 20芳基或C 3 -C 20杂芳基; R1是例如氢，C2-C5链烯基，C3-C8环烷基，C1-C12烷基，苯基，萘基，C3-C20杂芳基，C1-C8烷氧基，苄氧基或苯氧基; R 2是例如C 1 -C 20烷基，C 2 -C 12烯基，C 4 -C 8环烯基，C 2 -C 12炔基，C 3 -C 10环烷基，苯基或萘基; R 15，R 16，R 17，R 18，R 19和R 20彼此独立地为氢，卤素，C 1 -C 20烷基，C 6 -C 20芳基或C 4 -C 20杂芳基; 条件是其中R 15，R 16，R 17，R 18，R 19和R 20为氢，Y为噻吩基，R 1为甲基，R 2为乙基，n为2，Q为直接键，Z为正丙烯的化合物及其中 R15，R16，R17，R18，R19和R20是氢，Y是噻吩基，R1是甲基，R2是乙基，n是2，n价连接基团是亚甲基，Z是亚甲基的Q被排除; 特别是电子应用中的反应性光引发剂。

公开(公告)号：EP3044208A4

公开(公告)日：2017-08-09

申请号：EP14844439

申请日：2014-09-08

Applicant: BASF SE

Inventor： KUNIMOTO KAZUHIKO ,  KURA HISATOSHI ,  YAMAMOTO HIROSHI ,  NAKAGAWA YUMIKO ,  ASAKURA TOSHIKAGE ,  SAMESHIMA KAORI

IPC: G03F7/031 ,  C07C251/60 ,  C07C251/66 ,  C07D209/12 ,  C07D307/56 ,  C07D307/80 ,  C07D307/83 ,  C07D307/86 ,  C07D307/91 ,  C07D307/92 ,  C07D333/56 ,  C07D407/12 ,  C07D409/06 ,  G02B5/20 ,  G02B5/22 ,  G03F7/00 ,  G03F7/20 ,  G03F7/32

CPC classification number: C07D409/06 ,  C07D209/12 ,  C07D307/56 ,  C07D307/80 ,  C07D307/83 ,  C07D307/86 ,  C07D307/91 ,  C07D307/92 ,  C07D333/56 ,  C07D407/12 ,  G02B5/201 ,  G02B5/223 ,  G03F7/0007 ,  G03F7/031 ,  G03F7/20 ,  G03F7/32