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公开(公告)号:CA2717609C
公开(公告)日:2016-11-29
申请号:CA2717609
申请日:2009-03-20
Applicant: BASF SE
Inventor: TERRENOIRE ALEXANDRE , TITMARSH CHRIS , YAMASHITA HIDEKI , YONG CHEE SENG , CHOWDHRY MUBARIK MAHMOOD , KWAN MUN HOE (STANLEY) , ALLEN JONATHAN
IPC: C08F230/02 , C08F220/18 , C08K5/521 , C08L43/02 , C09D143/02
Abstract: The present invention relates to the use of a polymer dispersion (PD) containing at least one polymer (P) obtained through radical emulsion polymerization of at least one ethylenically unsaturated monomer (m1) and at least one monomer (m2) different therefrom selected from among the esters of phosphonic acid or phosphoric acid, alternatively with alkoxylated hydroxyalkyl (meth)actylates and at least one emulsifier (E) selected from the phosphoric acid esters, alternatively with alkoxylated C8-C30 alcohols and salts thereof, in coating agents for improving the abrasion resistance of coatings produced therefrom and/or for improving the polishing resistance of the coatings produced therefrom and/or for improving the stain resistance of the coatings produced therefrom and/or for improving the pigment distribution in the coatings produced therefrom and/or for reducing the emissions of volatile organic compounds from the coatings produced therefrom, polymer dispersions used according to the invention, and coating agents containing the polymer dispersions according to the invention.
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公开(公告)号:PL1926787T3
公开(公告)日:2010-07-30
申请号:PL06793397
申请日:2006-09-11
Applicant: BASF SE
Inventor: CHOWDHRY MUBARIK MAHMOOD , YAMASHITA HIDEKI , YONG CHEESENG , CATTERALL GREGORY JOHN , ALLEN JONATHON SHANE , VAN SONSBEEK ROGER JAN , REDFERN DAVID , SCHULER BERNHARD , WAGNER OLIVER , CHRISTIE DAVID
IPC: C09D133/08 , C08K5/521 , C09D7/12 , C09D133/12
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公开(公告)号:BRPI0615824B1
公开(公告)日:2016-07-19
申请号:BRPI0615824
申请日:2006-09-11
Applicant: BASF SE
Inventor: CHOWDHRY MUBARIK , YAMASHITA HIDEKI , YONG CHEESENG , CATTERALL GREGORY , ALLEN JONATHON , VAN SONSBEEK ROGER , REDFERN DAVID , SCHULER BERNHARD , WAGNER OLIVER , CHRISTIE DAVID
IPC: C08K5/36 , C08K5/51 , C09D7/12 , C09D133/08 , C09D133/12 , C09D135/06 , C09D201/00
Abstract: método para melhorar a resistência ao manchamento e resistência à penetração de composições de revestimento aquosas, e, uso de um tensoativo aniônico. a invenção tambpem diz respeito a um método para aumentar a resistência ao manchamento e a resistência à penetração de composições de revestimento aquosas, cujo método compreende fornecer uma composição de revestimento que contém pelo menos um pigmento, pelo menos um polímero que forma filme na forma de uma dispersão de polímeto aquosa e pelo menos um tensoativo aniônico, em que o tensoativo aniônico compreende pelo menos 85% em peso, preferivelmente pelo menos 90% em peso mais preferivelmente pelo menos 95 % em peso, com base no peso total de tensoativo aniônico na composição de revestimento, de pelo menos um tensoativo aniônico s, que é selecionado de semi-ésteres de ácido sulfúrico ou a´cido fosfórico com um álcool, cujo carrega pelo menos um radical alquila tendo de 8 a 30 átomos de carbono ou um radical fenila substituído por alquila cm em que alquila tem 4 a 20 átomos de carbono e cujo álcool pode carregar um grupo oligo-alquileno c~ 2~-c~ 3~-éter desde que o número de unidades de repetição no grupo oligo-alquileno c~ 2~-c~ 3~éter seja no máximo 15, ou um sal deste.
