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    USE OF BENZOTROPOLONE DERIVATIVES AS UV ABSORBERS AND ANTIOXIDANTS AND THEIR USE IN SUNSCREENS AND/OR COSMETIC COMPOSITIONS
    2.
    发明申请
    USE OF BENZOTROPOLONE DERIVATIVES AS UV ABSORBERS AND ANTIOXIDANTS AND THEIR USE IN SUNSCREENS AND/OR COSMETIC COMPOSITIONS 审中-公开
    作为紫外线吸收剂和抗氧化剂的苯并吡喃酮衍生物的使用及其在SUNSCREENS和/或化妆品组合物中的应用

    公开(公告)号：WO2009156324A3

    公开(公告)日：2012-06-21

    申请号：PCT/EP2009057587

    申请日：2009-06-18

    Applicant: BASF SE ,  WAGNER BARBARA ,  OEHRLEIN REINHOLD ,  HERZOG BERND ,  EICHIN KAI ,  BAISCH GABRIELE ,  PORTMANN STEPHANIE

    Inventor： WAGNER BARBARA ,  OEHRLEIN REINHOLD ,  HERZOG BERND ,  EICHIN KAI ,  BAISCH GABRIELE ,  PORTMANN STEPHANIE

    IPC: A61Q17/00 ,  A61K8/35 ,  A61Q17/04 ,  C07C49/717 ,  C07C49/747 ,  C07C62/38 ,  C07C69/712 ,  C07C69/757 ,  C07C305/18 ,  C07D311/02 ,  C07F9/40 ,  C07H15/18 ,  C07H15/203 ,  C07H15/26

    CPC classification number: A61Q17/04 ,  A61K8/35 ,  A61Q19/08 ,  C07C49/747 ,  C07C62/38 ,  C07C69/712 ,  C07C69/757 ,  C07C305/18 ,  C07C2602/12 ,  C07F9/4006 ,  C07H15/18 ,  C07H15/203 ,  C07H15/26

