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公开(公告)号：PL2601240T3
公开(公告)日：2014-09-30
申请号：PL11735655
申请日：2011-07-26
Applicant: BASF SE
Inventor： KLUMPE MARKUS , OSTROWSKI THOMAS , ZIPPLIES MATTHIAS
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公开(公告)号：AU2011287702A1
公开(公告)日：2013-02-21
申请号：AU2011287702
申请日：2011-07-26
Applicant: BASF SE
Inventor： KLUMPE MARKUS , OSTROWSKI THOMAS , ZIPPLIES MATTHIAS
Abstract: What is proposed is a process for preparing polyether alcohols by reaction of one or more unsaturated starters having at least one active hydrogen atom per molecule with one or more alkylene oxides in the liquid phase, in the presence of a basic catalyst, in a reactor, which is characterized in that the metered addition of the one or more alkylene oxides into the reactor is effected in such a way that the concentration of unreacted alkylene oxide in the liquid reaction mixture in the reactor is increased as far as possible with increasing degree of addition of the alkylene oxide onto the starter, it being necessary at all times to meet the condition that the temperature at the end of a runaway reaction is at least 100 K below the onset temperature of the decomposition reaction of the liquid reaction mixture.
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公开(公告)号：AU2011287702B2
公开(公告)日：2015-04-09
申请号：AU2011287702
申请日：2011-07-26
Applicant: BASF SE
Inventor： KLUMPE MARKUS , OSTROWSKI THOMAS , ZIPPLIES MATTHIAS
Abstract: What is proposed is a process for preparing polyether alcohols by reaction of one or more unsaturated starters having at least one active hydrogen atom per molecule with one or more alkylene oxides in the liquid phase, in the presence of a basic catalyst, in a reactor, which is characterized in that the metered addition of the one or more alkylene oxides into the reactor is effected in such a way that the concentration of unreacted alkylene oxide in the liquid reaction mixture in the reactor is increased as far as possible with increasing degree of addition of the alkylene oxide onto the starter, it being necessary at all times to meet the condition that the temperature at the end of a runaway reaction is at least 100 K below the onset temperature of the decomposition reaction of the liquid reaction mixture.
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公开(公告)号：MX2013001101A
公开(公告)日：2013-03-21
申请号：MX2013001101
申请日：2011-07-26
Applicant: BASF SE
Inventor： OSTROWSKI THOMAS , KLUMPE MARKUS , ZIPPLIES MATTHIAS
Abstract: Se propone un procedimiento para preparar poliéteralcoholes haciendo reaccionar en un reactor uno o varios iniciadores no saturados que tenga al menos un átomo de hidrógeno activo por cada molécula, con uno o varios óxidos de alquileno en fase líquida, en presencia de un catalizador básico, caracterizado porque el añadido dosificado de uno o varios óxidos de alquileno en el reactor se efectúa de tal manera que la concentración de óxido de alquileno sin reaccionar en la mezcla de reacción líquida dentro del reactor, al ir aumentando el grado de adicionamiento de óxido de alquileno al iniciador, se aumenta en todo lo posible, teniendo que cumplirse en todo momento la condición de que la temperatura al finalizar la reacción fuera de control se halle por lo menos 100 K por debajo de la temperatura de iniciación de la reacción de descomposición de la mezcla de reacción líquida.
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公开(公告)号：ES2387044T3
公开(公告)日：2012-09-12
申请号：ES07821852
申请日：2007-10-25
Applicant: BASF SE
Inventor： GROSCH GEORG HEINRICH , ZIPPLIES MATTHIAS , OSTROWSKI THOMAS , ANNEN ULRICH , KLUMPE MARKUS
Abstract: Método para la producción de polieteralcoholes mediante la reacción de por lo menos un óxido de alquileno conpor lo menos un iniciador insaturado con por lo menos un átomo de hidrógeno activo por molécula bajó catálisisbásica, caracterizado porque la alcoxilación es ejecutada en por lo menos dos etapas, donde en la primera etapa(I) se realiza la alcoxilación del o de los iniciadores con máximo 10 mol de óxido de alquileno por mol de iniciadorcon una concentración de catalizador de máximo 0,00415 mol de catalizador básico por mol de iniciador, y en laetapa (II) y la o las etapas siguientes el o los iniciadores alcoxilados de la etapa (I) reaccionan con otro óxido dealquileno a una concentración de catalizador de por lo menos 0,015 mol de catalizador básico por mol de iniciador.