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公开(公告)号:AU2009227048B2
公开(公告)日:2014-07-17
申请号:AU2009227048
申请日:2009-03-20
Applicant: BASF SE
Inventor: YAMASHITA HIDEKI , CHOWDHRY MUBARIK MAHMOOD , ALLEN JONATHAN , KWAN MUN HOE STANLEY , YONG CHEE SENG , TITMARSH CHRIS , TERRENOIRE ALEXANDRE
IPC: C08F230/02 , C08F220/18 , C08K5/521 , C08L43/02 , C09D143/02
Abstract: The present invention relates to the use of a polymer dispersion (PD) containing at least one polymer (P) obtained through radical emulsion polymerization of at least one ethylenically unsaturated monomer (M1) and at least one monomer (M2) different therefrom selected from among the esters of phosphonic acid or phosphoric acid, alternatively with alkoxylated hydroxyalkyl (meth)actylates and at least one emulsifier (E) selected from the phosphoric acid esters, alternatively with alkoxylated C
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公开(公告)号:CA2717609A1
公开(公告)日:2009-09-24
申请号:CA2717609
申请日:2009-03-20
Applicant: BASF SE
Inventor: TERRENOIRE ALEXANDRE , TITMARSH CHRIS , YAMASHITA HIDEKI , YONG CHEE SENG , CHOWDHRY MUBARIK MAHMOOD , KWAN MUN HOE STANLEY , ALLEN JONATHAN
IPC: C08F230/02 , C08F220/18 , C08K5/521 , C08L43/02 , C09D143/02
Abstract: The present invention relates to the use of a polymer dispersion (PD) containing at least one polymer (P) obtained through radical emulsion polymerization of at least one ethylenically unsaturated monomer (M1) and at least one monomer (M2) different therefrom selected from among the esters of phosphonic acid or phosphoric acid, alternatively with alkoxylated hydroxyalkyl (meth)actylates and at least one emulsifier (E) selected from the phosphoric acid esters, alternatively with alkoxylated C8-C30 alcohols and salts thereof, in coating agents for improving the abrasion resistance of coatings produced therefrom and/or for improving the polishing resistance of the coatings produced therefrom and/or for improving the stain resistance of the coatings produced therefrom and/or for improving the pigment distribution in the coatings produced therefrom and/or for reducing the emissions of volatile organic compounds from the coatings produced therefrom, polymer dispersions used according to the invention, and coating agents containing the polymer dispersions according to the invention.
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6.
公开(公告)号:AU2006290757B2
公开(公告)日:2012-09-27
申请号:AU2006290757
申请日:2006-09-11
Applicant: BASF SE
Inventor: YONG CHEESENG , ALLEN JONATHON SHANE , CHRISTIE DAVID , SCHULER BERNHARD , VAN SONSBEEK ROGER JAN , YAMASHITA HIDEKI , CHOWDHRY MUBARIK MAHMOOD , CATTERALL GREGORY JOHN , WAGNER OLIVER , REDFERN DAVID
IPC: C09D133/08 , C08K5/36 , C08K5/51 , C09D7/12 , C09D133/12 , C09D135/06 , C09D201/00
Abstract: The invention also relates to a method to increase stain resistance and penetration resistance of aqueous coating compositions which method comprises providing a coating composition which contain at least one pigment, at least one film-forming polymer in the form of an aqueous polymer dispersion and at least one anionic surfactant, wherein the anionic surfactant comprises at least 85 % by weight, preferably at least 90 % by weight, more preferably at least 95 % by weight, based on the total weight of ani- onic surfactant in the coating composition, of at least one anionic surfactant S, which is selected from semi-esters of sulfuric acid or phosphoric acid with an alcohol, which alcohol carries at least one alkyl radical having from 8 to 30 carbon atoms or an alkyl substituted phenyl radical wherein alkyl has from 4 to 30 carbon atoms and which alco- hol may carry an oligo-C-C-alkylene-ether group provided that the number of repeat- ing units in the oligo-C-C-alkylene-ether group is at most 15, or a salt thereof.