    Abstract: Described is the use of benzotropolone and their derivatives, especially the compounds of formula (1); wherein R2, R3, R4, R5 and R6 independently of one another are hydrogen; OH; C1-C30alkyl, C2-C30al- kenyl, C1-C30alkoxy, C3-C12cycloalkyl or C1C30hydroxyalkyl, which may be substituted by one or more E and/or interrupted by one or more D; C6-C20aryl, which may be substitu¬ ted by one or more G; C4-C20heteroaryl, which may be substituted by one or more G, C2- C18alkenyl, C2-C18alkynyl, C7-C25aralkyl, CN, or -CO-R17; C1-C30mono- or dialkylamino; COR9; COOR9; CONR9R10; CN; SO2R9; OCOOR9; OCOR9; NHCOOR9; NR9COR10; NH2; *-(CO)-NH-(CH2)n1-(PO)-(OR11)2; -(CO)-O-(CH2)n1-(PO)-(OR11)2; sulphate; sulphonate; phosphate; phosphonate; -(CH2)n2-[O-(SO2)]n3-OR11; -O-(CH2)n4(CO)n5-R11; -(O)n6-(CH2)n7-(PO)-(OR9)2; -(O)n6-(CH2)n7-SO2-OR9; halogen; organosilanyl; organo- siloxanyl; or a sugar residue linked directly in an a- or ß-mode via the anomeric oxygen to the benzotropolone system or via a linear or branched alkylene, alkenylene, alkadiene or alkatriene spacer (sugar- (CH2)n-(X1)1 or 0 -benzotropolone system, wherein n = 1 -10 and X1 = -0-; -(CO)-; -0-C0-; -COO-, -NH-; -S-; -SO2-); R1, R7 and R8 independently of one another are hydrogen; C1C12alkyl or C3-C12-cycloalkyl, which may be substituted by one or more E and/or interrupted by one or more D; C6- C20aryl, which may be substituted by one or more G; C4-C20heteroaryl, which may be substituted by one or more G, C2-C18alkenyl, C2-C18alkynyl, C7-C25aralkyl, or COOR9; COR9; CONR9R10; SO3R9; SO2R9; PO3(R9)2; PO2(R9)2; organosilanyl; organosiloxanyl; or a sugar residue linked directly in an a- or ß-mode via the anomeric oxygen to the benzotropolone system or via a linear or branched alkylene, alkenylene, alkadiene or alkatriene spacer (sugar-(CH2)n-(X2)1 or 0-*, wherein n = 1 -10 and X2 = -C(=0)-; -0-C0-*); R9 and R10 independently from each other are hydrogen; C1C18alkyl or C3-C12-cycloalkyl which may be substituted by one or more E and/or interrupted by one or more D; C6- C20aryl, which may be substituted by one or more G; C4-C20heteroaryl, which may be substituted by one or more G; organosilanyl; organosiloxanyl; or a sugar residue linked directly in an a- or ß-mode via the anomeric oxygen or via a linear or branched alkylene, alkenylene, alkadiene or alkatriene spacer (sugar- (CH2)n-*, wherein n = 1 -10); or R9 and R10 together form a five or six membered ring, R11 is hydrogen; or C1-C5alkyl; n1, n2, n4 and n7 independently from each other are a number from 1 to 5; n3, n5 and n6 independently from each other are a 0; or 1; D is -CO-; -COO-; -S-; -SO-; -SO2-; -O-; -NR14-; -S1R19R20-; -POR11-; -CR12=CR13-; or -C=C-; and E is -0R18; -SR18; -NR14R15; -NR14COR15; -C0R17; -COOR16; -CONR14R15; -CN; halogen; Or SO3R18; SO2R18; PO3(R18)2; PO2(R18)2; organosilanyl; organosiloxanyl; or a sugar residue linked directly in an a- or ß-mode via the anomeric oxygen or via a linear or branched alkylene, alkenylene, alkadiene or alkatriene spacer (sugar- (CH2)n-(X1)1 or 0-*, wherein n = 1 -10 and X1 = -0-; -C(=0)-; -0-C0-; -COO-; -NH-; -S-; -SO2-); G is E; C1-C18alkyl, which is optionally interrupted by D; C1-C18perfluoroalkyl; C1-C18alkoxy, which is optionally substituted by E and/or interrupted by D; wherein R12, R13, R14 and R15 independently of each other are hydrogen; C6-C18aryl which is optionally substituted by OH, C1-C18alkyl or C1-C18alkoxy; C1-C18alkyl, which is optionally interrupted by -O-; or Ri4 and Ri5 together form a five or six membered ring, Ri6 is hydrogen; C6-Ci8aryl which is optionally substituted by OH, C1-C18alkyl or d- C18alkoxy; C1-C18alkyl which is optionally interrupted by -O-; R17 is H; C6-C18aryl which is optionally substituted by OH, C1-C18alkyl or C1-C18alkoxy; or d- C18alkyl which is optionally interrupted by -O-; R18 is hydrogen; C6-C18aryl, which is optionally substituted by OH, C1-C18alkyl or d- C18alkoxy; C1-C18alkyl, which is optionally interrupted by -O-; R19 and R20 independently of each other are hydrogen; C1-C18alkyl; C6-C18aryl which is optionally substituted by C1-C18alkyl; and R21 is C1-C18alkyl; or C6-C18aryl, which is substituted by C1-C18alkyl; * means, that this radical is directed to the benzotropolone moiety; for the protection of human and animal hair and skin against UV radiation.