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Patent Agency Ranking
公开(公告)号：SG187585A1
公开(公告)日：2013-03-28
申请号：SG2013005145
申请日：2011-07-26
Applicant: BASF SE
Inventor： KLUMPE MARKUS , OSTROWSKI THOMAS , ZIPPLIES MATTHIAS
Abstract: 12Process for preparing allyl alcohol alkoxylates Abstract 5 A process for preparing polyether alcohols by reacting one or more unsaturatedstarters having at least one active hydrogen atom per molecule with one or more alkylene oxides in the liquid phase in the presence of a basic catalyst in a reactor, wherein the one or more alkylene oxides are introduced into the reactor in such a way that the concentration of unreacted alkylene oxide in the liquid reaction mixture in the 10 reactor is increased as far as possible with increasing degree of addition of the alkylene oxide onto the starter, with the proviso that the temperature at the end of a runaway reaction is at any point in time at least 100 K below the onset temperature of the decomposition reaction of the liquid reaction mixture, is proposed. No suitable figure
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公开(公告)号：BR112013001723A2
公开(公告)日：2016-05-31
申请号：BR112013001723
申请日：2011-07-26
Applicant: BASF SE
Inventor： KLUMPE MARKUS , ZIPPLIES MATTHIAS , OSTROWSKI THOMAS
Abstract: processo para preparar poliéter alcoóis reagindo um ou mais iniciadores insaturados. é proposto um processo para preparar poliéter alcoóis pela reação d eum ou mais iniciadores insaturados tendo pelo menos um átomo de hidrogênio ativo por molécula com um ou mais óxidos de alquileno na fase líquida, na presença de um catalisador básico, em um reator, que é caracterizado em que a adição medida de um ou mais óxidos de alquileno no reator é afetada, de maneira tal que a concentração de óxido de alquileno não regaido na mistura de reação líquida no reator seja aumentada o máximo possível com grau crescente de adição do óxido de alquileno no iniciador, sendo necessário toda vez atender a condição de que a temperatura no final da reação seja pelo menos 100k abaixo da temperatuta de início da reação de decomposição da mistura de reação líquida.
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公开(公告)号：CA2703076A1
公开(公告)日：2009-04-30
申请号：CA2703076
申请日：2007-10-25
Applicant: BASF SE
Inventor： GROSCH GEORG HEINRICH , ZIPPLIES MATTHIAS , OSTROWSKI THOMAS , ANNEN ULRICH , KLUMPE MARKUS
Abstract: A process for preparing polyether alcohols by reacting at least one alkylene oxide with at least one unsaturated starter having at least one active hydrogen atom per molecule under basic catalysis, which comprises performing the alkoxylation in at least two stages, the alkoxylation of the starter(s) being performed in stage (I) with a maximum of 10 mol of alkylene oxide per mole of starter with a catalyst concentration of not more than 0.0085 mol of basic catalyst per mole, and, in stage (II) and any subsequent stages, reacting the alkoxylated starter(s) from stage (I) with further alkylene oxide at a catalyst concentration of at least 0.010 mol of basic catalyst per mole of starter.
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公开(公告)号：BRPI0722123A2
公开(公告)日：2014-04-08
申请号：BRPI0722123
申请日：2007-10-25
Applicant: BASF SE
Inventor： GROSCH GEORG HEINRICH , ZIPPLIES MATTHIAS , OSTROWSKI THOMAS , ANNEN ULRICH , KLUMPE MARKUS
Abstract: A process for the preparation of polyether alcohols by reacting at least one alkylene oxide with at least one unsaturated starter having at least one active hydrogen atom per molecule under basic catalysis, that the alkoxylation is carried out in at least two stages, in stage (I) the alkoxylation of the starter or starters being carried out with not more than 10 mol of alkylene oxide per mole of starter with a catalyst concentration of not more than 0.0085 mol of basic catalyst per mole and in stage (II) and the optionally following stages, the alkoxylated starter or starters from stage (I) being reacted with further alkylene oxide at a catalyst concentration of at least 0.01 mol of basic catalyst per mole of starter.
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10.发明专利
公开(公告)号：CA2703076C
公开(公告)日：2013-11-19
申请号：CA2703076
申请日：2007-10-25
Applicant: BASF SE
Inventor： GROSCH GEORG HEINRICH , ZIPPLIES MATTHIAS , OSTROWSKI THOMAS , ANNEN ULRICH , KLUMPE MARKUS
Abstract: A process for the preparation of polyether alcohols by reacting at least one alkylene oxide with at least one unsaturated starter having at least one active hydrogen atom per molecule under basic catalysis, that the alkoxylation is carried out in at least two stages, in stage (I) the alkoxylation of the starter or starters being carried out with not more than 10 mol of alkylene oxide per mole of starter with a catalyst concentration of not more than 0.0085 mol of basic catalyst per mole and in stage (II) and the optionally following stages, the alkoxylated starter or starters from stage (I) being reacted with further alkylene oxide at a catalyst concentration of at least 0.01 mol of basic catalyst per mole of starter.
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