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公开(公告)号:DE502004007960D1
公开(公告)日:2008-10-09
申请号:DE502004007960
申请日:2004-12-29
Applicant: BASF SE
Inventor: RATH HANS PETER , PERNER THOMAS , SCHAUSS ECKARD
IPC: C08F8/26 , C08F4/14 , C08F10/10 , C08F110/10
Abstract: A process is described for preparing polyisobutene having a low halogen content, in which isobutene is polymerized in the presence of a catalyst which comprises a halogenated Lewis acid, the catalyst is removed and/or deactivated, and the resulting polyisobutene is contacted with a zeolite of an average pore size of from 5 to 15 Å.
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公开(公告)号:MX2010005449A
公开(公告)日:2010-06-01
申请号:MX2010005449
申请日:2008-12-16
Applicant: BASF SE
Inventor: LOEFFLER ACHIM , MECKELNBURG DIRK , SCHOPOHL MATTHIAS , SCHAUSS ECKARD
Abstract: La invención proporciona un proceso para preparar alcoholes de poliéter añadiendo óxidos de alquileno en substancias iniciadoras H-funcionales, de las cuales cuando menos una es sólida a temperatura ambiente en un recipiente de reacción, alimentando los componentes iniciadores continuamente al recipiente de reacción, que comprende preparar una pasta de la substancia iniciadora sólida y alimentar esta pasta continuamente al recipiente de reacción.
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公开(公告)号:ES2463116T3
公开(公告)日:2014-05-27
申请号:ES10736725
申请日:2010-07-27
Applicant: BASF SE
Inventor: SCHOPOHL MATTHIAS , OSTROWSKI THOMAS , MECKELNBURG DIRK , JOVANOVIC RENATA , LÖFFLER ACHIM , PALLASCH HANS-JÜRGEN , FRIESE THORSTEN , SCHAUSS ECKARD , SZESCHKUS SUSANNE , CHILEKAR VINIT , SCHWARZ HANS VOLKMAR
IPC: C08G65/30
Abstract: Procedimiento para la preparación de polioléteres que comprende los siguientes pasos: a) hacer reaccionar al menos un compuesto iniciador con al menos un óxido de alquileno y un catalizador de amina o DMC para obtener un polioléter bruto y b) eliminar subproductos de bajo peso molecular del polioléter bruto del paso a), caracterizado porque el polioléter bruto en el paso b) se trata en una columna con elementos incorporados con un gas de arrastre, realizándose el procedimiento en continuo.
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公开(公告)号:AT444314T
公开(公告)日:2009-10-15
申请号:AT06762534
申请日:2006-07-11
Applicant: BASF SE
Inventor: BODE ANDREAS , RACHWALSKY UWE , SAUER FRIEDRICH , SCHAUSS ECKARD , VOLLAND MARCO-CHRISTIAN , WETTLING THOMAS
Abstract: The present invention relates to a process for preparing polyisobutenes by polymerizing isobutene in the presence of a Lewis acid catalyst in liquid organic phase, terminating the reaction by admixing the organic phase with an aqueous terminator in a dynamic mixer which has a rotationally symmetric mixing chamber formed from one circumferential wall and two end walls, and a mixing rotor driven such that it rotates therein, the organic phase being introduced through a first inlet orifice provided in the circumferential wall and the aqueous terminator via a second inlet orifice provided in the circumferential wall, and removing a finely dispersed mixture of the organic phase and of the terminator through an outlet orifice provided in the circumferential wall and feeding it to a phase separation. The process serves to prepare high-reactivity polyisobutenes and/or polyisobutenes with narrow molecular weight distribution.