    Abstract translation: 描述了苯佐龙醇及其衍生物，特别是式（1）的化合物的用途; 其中R2，R3，R4，R5和R6彼此独立地是氢; 哦; C 1 -C 30烷基，C 2 -C 30亚烯基，C 1 -C 30烷氧基，C 3 -C 12环烷基或C 1 -C 30羟烷基，其可以被一个或多个E取代和/或被一个或多个D中断; 可以被一个或多个G取代的C 6 -C 20芳基; 可以被一个或多个G，C 2 -C 18烯基，C 2 -C 18炔基，C 7 -C 25芳烷基，CN或-CO-R 17取代的C 4 -C 20杂芳基; C 1 -C 30单 - 或二烷基氨基; COR 9; COOR9; CONR9R10; CN; SO 2 R 9; OCOOR9; OCOR9; NHCOOR9; NR9COR10; NH2; * - （CO）-NH-（CH 2）N 1 - （PO） - （OR 11）2; - （CO）-O-（CH 2）N 1 - （PO） - （OR 11）2; 硫酸盐; 磺酸盐; 磷酸盐; 膦酸盐; - （CH 2）N 2 - [O-（SO2）] N3-OR11; -O-（CH2）N4（CO）N5-R11; - （O）N 6 - （CH 2）N 7 - （PO） - （OR 9）2; - （O）N 6 - （CH 2）N7-SO2-OR 9; 卤素; organosilanyl; 有机硅氧烷基 或通过异头氧直接连接到苯佐洛酮系统或通过直链或支链亚烷基，亚烯基，链二烯或烷基三烯间隔物（糖 - （CH 2）n - （X1）1或O - 苯并异噻唑酮系统，其中n = 1-10且X1 = -0-; - （CO） - ; -O-C0-; -COO-，-NH-; -S-; -SO2-）; R 1，R 7和R 8彼此独立地是氢; C 1 -C 12烷基或C 3 -C 12环烷基，其可以被一个或多个E取代和/或被一个或多个D中断; C 6 -C 20芳基，其可以被一个或多个G取代; 可以被一个或多个G，C 2 -C 18烯基，C 2 -C 18炔基，C 7 -C 25芳烷基或COOR 9取代的C 1 -C 20杂芳基; COR 9; CONR9R10; SO3R9; SO 2 R 9; PO3（R 9）2; PO2（R 9）2; organosilanyl; 有机硅氧烷; 或直链或α-支链的亚烷基，链烯二烯或三亚胺间隔基（糖 - （CH 2）n - （X 2）1或O - *，其中n = 1-10，X2 = -C（= O） - ; - O-C0- *）; R9和R10彼此独立地是氢; 可以被一个或多个E取代和/或被一个或多个D中断的C 1 -C 18烷基或C 3 -C 12 - 环烷基; 可以被一个或多个G取代的C 6 -C 20芳基; 可以被一个或多个G取代的C 4 -C 20杂芳基; organosilanyl; 有机硅氧烷; 或通过端基异构体氧或经由直链或支链的亚烷基，亚烯基，链二烯或烷基三烯间隔物（糖 - （CH 2）n - ），其中n = 1-10）直接连接在α-或β-模式中的糖残基; 或R 9和R 10一起形成五元或六元环，R 11为氢; 或C 1 -C 5烷基; n1，n2，n4和n7彼此独立地为1至5的数; n3，n5和n6彼此独立地为0; 或1; D是-CO-; -COO-; -S-; -所以-; -SO2-; -O-; NR 14; -S1R19R20-; -POR11-; -CR12 = CR13-; 或-C = C-; E为-0R18; -SR18; -NR14R15; -NR14COR15; -C0R17; -COOR16; -CONR14R15; -CN; 卤素; 或SO3R18; SO2R18; PO3（R18）2; PO2（R18）2; organosilanyl; 有机硅氧烷; 或通过异头氧直接或通过直链或支链亚烷基，亚烯基，链二烯或烷三胺间隔基（糖 - （CH 2）n - （X1）1或0- *）直接连接在α-或β-模式上的糖残基，其中 n = 1-10且X1 = -0-; -C（= O） - ; - O-O-COO-; -NH-; -S-; -SO2-）; G是E 任选地被D中断的C 1 -C 18烷基; C1-C18perfluoroalkyl; C1-C18烷氧基，其任选地被E取代和/或被D中断; 其中R 12，R 13，R 14和R 15彼此独立地是氢; 任选被OH，C 1 -C 18烷基或C 1 -C 18烷氧基取代的C 6 -C 18芳基; 任选地被-O-间隔的C 1 -C 18烷基; 或R 14和R 15一起形成五元或六元环，R 6为氢; 任选被OH，C 1 -C 18烷基或C 1 -C 18烷氧基取代的C 6 -C 18芳基; 任选被-O-间隔的C 1 -C 18烷基; R17为H; 任选被OH，C 1 -C 18烷基或C 1 -C 18烷氧基取代的C 6 -C 18芳基; 或任选被-O-中断的C 1 -C 18烷基; R18是氢; 任选被OH，C 1 -C 18烷基或C 1 -C 18烷氧基取代的C 6 -C 18芳基; 任选地被-O-间隔的C 1 -C 18烷基; R 19和R 20彼此独立地是氢; C1-C18烷基; 任选被C 1 -C 18烷基取代的C 6 -C 18芳基; 和R 21是C 1 -C 18烷基; 或被C 1 -C 18烷基取代的C 6 -C 18芳基; *表示该基团针对苯佐洛尔酮部分; 用于保护人和动物的头发和皮肤免受紫外线辐射。

