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公开(公告)号:HUE035346T2
公开(公告)日:2018-05-02
申请号:HUE13196584
申请日:2013-12-11
Applicant: BASF SE
Inventor: WEICKGENANNT ANDREAS , SCHAACK BERND BASTIAN , WUCHER BARBARA , PANCHENKO ALEXANDER , HETTCHE FRANK , BOCK MARTIN , TAN AIK MEAM , DAHMEN KIRSTEN
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公开(公告)号:IN10837DEN2014A
公开(公告)日:2015-09-04
申请号:IN10837DEN2014
申请日:2014-12-18
Applicant: BASF SE
Inventor: BOU CHEDID ROLAND , MELDER JOHANN PETER , DOSTALEK ROMAN , PASTRE JÖRG , TAN AIK MEAM
IPC: C07D295/023
Abstract: Disclosed is a method for producing pyrollidine of formula (I) by reacting 1.4 butandiol (BDO) of formula (II) with ammoniac in the presence of hydrogen and a supported metal containing catalyser characterised in that prior to its reduction with hydrogen the catalytically active mass of the catalyser contains oxygen containing compounds of aluminium copper nickel and cobalt and oxygen containing compounds of tin in the wt.% range of 0.2 to 5.0% calculated as SnO and in that the reaction is performed in the liquid phase at an absolute pressure in the range of 160 to 220 bar at a temperature in the range of 160 to 230C using ammoniac at a molar ratio to the used BDO of 5 to 50 and in the presence of 1.0 to 4.5 wt.% hydrogen relative to the quantity of BDO used.
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公开(公告)号:EP2883863B1
公开(公告)日:2017-05-03
申请号:EP13196584
申请日:2013-12-11
Applicant: BASF SE
Inventor: WEICKGENANNT ANDREAS , SCHAACK BERND BASTIAN , WUCHER BARBARA , PANCHENKO ALEXANDER , HETTCHE FRANK , BOCK MARTIN , TAN AIK MEAM , DAHMEN KIRSTEN
IPC: C07C209/72 , C07C211/36
CPC classification number: C07C209/72 , B01J23/462 , B01J35/1014 , B01J35/1038 , B01J35/1042 , B01J37/0225 , B01J37/0236 , B01J37/08 , B01J37/18 , Y02P20/582 , C07C211/36
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