PROCESS FOR PREPARING 2-(2-TERT-BUTYLAMINOETHOXY)ETHANOL (TERT-BUTYLAMINODIGLYCOL, TBADG)

    公开(公告)号:CA2798971C

    公开(公告)日:2018-07-24

    申请号:CA2798971

    申请日:2011-05-18

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing 2-(2-tert.-butylamino-ethoxy)-ethanol (tert.-butylaminodiglycol, TBADG) by reacting diethylene glycol (DG) with tert.-butylamine (TBA) in the presence of hydrogen and a copper-containing catalyst, the reaction being carried out at a temperature ranging from 160 to 220°C in the presence of a copper- and alumina-containing catalyst, wherein the catalytically active mass of the catalyst, prior to the reduction thereof using hydrogen, contains 20 to 75% by weight of alumina (A12O3), 20 to 75% by weight of oxygen-containing copper compounds, calculated as CuO, and

    Procedimiento para la preparación de una mono-N-alquil-piperazina

    公开(公告)号:ES2573287T3

    公开(公告)日:2016-06-07

    申请号:ES13724592

    申请日:2013-05-23

    Applicant: BASF SE

    Abstract: Procedimiento para la preparación de una mono-N-alquil-piperazina de Fórmula I**Fórmula** en la que R1 significa alquilo de C1 a C5 o 2-(2-hidroxi-etoxi)-etilo mediante reacción de dietanolamina (DEOA) de fórmula II**Fórmula** con una amina primaria de fórmula H2N-R1 (III) en presencia de hidrógeno y de un catalizador soportado que contiene metal, caracterizado porque la masa catalíticamente activa del catalizador antes de su reducción con hidrógeno contiene compuestos de aluminio, de cobre, de níquel y de cobalto que contienen oxígeno y, en el intervalo del 0,2 al 5,0 % en peso, compuestos de estaño que contienen oxígeno, calculado como SnO y se lleva a cabo la reacción en la fase líquida a una presión absoluta en el intervalo de 95 a 145 bar.

    PROCESS FOR PREPARING RACEMIC .ALPHA.-AMINO ACIDS

    公开(公告)号:CA2856957A1

    公开(公告)日:2013-06-27

    申请号:CA2856957

    申请日:2012-12-12

    Applicant: BASF SE

    Abstract: A process for preparing racemic a-amino acids or glycine, characterized in that the corresponding a-hydroxycarboxylic acid selected from hydroxyacetic acid, lactic acid, maleic acid, a-hydroxyglutamic acid, isocitric acid, tartronic acid and tartaric acid, or at least one salt of the corresponding a-hydroxycarboxylic acid is reacted with at least one nitrogen compound (c) in the presence of at least one heterogeneous catalyst containing at least one transition metal and in the presence of hydrogen, nitrogen compound (c) being selected from primary and secondary amines and ammonia.

    METHOD FOR PRODUCING PYROLLIDINE
    8.
    发明专利

    公开(公告)号:IN10837DEN2014A

    公开(公告)日:2015-09-04

    申请号:IN10837DEN2014

    申请日:2014-12-18

    Applicant: BASF SE

    Abstract: Disclosed is a method for producing pyrollidine of formula (I) by reacting 1.4 butandiol (BDO) of formula (II) with ammoniac in the presence of hydrogen and a supported metal containing catalyser characterised in that prior to its reduction with hydrogen the catalytically active mass of the catalyser contains oxygen containing compounds of aluminium copper nickel and cobalt and oxygen containing compounds of tin in the wt.% range of 0.2 to 5.0% calculated as SnO and in that the reaction is performed in the liquid phase at an absolute pressure in the range of 160 to 220 bar at a temperature in the range of 160 to 230C using ammoniac at a molar ratio to the used BDO of 5 to 50 and in the presence of 1.0 to 4.5 wt.% hydrogen relative to the quantity of BDO used.

    METHOD FOR PRODUCING A MONO -N- ALKYL PIPERAZINE

    公开(公告)号:IN9198DEN2014A

    公开(公告)日:2015-07-10

    申请号:IN9198DEN2014

    申请日:2014-11-03

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing a mono-N-alkyl piperazine of formula (I), where R1 represents Ci to — alkyl or 2-(2-hydroxy-ethoxy) ethyl, by reacting diethanolamine (DEOA) of formula (II) with a primary amine of formula H2N-R1 - (III) in the presence of hydrogen and a supported catalyst containing metal. The catalytically active mass of the catalyst, before reduction of the latter using hydrogen, contains oxygenic Compounds of aluminum, copper, nickel and cobalt and between 0.2 and - 5.0 wt. % oxygenic Compounds of tin, calculated as SnO, and the reaction is carried out in the liquid phase at an absolute pressure ranging from 95 to 145 bar.

    PROCESS FOR PREPARING 2-(2-TERT-BUTYLAMINOETHOXY)ETHANOL (TERT-BUTYLAMINODIGLYCOL, TBADG)

    公开(公告)号:CA2798971A1

    公开(公告)日:2011-11-24

    申请号:CA2798971

    申请日:2011-05-18

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing 2-(2-tert.-butylamino-ethoxy)-ethanol (tert.-butylaminodiglycol, TBADG) by reacting diethylene glycol (DG) with tert.-butylamine (TBA) in the presence of hydrogen and a copper-containing catalyst, the reaction being carried out at a temperature ranging from 160 to 220ºC in the presence of a copper- and alumina-containing catalyst, wherein the catalytically active mass of the catalyst, prior to the reduction thereof using hydrogen, contains 20 to 75% by weight of alumina (Al2O3), 20 to 75% by weight of oxygen-containing copper compounds, calculated as CuO, and = 5% by weight of oxygen-containing nickel compounds, calculated as NiO.

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