    BENZYLIDENE COMPOUNDS COMPRISING PHOSPHONO-GROUPS
    4.
    发明申请
    BENZYLIDENE COMPOUNDS COMPRISING PHOSPHONO-GROUPS 审中-公开
    含有菲律宾组合物的苯并噻唑化合物

    公开(公告)号：WO2010054966A2

    公开(公告)日：2010-05-20

    申请号：PCT/EP2009064593

    申请日：2009-11-04

    Applicant: BASF SE ,  WAGNER BARBARA

    Inventor： WAGNER BARBARA

    IPC: A61K8/55 ,  A61Q17/04

    CPC classification number: A61Q17/04 ,  A61K8/55

    Abstract: Disclosed is the use of the compounds of formula (1) wherein R1 and R2 independently of one another are hydrogen; unsubstituted or substituted C1- C12 alkyl; unsubstituted or substituted C3 -C12 cycloalkyl; unsubstituted or substituted C6- C20 aryl; or unsubstituted or substituted C2-C20 alkenyl; R3 is PO3 R1 R2; COOR6; COR7; CONR7 R8; -SO2 R6; CN; unsubstituted or substituted C6- C20 aryl; R4 is unsubstituted C6- C20 aryl; or C6- C20 aryl which is substituted by at least one C1- C18 alkyl, C1- C18 alkoxy, C3- C12 cycloalkyl, hydroxy, amino, mono-or di-C1- C18 alkylamino, -NR10 COR11 or the radical of formula (1a) or unsubstituted or substituted C4 -C20 heteroaryl; R5 is hydrogen; substituted or unsubstituted C1 -C20 alkyl; unsubstituted or substituted C3 - C12 cycloalkyl; unsubstituted or substituted C6 -C20 aryl; or unsubstituted or substituted C4- C20 heteroaryl; or R4 and R5 form a cycloaliphatic ring; R6, R7 and R8 independently from each other are hydrogen; C1- C18 alkylor C3-C12 cycloalkyl, which may be substituted by one or more E and/or interrupted by one or more D; or C6- C20 aryl, which may be substituted by G; or R7 and R8 together form a five or six membered ring; D is -CO-; -COO-; -S-; -SO-; -SO2 -; -O-; -NR9 -; -SiR12 R13 -; -POR14 -; -CR15 =CR16 -; or -C=C-; E is -OR17; -SR17; -NR10 R11; -NR10 COR11; -COR11; -COOR 11; -CONR10 R11; -CN; halogen; SO3 R18; SO2 R18; PO3 (R18 )2; or PO2 (R18 )2; G is E; C1-C18 alkyl, which is optionally interrupted by D; C1-C18 perfluoroalkyl; C1 -C18 alkoxy, which is optionally substituted by E and/or interrupted by D; wherein R9, R10 and R11, independently of each other are hydrogen; C6 -C18 aryl which is optionally substituted by C1-C18 alkyl or C1-C18 alkoxy; C1-C18 alkyl, which is optionally interrupted by -O-;or R10 and R11 together form a five or six membered ring; R12 and R13 independently of each other are hydrogen; C1- C18 alkyl; or C6-C18 aryl which is optionally substituted by C1-C18 alkyl; R14 is C1-C18 alkyl; or C6-C18 aryl, which is optionally substituted by C1-C18 alkyl; R15 and R16 independently of each other are hydrogen; C6-C18 aryl which is optionally substituted by C1- C18 alkylor C1-C18 alkoxy; or C1-C18 alkyl which is optionally interrupted by -O-; R17 is H; C6-C18 aryl which is optionally substituted by C1- C18 alkyl or C1-C18 alkoxy; or C1- C18 alkyl which is optionally interrupted by -O-; and R18 is hydrogen; C6-C18 aryl, which is optionally substituted by C1-C18 alkyl or C1- C18 alkoxy; or C1 -C18 alkyl, which is optionally interrupted by -O-; for the protecting of human and animal hair and skin from UV radiation. The UV filters of the present invention represent oil-soluble substances which advantageously absorb in the UV-A and UV-B region.

