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公开(公告)号:EA022635B1
公开(公告)日:2016-02-29
申请号:EA201270743
申请日:2011-04-12
Applicant: UNIV TEXAS , BASF SE
Inventor: WEERASOORIYA UPALI P , POPE GARY A , BITTNER CHRISTIAN , OETTER GUNTER , TINSLEY JACK F , SPINDLER CHRISTIAN , JURGENSON GABRIELA ALVAREZ , VOGEL SOPHIE
Abstract: Вдокументеописаныкомпозициии способыполученияанионныхповерхностно-активныхвеществпутемалкоксилированияспиртаГербе (GA), имеющего 18-36 атомовуглерода, сприменениембутиленоксидаи, факультативно, пропиленоксидаи/илиэтиленоксидас последующимвключениемконцевойанионнойгруппы. GA изобретенияполучаютпростыми недорогимспособом, которыйвключаетвысокотемпературнуюкатализируемуюоснованиямидимеризациюспиртовс 9-18 атомамиуглерода. Многочисленныегидрофобныеповерхностно-активныевеществанаосновепростыхэфировизобретениянаходятприменениепривнесенияхдляувеличениянефтеотдачи (EOR), гдеегоприменяютдлясолюбилизациии мобилизациинефтии дляочисткиокружающихвеществ. Дополнительногидрофобныйалкоксилированный GA безанионнойконцевойгруппыможноприменятьв качественеионогенногоповерхностно-активноговеществасосверхвысокиммолекулярнымвесом.
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公开(公告)号:DK2488599T3
公开(公告)日:2014-06-16
申请号:DK10763701
申请日:2010-10-11
Applicant: BASF SE
Inventor: BITTNER CHRISTIAN , OETTER GÜNTER , TINSLEY JACK , SPINDLER CHRISTIAN , ALVAREZ JÜRGENSON GABRIELA , VOGEL SOPHIE
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公开(公告)号:AU2011240606A1
公开(公告)日:2012-09-27
申请号:AU2011240606
申请日:2011-04-12
Applicant: BASF SE , UNIV TEXAS
Inventor: WEERASOORIYA UPALI P , POPE GARY A , BITTNER CHRISTIAN , OETTER GUNTER , TINSLEY JACK F , SPINDLER CHRISTIAN , JURGENSON GABRIELA ALVAREZ , VOGEL SOPHIE
Abstract: Compositions and methods of synthesis of anionic surfactants by alkoxylation of a Guerbet alcohol (GA) having 12 to 36 carbon atoms using butylene oxide, and optionally propylene oxide and/or ethylene oxide followed by the incorporation of a terminal anionic group are described herein. The GA of the present invention is made by a facile and inexpensive method that involves high temperature base catalyzed dimerization of alcohols with 6 to 18 carbon atoms. The large hydrophobe ether surfactants of the present invention find uses in enhanced oil recovery (EOR) applications where it is used for solubilization and mobilization of oil and for environmental cleanup. Further, the hydrophobe alkoxylated GA without anionic terminal group can be used as an ultra- high molecular weight non-ionic surfactant.
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公开(公告)号:CA2777535A1
公开(公告)日:2011-04-21
申请号:CA2777535
申请日:2010-10-05
Applicant: BASF SE
Inventor: BITTNER CHRISTIAN , OETTER GUENTER , TINSLEY JACK , SPINDLER CHRISTIAN , ALVAREZ JUERGENSON GABRIELA , VOGEL SOPHIE
Abstract: The invention relates to a method for producing oil, in particular Winsor Type III microemulsion flooding, wherein an aqueous surfactant formulation comprising at least one non-ionic surfactant having 11 to 40 ethoxy unit and having a hydrophobic radical of 8 to 32 carbon atoms, and comprising at least one further surfactant different therefrom, is pressed through injection wells into an oil deposit, and crude oil is extracted from the deposit via production wells.
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公开(公告)号:AU2010305947B9
公开(公告)日:2015-07-09
申请号:AU2010305947
申请日:2010-10-05
Applicant: BASF SE
Inventor: BITTNER CHRISTIAN , OETTER GUENTER , TINSLEY JACK , SPINDLER CHRISTIAN , ALVAREZ JUERGENSON GABRIELA , VOGEL SOPHIE
IPC: C09K23/00
Abstract: The invention relates to a method for producing oil, in particular Winsor Type III microemulsion flooding, wherein an aqueous surfactant formulation comprising at least one non-ionic surfactant having 11 to 40 ethoxy unit and having a hydrophobic radical of 8 to 32 carbon atoms, and comprising at least one further surfactant different therefrom, is pressed through injection wells into an oil deposit, and crude oil is extracted from the deposit via production wells.
