公开(公告)号：WO2013092579A3

公开(公告)日：2013-08-15

申请号：PCT/EP2012075939

申请日：2012-12-18

Applicant: BASF SE ,  BASF SCHWEIZ AG

Inventor： BAUMANN ROBERT ,  BIEL MARKUS CHRISTIAN ,  FRANZKE AXEL ,  OFTRING ALFRED ,  TEICH FRIEDHELM ,  KLINGELHOEFER PAUL ,  HENZE GUIDO ,  SCHROETER MARIE KATRIN ,  KISTER OLESYA ,  BORCHERS SABINE ,  TUZINA PAVEL ,  DEIMLING BEATE ,  LEIDEL UDO

IPC: C07C227/02 ,  B01J21/06 ,  B01J23/72 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  B01J37/18

CPC classification number: B01J23/72 ,  B01J21/066 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/031 ,  B01J37/033 ,  B01J37/18 ,  C07C227/02 ,  C07C229/04

Abstract: The invention relates to a method for producing one or more complexing agents, selected from methylglycinediacetic acid, glutamic acid diacetic acid, and salts thereof, by catalytically dehydrogenating N,N-bis-(2-hydroxyethyl)-alanine and/or N,N-bis-(2-hydroxyethyl)-glutamic acid or salts thereof in the presence of alkali hydroxide, a catalyst containing copper and zirconium dioxide being used, the activation of which is a reduction, characterized in that the precursor of the catalyst in question has a degree of crystallization K defined as (I) in the range of 0 to 50%.

Abstract translation: 一种用于生产从甲基甘氨酸二乙酸，谷氨酸二乙酸和它们的盐中选择的一种或多种络合剂，通过N，N-双（2-羟乙基）丙氨酸和/或N，N-双（2-羟乙基） - 谷氨酸的催化脱氢方法 或其盐在碱金属氢氧化物的存在下它们，使用含有铜和二氧化锆的催化剂，其激活为还原，其特征在于各自的催化剂的前体的结晶度K，定义为在0至50％的范围（I） 有。

公开(公告)号：ES2661128T3

公开(公告)日：2018-03-27

申请号：ES14790620

申请日：2014-10-30

Applicant: BASF SE

Inventor： MAITRO-VOGEL SOPHIE ,  ERNST MARTIN ,  SCHADE CHRISTIAN ,  TUZINA PAVEL ,  TRAN-THIEN HOANG TRANG ,  REIS-WALTHER EVA-MARIA ,  SHABELINA NATALIA ,  HILLESHEIM NINA SUSANNE ,  SCHOLZ CHRISTIAN

IPC: C04B24/32 ,  C04B24/16 ,  C07C323/14

Abstract: Compuestos insaturados de fórmula general (I) **(Ver fórmula)** en la que R1, R2, R3 independientemente entre sí, siendo iguales o distintos, significan H, CH3, R4 significa alquileno C1-C30 lineal o ramificado, R5, R6 independientemente entre sí, siendo iguales o distintos, significan H, alquilo C1-C20, cicloalquilo C3-C15, arilo, alquilo -CH2-O-C1-C20, alquenilo CH2-O-C2-C20, pudiendo formar R5 y R6 también conjuntamente un alquileno C3-C6, R7 independientemente entre sí, siendo iguales o distintos, significa H, alquilo C1-C4, **(Ver fórmula)** R8 significa alquilo C1-C22, alquenilo C2-C22, y n significa un número entero de 2 a 200.