    Abstract translation: 公开了其中R 1和R 2彼此独立地是氢的式（1）化合物的用途; 未取代或取代的C 1 -C 12烷基; 未取代或取代的C 3 -C 12环烷基; 未取代或取代的C 6 -C 20芳基; 或未取代或取代的C 2 -C 20烯基; R3是PO3 R1R2; COOR6; COR 7; CONR7 R8; -SO 2 R 6; CN; 未取代或取代的C 6 -C 20芳基; R4是未取代的C6-C20芳基; 或被至少一个C 1 -C 18烷基取代的C 6 -C 20芳基，C 1 -C 18烷氧基，C 3 -C 12环烷基，羟基，氨基，单或二-C 18烷基氨基，-NR 10 COR 11或式 1a）或未取代或取代的C 4 -C 20杂芳基; R5是氢; 取代或未取代的C 1 -C 20烷基; 未取代或取代的C 3 -C 12环烷基; 未取代或取代的C 6 -C 20芳基; 或未取代或取代的C 4 -C 20杂芳基; 或R 4和R 5形成脂环族环; R6，R7和R8彼此独立地是氢; C 1 -C 18烷基或C 3 -C 12环烷基，其可以被一个或多个E取代和/或被一个或多个D中断; 或可被G取代的C 6 -C 20芳基; 或R 7和R 8一起形成五元或六元环; D是-CO-; -COO-; -S-; -所以-; -SO 2 - ; -O-; -NR9 - ; -SiR12 R13 - ; -POR14 - ; -CR15 = CR16 - ; 或-C = C-; E为-OR17; -SR17; -NR10 R11; -NR10 COR11; -COR11; -COOR 11; -CONR10 R11; -CN; 卤素; SO3 R18; SO2 R18; PO3（R18）2; 或PO2（R18）2; G是E C1-C18烷基，其任选地被D中断; C1-C18全氟烷基; 任选被E取代和/或被D中断的C 1 -C 18烷氧基， 其中R9，R10和R11彼此独立地是氢; 任选被C 1 -C 18烷基或C 1 -C 18烷氧基取代的C 6 -C 18芳基; C1-C18烷基，其任选被-O-间隔;或R 10和R 11一起形成五元或六元环; R 12和R 13彼此独立地是氢; C 1 -C 18烷基; 或任选被C 1 -C 18烷基取代的C 6 -C 18芳基; R14是C1-C18烷基; 或任选被C 1 -C 18烷基取代的C 6 -C 18芳基; R 15和R 16彼此独立地是氢; 任选被C 1 -C 18烷基或C 1 -C 18烷氧基取代的C 6 -C 18芳基; 或任选被-O-间隔的C 1 -C 18烷基; R17为H; 任选被C 1 -C 18烷基或C 1 -C 18烷氧基取代的C 6 -C 18芳基; 或任选被-O-间隔的C 1 -C 18烷基; R18为氢; 任选被C 1 -C 18烷基或C 1 -C 18烷氧基取代的C 6 -C 18芳基; 或任选被-O-间隔的C 1 -C 18烷基; 用于保护人体和动物毛发和皮肤免受紫外线辐射。 本发明的UV滤光器代表在UV-A和UV-B区域有利地吸收的油溶性物质。

    DIMERIC BENZYLIDENE MALONATES
    5.
    发明申请
    DIMERIC BENZYLIDENE MALONATES 审中-公开
    二甲苯胆碱

    公开(公告)号：WO2009112403A3

    公开(公告)日：2009-11-12

    申请号：PCT/EP2009052531

    申请日：2009-03-04

    Applicant: BASF SE ,  HANSCH MARKUS ,  EHLIS THOMAS ,  WAGNER BARBARA

    Inventor： HANSCH MARKUS ,  EHLIS THOMAS ,  WAGNER BARBARA

    IPC: A61K8/37 ,  A61Q17/04 ,  C07C67/347 ,  C07C69/618

    CPC classification number: A61Q17/04 ,  A61K8/37 ,  A61K8/585 ,  C07C67/03 ,  C07C67/31 ,  C07C67/343 ,  C07C69/734 ,  C07C2601/14 ,  C07F7/0889 ,  C07C69/732