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公开(公告)号:ECSP12011882A
公开(公告)日:2012-07-31
申请号:ECSP12011882
申请日:2012-05-11
Applicant: BASF SE
Inventor: BITTNER CHRISTIAN , OETTER GÜNTER , TINSLEY JACK , SPINDLER CHRISTIAN , ALVAREZ JÜRGENSON GABRIELA , VOGEL SOPHIE
Abstract: Proceso para la extracción de petróleo, especialmente, la inundación con microemulsionesWinsor tipo III, en el que se inyecta una formulación acuosa de surfactante, que comprende por lo menos un alquilpolialcoxisulfato que contiene grupos propoxi, así como por lo menos otro surfactante diferente del primero, por pozos de inyección en un yacimiento de petróleo y se extrae el petróleo crudo del yacimiento por pozos de producción. El alquilpolialcoxisulfato que contiene grupos propoxi se obtiene aquí por sulfonación de un alcohol alcoxilado, cuyo alcohol alcoxilado se prepara por alcoxilación de un alcohol usando catalizadores de cianuro de metal doble o arcillas de hidróxido doble.
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公开(公告)号:AU2010305947A1
公开(公告)日:2012-06-07
申请号:AU2010305947
申请日:2010-10-05
Applicant: BASF SE
Inventor: BITTNER CHRISTIAN , OETTER GUNTER , TINSLEY JACK , SPINDLER CHRISTIAN , ALVAREZ JURGENSON GABRIELA , VOGEL SOPHIE
Abstract: The invention relates to a method for producing oil, in particular Winsor Type III microemulsion flooding, wherein an aqueous surfactant formulation comprising at least one non-ionic surfactant having 11 to 40 ethoxy unit and having a hydrophobic radical of 8 to 32 carbon atoms, and comprising at least one further surfactant different therefrom, is pressed through injection wells into an oil deposit, and crude oil is extracted from the deposit via production wells.
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公开(公告)号:AU2010305948A2
公开(公告)日:2012-05-31
申请号:AU2010305948
申请日:2010-10-05
Applicant: BASF SE
Inventor: BITTNER CHRISTIAN , OETTER GUNTER , TINSLEY JACK , SPINDLER CHRISTIAN , ALVAREZ JURGENSON GABRIELA , VOGEL SOPHIE
Abstract: The invention relates to a method for producing oil, in particular Winsor Type III microemulsion flooding, wherein an aqueous surfactant formulation comprising at least one non-ionic surfactant having 8 to 40 ethoxy units and having a polydispersion index of 1.01 to 1.12, and at least one further surfactant is pressed through injection wells into an oil deposit, and crude oil is extracted from the deposit via production wells.
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公开(公告)号:AU2010305948A1
公开(公告)日:2012-05-24
申请号:AU2010305948
申请日:2010-10-05
Applicant: BASF SE
Inventor: BITTNER CHRISTIAN , OETTER GUNTER , TINSLEY JACK , SPINDLER CHRISTIAN , ALVAREZ JURGENSON GABRIELA , VOGEL SOPHIE
Abstract: The invention relates to a method for producing oil, in particular Winsor Type III microemulsion flooding, wherein an aqueous surfactant formulation comprising at least one non-ionic surfactant having 8 to 40 ethoxy units and having a polydispersion index of 1.01 to 1.12, and at least one further surfactant is pressed through injection wells into an oil deposit, and crude oil is extracted from the deposit via production wells.
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公开(公告)号:MX2012003976A
公开(公告)日:2012-05-08
申请号:MX2012003976
申请日:2010-10-11
Applicant: BASF SE
Inventor: OETTER GUENTER , BITTNER CHRISTIAN , SPINDLER CHRISTIAN , TINSLEY JACK , JUERGENSON GABRIELA ALVAREZ , VOGEL SOPHIE
Abstract: Proceso para la extracción de petróleo, especialmente, la inundación con microemulsiones Winsor tipo III, en el que se inyecta una formulación acuosa de surfactante, que comprende por lo menos un alquilpolialcoxisulfato que contiene grupos propoxi, así como por lo menos otro surfactante diferente del primero, por pozos de inyección en un yacimiento de petróleo y se extrae el petróleo crudo del yacimiento por pozos de producción. El alquilpolialcoxisulfato que contiene grupos propoxi se obtiene aquí por sulfonación de un alcohol alcoxilado, cuyo alcohol alcoxilado se prepara por alcoxilación de un alcohol usando catalizadores de cianuro de metal doble o arcillas de hidróxido doble.
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