Abstract:
The invention relates to a method for producing one or more complexing agents, selected from methylglycinediacetic acid, glutamic acid diacetic acid, and salts thereof, by catalytically dehydrogenating N,N-bis-(2-hydroxyethyl)-alanine and/or N,N-bis-(2-hydroxyethyl)-glutamic acid or salts thereof in the presence of alkali hydroxide, a catalyst containing copper and zirconium dioxide being used, the activation of which is a reduction, characterized in that the precursor of the catalyst in question has a degree of crystallization K defined as (I) in the range of 0 to 50%.
Abstract:
Procedimiento para la obtención de aminocarboxilatos, en el que en una primera etapa se etoxila una amina auna temperatura de reacción en el intervalo de 30 a 100ºC para dar una alcanolamina, y la alcanolamina formada deeste modo se deshidrogena en una segunda etapa por oxidación para dar un aminocarboxilato.
Abstract:
La presente invención se refiere a un procedimiento para preparar aminocarboxilatos, procedentes de aminas, utilizando una secuencia de reacción compuesta de etoxilación a aminoalcoholes y deshidrogenación oxidativa subsiguiente a los aminocarboxilatos correspondientes, especialmente las sales de metal alcalino o metal alcalinotérreo de los agentes formadores de complejo MGDA (ácido metilglicinodiacético), EDTA (ácido etilendiaminotetraacéti co) y GLDA (ácido glutámico-ácido diacético) o los ácidos libres de los mismos.
Abstract:
16030 16030 160304 44 4 56 5656 56 Process for activating a catalyst The present invention relates to a novel process for activating a fixed c atalyst bed, to a 5 process for providing a reactor comprising a fixed catalyst bed that h as been activated in this way, and to the use of the activated fixed catalyst bed and of r eactors comprising such an activated fixed catalyst bed for hydrogenation reactions.
Abstract:
A process for the preparation of a copper/zirconia-catalyst for the hydrogenation of ethyl acetate to ethanol comprising the steps: a) preparation of an aqueous solution of water-soluble copper and zirconium salts; b) precipitation of a solid from this solution by addition of a basic precipitating agent, and optionally aging of the solid; c) separation and washing of the solid; d) drying of the solid; e) calcination of the solid; characterized in that the precipitation of the solid in step b) is carried out at a pH in the range of from 7 to 7,5, and the basic precipitation agent contains a mixture of Na2CO3 and NaOH.
Abstract:
The present invention relates to a method for producing aminocarboxylates starting from amines using a reaction sequence of ethoxylation to form amino alcohols and subsequent oxidative dehydrogenation to form the corresponding aminocarboxylates, in particular the alkali or alkaline earth salts of the complexing agents MGDA (methylglycinediacetic acid), EDTA (ethylenediaminetetraacetic acid) and GLDA (glutamic acid diacetic acid) or the free acids thereof.
Abstract:
10 Abstract METHOD FOR PRODUCING AMINOCARBOXYLATES LOW IN BY-PRODUCTThe present ineentMn relateg to a pfocesti for pa:paring eminocarboxy(ates, proceeding from amines, by cdapbying g rdgcton sag:fence corn:used of ethoxylonon5 to amino afoot:ors gad subseouent oxidative dertytimemalort to the corm:Tonal no ardhocatboxylatos, especialy the aka:it rnatat or elaiine earth metal said., of the conveying agents MGDA frnothylgtyoulaitaraffie aoid), EF). TA (ethyienediamlnetetra atel:e acid) end GI_DA (glutamic add diacottc add) Dr the nee adds hereof. No suitable figure
Abstract:
Ein Verfahren zur Herstellung eines Trägerkatalysators, wobei wenigstens drei Schritte der folgenden Verfahrensschrittei) Imprägnierung eines Katalysatorträgers,ii) Trocknung des erhaltenen Katalysatorvorläufers,iii) Nachbehandlung des getrockneten Katalysatorvorläufers durch wenigstens einen der Schritteiiia) Calcinierung und/oderiiib) Reduktion mit einem Reduktionsmittel in einem spezifischen Freifallmischer-Reaktor durchgeführt werden; und ein Trägerkatalysator, der mit dem Verfahren hergestellt wird.
Abstract:
160303 160303 160303 81 8181 81 Method for providing a fixed catalyst bed containing a doped structured sh aped catalyst body 5 The present invention relates to a novel process for providing a fixed catal yst bed com- prising doped structured shaped catalyst bodies, to a reactor comprising such a f ixed catalyst bed installed in a fixed location, and to the use of the fixed catalyst beds and reactors thus obtained for hydrogenation reactions.