    Abstract: Disclosed is the use of benzylidene malonates of formula (1), wherein R1 and R2, independently from each other are hydrogen; OH; C1-C12alkyl; C1-C12alkoxy; C1-C12alkylamino; C1-C12dialkylamino; water-solubilizing groups, selected from carboxylate, sulfonates or ammonium radicals; R3 is COOR5; COR5; CONR5R6; CN; or SO2R7, R4 is COOR8; COR9; CONR8R9; CN; or SO2R10; R5, R6, R7, R8, R9 and R10 independently from each other are C1-C18alkyl; unsubstituted or by one or more than one C1-C4alkyl substituted C3-C12-cycloalkyl; unsubstituted or C1-C6alkyl-substituted C6-C20aryl; organosilanyl, or organosiloxanyl; A is -C1-C20alkylene-, -CH2CH(OH)CH2-, -C5-C20cycloalkylene, --C2-C20alkenylene-, -C5- C10arylene-, or -C5-C10arylene-(C1-C10alkylene)- which are unsubstituted or substituted, straight-chain or branched, optionally interrupted by one or more than one heteroatoms selected from -O, -S- or -NH-; for the protection of human and animal hair and skin against UV radiation.

    Abstract translation: 公开了式（1）的亚苄基丙二酸酯的用途，其中R 1和R 2彼此独立地为氢; 哦; C1-C12烷基; C1-C12烷氧基; C1-C12alkylamino; C1-C12dialkylamino; 选自羧酸盐，磺酸盐或铵基的水溶性基团; R3为COOR5; COR5; CONR5R6; CN; 或SO 2 R 7，R 4为COOR 8; COR 9; CONR8R9; CN; 或SO2R10; R 5，R 6，R 7，R 8，R 9和R 10彼此独立地为C 1 -C 18烷基; 未取代或被一个或多个C 1 -C 4烷基取代的C 3 -C 12 - 环烷基取代; 未取代的或C 1 -C 6烷基取代的C 6 -C 20芳基; 有机硅烷基或有机硅氧烷基; A是未取代的-C 1 -C 20亚烷基 - ， - CH 2 CH（OH）CH 2 - ， - C 5 -C 20亚环烷基，-C 2 -C 20亚烯基，-C 5 -C 10亚芳基或-C 5 -C 10亚芳基 - （C 1 -C 10亚烷基） 任选被一个或多于一个选自-O，-S-或-NH-的杂原子间隔的取代的，直链或支链的; 用于保护人和动物的头发和皮肤免受紫外线辐射。

    BENZYLIDENE MALONATES
    6.
    发明申请
    BENZYLIDENE MALONATES 审中-公开
    苯并噻唑啉酮

    公开(公告)号：WO2010136360A3

    公开(公告)日：2011-11-24

    申请号：PCT/EP2010056843

    申请日：2010-05-19

    Applicant: BASF SE ,  HANSCH MARKUS ,  EHLIS THOMAS ,  WALLQUIST OLOF ,  WAGNER BARBARA ,  HERZOG BERND ,  GIESINGER JOCHEN

    Inventor： HANSCH MARKUS ,  EHLIS THOMAS ,  WALLQUIST OLOF ,  WAGNER BARBARA ,  HERZOG BERND ,  GIESINGER JOCHEN

    IPC: A61K8/37 ,  A61Q17/04 ,  C07C69/73

    CPC classification number: A61K8/37 ,  A61Q17/04 ,  C07C69/73

    Abstract: Disclosed is the use of benzylidene malonates of formula (1), wherein R1 is methyl; ethyl; propyl; or n-butyl; if R1 is methyl, then R is tert. butyl; formula (A); a radical of formula (1a); or a radical of formula (1b); wherein R2 and R3, independently from each other are hydrogen; or methyl; R4 is methyl; ethyl; or n-propyl; R5 and R6 independently from each other are hydrogen; or C1-C3alkyl; if R1 is ethyl; propyl; or n-butyl, then R is isopropyl; for the protection of human and animal hair and skin against UV radiation.

