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    PROCESS FOR PRODUCING REFORMING CATALYST AND REFORMING OF METHANE
    4.
    发明专利
    PROCESS FOR PRODUCING REFORMING CATALYST AND REFORMING OF METHANE 未知

    公开(公告)号：ZA201404090B

    公开(公告)日：2017-05-31

    申请号：ZA201404090

    申请日：2014-06-05

    Applicant: BASF SE

    Inventor： WASSERSCHAFF GUIDO ,  STRASSER ANDREAS ,  SCHWAB EKKEHARD ,  SCHUNK STEPHAN ,  ROUSSIÈRE THOMAS ,  MILANOV ANDRIAN

    Abstract: A catalyst for the reforming of hydrocarbon-comprising compounds with CO2, water and/or hydrogen, a process for producing the same, and a process using the same for the reforming of the hydrocarbon-comprising compounds are provided. The production of the catalyst is based on contacting, intimately mixing and thermal treating of a hydrotalcite-comprising starting material with a fusible metal salt, which more preferably comprises nickel nitrate hexahydrate, to result in the metal salt melt. After molding and shaping, the compounds are subjected to high-temperature calcination step. In addition, the process using the catalyst for the reforming of the hydrocarbon-comprising compounds is carried out in a temperature range from 500 to 1100 °C at a pressure in the range from 2 to 70 bar. The catalyst is distinguished from the prior art by physicochemical properties.

    HIGH-TEMPERATURE SYNTHESIS OF ALUMINATES BY FLAME SPRAY PYROLYSIS
    5.
    发明专利
    HIGH-TEMPERATURE SYNTHESIS OF ALUMINATES BY FLAME SPRAY PYROLYSIS 未知

    公开(公告)号：CA2965415A1

    公开(公告)日：2016-04-28

    申请号：CA2965415

    申请日：2015-10-23

    Applicant: BASF SE

    Inventor： KONIG RENE ,  KOBAN WIELAND ,  MILANOV ANDRIAN ,  SCHWAB EKKEHARD ,  SCHUNK STEPHAN A ,  LIZANDARA CARLOS ,  WASSERSCHAFF GUIDO

    IPC: B01J23/78 ,  B01J23/83 ,  C01B3/40 ,  C01F7/02 ,  C01F17/00

    Abstract: The invention relates to a method for producing aluminates of general formula (I): A1BxAl12-xO19-y, wherein A means at least one element from the group consisting of Sr, Ba, and La, B means at least one element from the group consisting of Mn, Fe Co, Ni, Rh, Cu, and Zn, x means 0.05 to 1.0, and y means a value that is determined by the oxidation states of the other elements, comprising the following steps: (i) providing one or more solutions or suspensions containing precursor compounds of elements A and B and a precursor compound of aluminum in a solvent, (ii) converting the solutions or suspensions or the suspensions into an aerosol, (iii) introducing the aerosol into a directly or indirectly heated pyrolysis zone, (iv) performing the pyrolysis, and (v) separating the formed particles containing hexaaluminate of general formula (I) from the pyrolysis gas.

    HEXAALUMINATE-COMPRISING CATALYST FOR REFORMING OF HYDROCARBONS AND REFORMING PROCESS
    10.
    发明专利
    HEXAALUMINATE-COMPRISING CATALYST FOR REFORMING OF HYDROCARBONS AND REFORMING PROCESS 未知

    公开(公告)号：ZA201406561B

    公开(公告)日：2016-08-31

    申请号：ZA201406561

    申请日：2014-09-08

    Applicant: BASF SE

    Inventor： WASSERSCHAFF GUIDO ,  STRASSER ANDREAS ,  SCHUNK STEPHAN ,  ROUSSIÈRE THOMAS ,  MILANOV ANDRIAN

    IPC: C01B32/40

    Abstract: The present invention relates to a hexaaluminate-containing catalyst, which comprises a hexaaluminate-containing phase that includes cobalt and at least one additional element from the group La, Ba, Sr. The Co content of the hexaaluminate-containing catalyst is in the range of 2-15 mol%, preferably 3-10 mol% and further preferably in the range of 4-8 mol%, the content of the at least one additional element from the group La, Ba, Sr is in the range of 2-25 mol%, preferably 3-15 mol%, further preferably 4-10 mol% and the content of Al is in the range of 70-90 mol%. In addition to the hexaaluminate-containing phase, the catalyst can include a 0-50 wt% oxide secondary phase, the portion of oxide secondary phase preferably in the range of 3-40 wt% and further preferably in the range of 5-30 wt%. The method according to the invention for producing the catalyst is based on initially bringing a source of aluminium oxide, preferably, a boehmite, into contact with cobalt species and at least one element from the group La, Ba, Sr. The moulded and dried material is preferably calcined at a temperature greater than or equal to 800°C. The reforming method for converting hydrocarbons, preferably methane, in the presence of CO2 is characterised in that the catalyst is used at a process temperature greater than 700°C, preferably greater than 800°C and further preferably greater than 900°C, the process pressure being greater than 5 bar, preferably greater than 10 bar and further preferably greater than 15 bar.

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