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公开(公告)号:DE602006012067D1
公开(公告)日:2010-03-18
申请号:DE602006012067
申请日:2006-09-11
Applicant: BASF SE
Inventor: CHOWDHRY MUBARIK MAHMOOD , YAMASHITA HIDEKI , YONG CHEESENG , CATTERALL GREGORY JOHN , ALLEN JONATHON SHANE , VAN SONSBEEK ROGER JAN , REDFERN DAVID , SCHULER BERNHARD , WAGNER OLIVER , CHRISTIE DAVID
IPC: C09D133/08 , C08K5/36 , C08K5/51 , C09D7/12 , C09D133/12 , C09D135/06 , C09D201/00
Abstract: The invention also relates to a method for stain resistance and penetration resistance of aqueous coating compositions which method comprises providing a coating composition which contain at least one pigment, at least one film-forming polymer in the form of an aqeuous polymer dispersion and at least one anionic surfactant, wherein the anionic surfactant comprises at least 85 % by weight, preferably at least 90 % by weight, more preferably at least 95 % by weight, based on the total weight of anionic surfactant in the coating composition, of at least one anionic surfactant S, which is selected from semi-esters of sulfuric acid or phosphoric acid with an alcohol, which alcohol carries at least one alkyl radical having from 8 to 30 carbon atoms or an alkyl substituted phenyl radical wherein alkyl has from 4 to 30 carbon atoms and which alcohol may carry an oligo-C 2 -C 3 -alkylene-ether group provided that the number of repeating units in the oligo-C 2 -C 3 -alkylene-ether group is at most 15, or a salt thereof.
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公开(公告)号:AT456635T
公开(公告)日:2010-02-15
申请号:AT06793397
申请日:2006-09-11
Applicant: BASF SE
Inventor: CHOWDHRY MUBARIK , YAMASHITA HIDEKI , YONG CHEESENG , CATTERALL GREGORY , ALLEN JONATHON , VAN SONSBEEK ROGER , REDFERN DAVID , SCHULER BERNHARD , WAGNER OLIVER , CHRISTIE DAVID
IPC: C09D133/08 , C08K5/36 , C08K5/51 , C09D7/12 , C09D133/12 , C09D135/06 , C09D201/00
Abstract: The invention also relates to a method for stain resistance and penetration resistance of aqueous coating compositions which method comprises providing a coating composition which contain at least one pigment, at least one film-forming polymer in the form of an aqeuous polymer dispersion and at least one anionic surfactant, wherein the anionic surfactant comprises at least 85 % by weight, preferably at least 90 % by weight, more preferably at least 95 % by weight, based on the total weight of anionic surfactant in the coating composition, of at least one anionic surfactant S, which is selected from semi-esters of sulfuric acid or phosphoric acid with an alcohol, which alcohol carries at least one alkyl radical having from 8 to 30 carbon atoms or an alkyl substituted phenyl radical wherein alkyl has from 4 to 30 carbon atoms and which alcohol may carry an oligo-C 2 -C 3 -alkylene-ether group provided that the number of repeating units in the oligo-C 2 -C 3 -alkylene-ether group is at most 15, or a salt thereof.
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公开(公告)号:AU2009227048A1
公开(公告)日:2009-09-24
申请号:AU2009227048
申请日:2009-03-20
Applicant: BASF SE
Inventor: CHOWDHRY MUBARIK MAHMOOD , TERRENOIRE ALEXANDRE , YONG CHEE SENG , KWAN MUN HOE STANLEY , ALLEN JONATHAN , TITMARSH CHRIS , YAMASHITA HIDEKI
IPC: C08F230/02 , C08F220/18 , C08K5/521 , C08L43/02 , C09D143/02
Abstract: The present invention relates to the use of a polymer dispersion (PD) comprising at least one polymer (P), obtainable by free-radical emulsion polymerization of at least one ethylenically unsaturated monomer (M1) and at least one monomer (M2) different therefrom and selected from esters of phosphonic acid or of phosphoric acid with unalkoxylated or alkoxylated hydroxyalkyl(meth)acrylates, and at least one emulsifier (E) selected from phosphoric esters with unalkoxylated or alkoxylated C8-C30 alkanols, and their salts, in coating materials to improve the scrub resistance of the coatings produced therefrom and/or to improve the burnish resistance of the coatings produced therefrom and/or to improve the stain resistance of the coatings produced therefrom and/or to improve the pigment distribution in the coatings produced therefrom and/or to reduce the emission of volatile organic compounds by the coatings produced therefrom, to polymer dispersions used in accordance with the invention, and to coating materials comprising the polymer dispersions of the invention.