    Abstract translation: 公开了式（1）的亚苄基丙二酸酯的用途，其中R 1是甲基; 乙基; 丙基; 或正丁基; 如果R1是甲基，那么R是叔丁基。 丁基; 式（A）; 式（1a）的基团; 或式（1b）的基团; 其中R2和R3彼此独立地是氢; 或甲基; R4是甲基; 乙基; 或正丙基​​; R5和R6彼此独立地是氢; 或C 1 -C 3烷基; 如果R1是乙基; 丙基; 或正丁基，那么R是异丙基; 用于保护人和动物的头发和皮肤免受紫外线辐射。

    Uso de benzotropolona e derivados da mesma
    8.
    发明专利
    Uso de benzotropolona e derivados da mesma 未知

    公开(公告)号：BRPI0914926B1

    公开(公告)日：2022-04-12

    申请号：BRPI0914926

    申请日：2009-06-18

    Applicant: BASF SE

    Inventor： WAGNER BARBARA ,  HERZOG BERND ,  BAISCH GABRIELE ,  EICHIN KAI ,  OHRLEIN REINHOLD ,  PORTMANN STEPHANIE

    IPC: C07C49/717 ,  A61K8/35 ,  A61Q17/00 ,  A61Q17/04 ,  C07D311/02 ,  C07H15/203

    Abstract: uso de benzotropolona e derlv ados da mesma, composição cosmética, compostos, e, método para sintetizar um derlv ado de benzotropolona descreve-se o uso de benzotropolona e derivados da mesma, particularmente os compostos de fórmula (1) sendo que r2, r3, r4, r5 e r6 independentemente um do outro são hidrogênio; oh; c1-c3oalquila, crc30alquenila, c1-c30alcóxi, c3-c12cicloalquila ou c1- c30hidroxialquila, que pode ser substituído por um ou mais e e/ ou interrompido por um ou mais d; c6-c20arila, que pode ser substituído por um ou mais g; c4-c20heteroarila, que pode ser substituído por um ou mais g, cr c1salquenila, crc18alquinila, crc25aralquila, cn, ou -co-r17; c1-c30monoou dialquilamino; cor9; coor9; conr9r10; cn; so2r9; ocoor9; ocor9; nhcoor9; nr9cor10; nh2; *-(co)-nh-(ch2)n1-(po)-(or11 )2; - (co)-o-(ch2)n1-(po)-(or11 ) 2; sulfato; sulfonato; fosfato; fosfonato; - (ch2)nr[o-(so2)]n3-ür11; -o-(ch2)n4(co)ns-r11; -(o)n6-(ch2)nr(po)( or9)2; -(o)n6-(ch2)nrsoror9; halogênio; organosilanila; organosiloxanila; ou um radical açúcar ligado diretamente em um modo a ou ~ via o oxigênio anomérico ao sistema benzotropolona ou via um espaçador alquileno, alquenileno, alcadieno ou alcatrieno linear ou ramificado (açúcar- (ch2)n( x1)1 ou o-sistema benzotropolona, sendo que n = 1 -10 e x1 = -0-; -(co)-; -oco-; -coo-, -nh-; -s-; -sor ); r1, r7 e r8 independentemente um do outro são hidrogênio; c1-c12alquila ou c3-c12-cicloalquila, que pode ser substituído por um ou mais e e/ou interrompido por um ou mais d; c6-c20arila, que pode ser substituído por um ou mais g; c4-c20heteroarila, que pode ser substituído por um ou mais g, crc1salquenila, crc18alquinila, crc25aralquila, ou coor9; cor9; conr9r10; so3r9; so2r9; po3(r9)2; po2(r9)2; organosilanila; organosiloxanila; ou um radical açúcar ligado diretamente em um modo a ou ~ via o oxigênio anomérico ao sistema benzotropolona ou via um espaçador alquileno, alquenileno, alcadieno ou alcatrieno linear ou ramificado (açúcar-(ch2)0-(x2)1 ou o-*, sendo que n = 1 -10 e x2 = -c(=o)-; - o-co-*); r9 e r10 independentemente um do outro são hidrogênio; c1- c18alquila ou c3-c12-cicloalquila que pode ser substituído por um ou mais e e/ou interrompido por um ou mais d; c6-c20arila, que pode ser substituído por um ou mais g; c4-c20heteroarila, que pode ser substituído por um ou mais g; organosilanila; organosiloxanila; ou um radical açúcar ligado diretamente em um modo alfa ou beta via o oxigênio anomérico ou via um espaçador alquileno, alquenileno, alcadieno ou alcatrieno linear ou ramificado (açúcar- (ch2)0 -*, sendo que n = 1 -10); ou r9 e r10 em conjunto formam um anel com cinco ou seis membros, r11 é hidrogênio; ou c1-c5alquila; n1, n2, il4 e n7 independentemente um do outro são um número de 1 a 5; n3, n5 e il6 independentemente um do outro são um o; ou l; d é -co-; -coo-; -s-; -so-; -sor; -0-; -nr14-; -sir19r20-; -por11-; -cr12 equivalente a cr13-; ou -c equivalente a c-; e e é -or1s; -sr1s; -nr14r1s; -nr14cor1s; -cor17; -coor16; -conr14r1s; -cn; halogênio; ou so3r18; so2r18; po3(r18)2; po2(r18)2; organosilanila; organosiloxanila; ou um radical açúcar ligado diretamente em um modo alfa ou beta via o oxigênio anomérico ou via um espaçador alquileno, alquenileno, alcadieno ou alcatrieno linear ou ramificado (açúcar- (ch2)0-(x1)1 ou o -*, sendo que n = 1 -10 e x1 = -o-· -c(=o)-· -o-co-· -coo-· -nh-· -s-· -so2-)· g é e; c1-c18alquila, que é opcionalmente interrompido por d; c1- c18perfluoroalquila; c1-c18alcóxi, que é opcionalmente substituído por e e/ou interrompido por d; sendo que r12, r13, r14 e r15 independentemente um do outro são hidrogênio; c6-c18arila que é opcionalmente substituído por oh, c1-c18alquila ou c1-c18alcóxi; c1-c18alquila, que é opcionalmente interrompido por -0-; ou r14 e r15 em conjunto formam um anel com cinco ou seis membros, r16 é hidrogênio; c6-c18arila que é opcionalmente substituído por oh, c1-c18alquila ou c1-c18alcóxi; c1-c18alquila que é opcionalmente interrompido por -0-; r17 é h; c6-c18arila que é opcionalmente substituído por oh, c1-c18alquila ou c1-c18alcóxi; ou c1- c18 alquila que é opcionalmente interrompido por -0-; r18 é hidrogênio; c6-c18 arila, que é opcionalmente substituído por oh, c1-c18alquila ou c1- c18 alcóxi; c1-c1salquila, que é opcionalmente interrompido por -0-; r19 e r20 independentemente um do outro são hidrogênio; c1-c18alquila; c6-c18arila que é opcionalmente substituído por c1-c18alquila; e r21 é c1-c18alquila; ou c6-c1sarila, que é substituído por c1-c18alquila; * significa que este radical se refere à porção benzotropolona; para a proteção de pele e cabelo de ser humano e pele e pelo de animal contra radiação uv.