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公开(公告)号:DE102008058448A1
公开(公告)日:2009-06-25
申请号:DE102008058448
申请日:2008-11-21
Applicant: BASF SE
Inventor: CSIHONY SZILARD , HILDEBRANDT NICOLE , SCHAUSS ECKARD
Abstract: New polyisobutyl derivatives (I) consist of a polyisobutyl moiety bonded to the heteroatom of a cyclic ammonio or acyclic or cyclic phosphonio, oxonio, sulfonio or selenio group. Polyisobutyl derivatives of formula PIB-X +>. Y ->(I) are new. PIB : polyisobutyl; X +>N-bonded 5-7 membered saturated, partially saturated or aromatic heterocyclic ammonio group (optionally containing additional heteroatoms and optionally substituted (os)), -N +>R 1>R 2>R 3>, -P +>R 4>R 5>R 6>, -O +>R 7>R 8>, -S +>R 9>R 1> 0>or -Se +>R 1> 1>R 1> 2>; R 1>- R 1> 2>H, alkyl, -A-OA, hydroxyalkyl, alkenyl, alkynyl, cycloalkyl, aryl, -A-aryl or Het (where hydrocarbyl or heterocyclyl moieties are os); or PR 4>R 5>, OR 7>R 8>, SR 9>R 1> 0>or SeR 1> 1>R 1> 1>heterocycle (os and optionally containing additional heteroatoms); Y ->halide anion or Lewis acid-Lewis base adduct of formula (M aZ b) ->; M : B, Al, Ti, V, Fe, Zn, Cu, Sn, Ga, Zr, Mo, Nb, Sb or In; Z : F, Cl oder Br; a : 1-3; b : 2-10; An independent claim is included for the production of homo- or copolymers of cationically polymerizable olefinically unsaturated monomer(s) (II) by polymerization in presence of (I), provided that in the case of (I; Y ->= halide or Lewis acid-Lewis base adduct in which a = 1) the polymerization is carried out in presence of a Lewis acid.
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公开(公告)号:PT2459618E
公开(公告)日:2014-05-19
申请号:PT01073672
申请日:2010-07-27
Applicant: BASF SE
Inventor: SCHAUSS ECKARD , OSTROWSKI THOMAS , LÖFFLER ACHIM , JOVANOVIC RENATA , PALLASCH HANS-JÜRGEN , SCHOPOHL MATTHIAS , MECKELNBURG DIRK , FRIESE THORSTEN , SZESCHKUS SUSANNE , CHILEKAR VINIT , SCHWARZ HANS VOLKMAR
IPC: C08G65/30
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公开(公告)号:MX2012001143A
公开(公告)日:2012-02-22
申请号:MX2012001143
申请日:2010-07-27
Applicant: BASF SE
Inventor: SCHWARZ HANS VOLKMAR , OSTROWSKI THOMAS , PALLASCH HANS-JUERGEN , FRIESE THORSTEN , LOEFFLER ACHIM , MECKELNBURG DIRK , JOVANOVIC RENATA , SCHOPOHL MATTHIAS , SCHAUSS ECKARD , SZESCHKUS SUSANNE , CHILEKAR VINIT
IPC: C08G65/30
Abstract: Método para producir polieteroles, que comprenden los siguientes pasos: a) hacer reaccionar por lo menos un compuesto de partida con por lo menos un óxido de alquileno y un catalizador para dar un polieterol crudo, y b) remover subproductos de bajo peso molecular del polieterol crudo del paso a), caracterizado porque el polieterol crudo se trata con un gas de separación en una columna que tiene partes internas.
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公开(公告)号:DE502006004991D1
公开(公告)日:2009-11-12
申请号:DE502006004991
申请日:2006-07-11
Applicant: BASF SE
Inventor: BODE ANDREAS , RACHWALSKY UWE , SAUER FRIEDRICH , SCHAUSS ECKARD , VOLLAND MARCO-CHRISTIAN , WETTLING THOMAS
Abstract: The present invention relates to a process for preparing polyisobutenes by polymerizing isobutene in the presence of a Lewis acid catalyst in liquid organic phase, terminating the reaction by admixing the organic phase with an aqueous terminator in a dynamic mixer which has a rotationally symmetric mixing chamber formed from one circumferential wall and two end walls, and a mixing rotor driven such that it rotates therein, the organic phase being introduced through a first inlet orifice provided in the circumferential wall and the aqueous terminator via a second inlet orifice provided in the circumferential wall, and removing a finely dispersed mixture of the organic phase and of the terminator through an outlet orifice provided in the circumferential wall and feeding it to a phase separation. The process serves to prepare high-reactivity polyisobutenes and/or polyisobutenes with narrow molecular weight distribution.
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公开(公告)号:AT406391T
公开(公告)日:2008-09-15
申请号:AT04804379
申请日:2004-12-29
Applicant: BASF SE
Inventor: RATH HANS , PERNER THOMAS , SCHAUSS ECKARD
IPC: C08F8/26 , C08F4/14 , C08F10/10 , C08F110/10
Abstract: A process is described for preparing polyisobutene having a low halogen content, in which isobutene is polymerized in the presence of a catalyst which comprises a halogenated Lewis acid, the catalyst is removed and/or deactivated, and the resulting polyisobutene is contacted with a zeolite of an average pore size of from 5 to 15 Å.
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