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公开(公告)号:ES2636995T3
公开(公告)日:2017-10-10
申请号:ES09721936
申请日:2009-03-20
Applicant: BASF SE
Inventor: TERRENOIRE ALEXANDRE , TITMARSH CHRIS , YAMASHITA HIDEKI , YONG CHEE SENG , CHOWDHRY MUBARIK MAHMOOD , KWAN MUN HOE (STANLEY) , ALLEN JONATHAN
IPC: C08F230/02 , C08F2/26 , C08F220/18 , C08K5/521 , C08L43/02 , C09D143/02
Abstract: Uso de una dispersión polimérica (PD) que contiene: i) al menos un polímero (P), que puede obtenerse mediante polimerización en emulsión por radicales de al menos un monómero etilénicamente insaturado (M1) y de al menos un monómero distinto de éste (M2), que se seleccionan entre ésteres del ácido fosfónico o del ácido fosfórico con (met)acrilatos de hidroxialquilo eventualmente alcoxilados y ii) al menos un emulsionante (E), seleccionado entre compuestos de fórmula (I) R1-O-(AO)m-P(>=O)(OR2)(OH) (I) en la que m representa un número entero de 0 a 20, AO representa alquilenoxi, R1 representa alquilo C8-C30 y R2 representa H o un grupo -(AO)m-R2a, en el que R2a presenta el significado dado para R1 y AO y m presentan uno de los significados dados anteriormente, y las sales de los compuestos de fórmula (I); en agentes de pintura para la mejora de la estabilidad frente a la abrasión de las pinturas preparadas a partir de estos y/o para la mejora de la estabilidad frente al pulido de las pinturas preparadas a partir de estos y/o para la mejora de la estabilidad frente a las manchas de las pinturas preparadas a partir de estos y/o para la mejora de la distribución de pigmentos en las pinturas preparadas a partir de estos y/o para la reducción de la emisión de compuestos orgánicos volátiles por las pinturas preparadas a partir de estos en el que el polímero (P) puede obtenerse mediante una polimerización en emulsión, en la que la proporción de los monómeros (M1) se encuentra en el intervalo del 95 al 99,99 % en peso, con respecto al peso total de los monómeros usados para la polimerización en emulsión, en el que los monómeros (M1) se seleccionan exclusivamente entre los monómeros principales (M1.a) y los monómeros secundarios (M1.b), y en el que al menos el 50 % en peso de los monómeros (M1), con respecto al peso total de los monómeros (M1), se seleccionan entre ésteres de ácidos mono- y dicarboxílicos a,b-etilénicamente insaturados con alcanoles C1-C30, ésteres de alcohol vinílico o alcohol alílico con ácidos monocarboxílicos C1-C30, nitrilos etilénicamente insaturados, haluros de vinilo, haluros de vinilideno y mezclas de los mismos (>= monómeros M1.a), y en el que menos del 50 % en peso de los monómeros (M1), con respecto al peso total de los monómeros (M1), se seleccionan entre ácidos mono- y dicarboxílicos etilénicamente insaturados, los anhídridos y semiésteres de ácidos dicarboxílicos etilénicamente insaturados, (met)acrilamidas, (met)-acrilatos de hidroxialquilo C1-C10, hidroxialquil(C1- C10)-(met)acrilamidas y mezclas de los mismos (>= monómeros M1.b).
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