    Uso de compuestos de hidrazida como catalizadores de oxidación
    9.
    发明专利
    Uso de compuestos de hidrazida como catalizadores de oxidación 未知

    公开(公告)号：ES2727511T3

    公开(公告)日：2019-10-16

    申请号：ES09731048

    申请日：2009-03-30

    Applicant: BASF SE

    Inventor： WAGNER BARBARA ,  ROHWER HAUKE ,  DUBS MARIE-JOSÉE ,  HAZENKAMP MENNO ,  EICHIN KAI ,  SCHNEIDER ALBERT

    IPC: B01J31/02 ,  A61L2/18 ,  A61L12/12 ,  C11D3/16 ,  C11D3/39 ,  D06L4/12

    Abstract: Uso, como catalizador para reacciones de oxidación, de al menos un compuesto de fórmula (2)**Fórmula** en la que R1 indica alquilo C1-C4 o fenilo, que están sustituidos con uno o más sustituyentes de extracción de electrones; R4 indica hidrógeno, y R2 y R3, independientemente entre sí, indican hidrógeno; o alquilo C1-C28, alquenilo C2-C28, alquinilo C2-C22, cicloalquilo C3-C12, cicloalquenilo C3-C12, aralquilo C7-C9, heteroalquilo C3-C20, cicloheteroalquilo C3-C12, heteroaralquilo C5-C16, fenilo o naftilo cada uno de los cuales es no sustituido o sustituido con hidroxilo, halógeno o alcoxi C1-C4; o heteroarilo no sustituido; o R2 y R3, junto con el átomo de carbono del alquilideno que los une, forman un anillo de 5, 6, 7, 8 o 9 miembros no sustituido o sustituido que puede contener otros heteroátomos, o formas tautoméricas o mezclas de diferentes formas tautoméricas de los compuestos de fórmula (2).

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