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    PROCESS FOR PRODUCING REFORMING CATALYST AND REFORMING OF METHANE
    5.
    发明专利
    PROCESS FOR PRODUCING REFORMING CATALYST AND REFORMING OF METHANE 未知

    公开(公告)号：ZA201404090B

    公开(公告)日：2017-05-31

    申请号：ZA201404090

    申请日：2014-06-05

    Applicant: BASF SE

    Inventor： WASSERSCHAFF GUIDO ,  STRASSER ANDREAS ,  SCHWAB EKKEHARD ,  SCHUNK STEPHAN ,  ROUSSIÈRE THOMAS ,  MILANOV ANDRIAN

    Abstract: A catalyst for the reforming of hydrocarbon-comprising compounds with CO2, water and/or hydrogen, a process for producing the same, and a process using the same for the reforming of the hydrocarbon-comprising compounds are provided. The production of the catalyst is based on contacting, intimately mixing and thermal treating of a hydrotalcite-comprising starting material with a fusible metal salt, which more preferably comprises nickel nitrate hexahydrate, to result in the metal salt melt. After molding and shaping, the compounds are subjected to high-temperature calcination step. In addition, the process using the catalyst for the reforming of the hydrocarbon-comprising compounds is carried out in a temperature range from 500 to 1100 °C at a pressure in the range from 2 to 70 bar. The catalyst is distinguished from the prior art by physicochemical properties.

    HEXAALUMINATE-COMPRISING CATALYST FOR REFORMING OF HYDROCARBONS AND REFORMING PROCESS
    9.
    发明专利
    HEXAALUMINATE-COMPRISING CATALYST FOR REFORMING OF HYDROCARBONS AND REFORMING PROCESS 未知

    公开(公告)号：ZA201406561B

    公开(公告)日：2016-08-31

    申请号：ZA201406561

    申请日：2014-09-08

    Applicant: BASF SE

    Inventor： WASSERSCHAFF GUIDO ,  STRASSER ANDREAS ,  SCHUNK STEPHAN ,  ROUSSIÈRE THOMAS ,  MILANOV ANDRIAN

    IPC: C01B32/40

    Abstract: The present invention relates to a hexaaluminate-containing catalyst, which comprises a hexaaluminate-containing phase that includes cobalt and at least one additional element from the group La, Ba, Sr. The Co content of the hexaaluminate-containing catalyst is in the range of 2-15 mol%, preferably 3-10 mol% and further preferably in the range of 4-8 mol%, the content of the at least one additional element from the group La, Ba, Sr is in the range of 2-25 mol%, preferably 3-15 mol%, further preferably 4-10 mol% and the content of Al is in the range of 70-90 mol%. In addition to the hexaaluminate-containing phase, the catalyst can include a 0-50 wt% oxide secondary phase, the portion of oxide secondary phase preferably in the range of 3-40 wt% and further preferably in the range of 5-30 wt%. The method according to the invention for producing the catalyst is based on initially bringing a source of aluminium oxide, preferably, a boehmite, into contact with cobalt species and at least one element from the group La, Ba, Sr. The moulded and dried material is preferably calcined at a temperature greater than or equal to 800°C. The reforming method for converting hydrocarbons, preferably methane, in the presence of CO2 is characterised in that the catalyst is used at a process temperature greater than 700°C, preferably greater than 800°C and further preferably greater than 900°C, the process pressure being greater than 5 bar, preferably greater than 10 bar and further preferably greater than 15 bar.

    PROCESS FOR PRODUCING METHANATION CATALYST AND PROCESS FOR THE METHANATION OF SYTHESIS GAS
    10.
    发明专利
    PROCESS FOR PRODUCING METHANATION CATALYST AND PROCESS FOR THE METHANATION OF SYTHESIS GAS 未知

    公开(公告)号：CA2854914A1

    公开(公告)日：2013-05-16

    申请号：CA2854914

    申请日：2012-11-07

    Applicant: BASF SE

    Inventor： QUERNER CLAUDIA ,  MILANOV ANDRIAN ,  SCHUNK STEPHAN ,  STRASSER ANDREAS ,  WASSERSCHAFF GUIDO ,  ROUSSIERE THOMAS

    IPC: B01J37/08 ,  B01J23/70 ,  C07C1/04 ,  C07C1/06 ,  C07C1/12

    Abstract: The present invention relates to a process for producing a catalyst for carrying out methanation reactions. The production of the catalyst is based on contacting of a hydrotaicite-comprising starting material with a fusible metal salt. The compounds brought into contact with one another are intimately mixed, thermally treated so that the metal salt fraction melts and subsequently subjected to a low-temperature calcination step and a high-temperature calcination step. The metal salt melt comprises at least one metal selected from the group consisting of K, La, Fe, Co, Ni, Cu and Ce, preferably Ni. The metal salt melt more preferably comprises/contains nickel nitrate hexahydrate. The hydrotaicite-comprising starting material is preferably hydrotaicite or a hydrotalcite-like compound as starting material, and the hydrotaicite-comprising starting material preferably comprises magnesium and aluminum as metal species. The catalyst of the invention is preferably used for carrying out methanation reactions at elevated pressures (from 10 to 50 bar) and elevated temperatures.

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